RankLab
Back to Questions
ChemistryHardNumerical2023 · 11 Apr Shift 1

Q57.In an electrochemical reaction of lead, at standard temperature, if EPb2o + / Pb = n Volt, then the value of E°Pb2 + / Pb4 + is given by m – xn. The value of x is _______. EPb4o + / Pb (Nearest integer)

What This Question Tests

This question tests the ability to combine standard electrode potentials for different oxidation states using the Gibbs free energy relationship (ΔG° = -nFE°) to find an unknown potential.

Concepts Tested

Standard electrode potentialGibbs free energy changeRelation between E° and ΔG°

Formulas Used

ΔG° = -nFE°

ΔG°_overall = ΔG°_1 + ΔG°_2

📚 NCERT Sections This Tests

2.4Calculate The Standard Cell Potentials Of Galvanic Cell In Which The Following

Chemistry Class 11 · Chapter 2

78% match

2.4 Calculate the standard cell potentials of galvanic cell in which the following reactions take place: (i) 2Cr(s) + 3Cd2+(aq) ® 2Cr3+(aq) + 3Cd (ii) Fe2+(aq) + Ag+(aq) ® Fe3+(aq) + Ag(s) Calculate the DrGo and equilibrium constant of the reactions. 2.5 Write the Nernst equation and emf of the following cells at 298 K: (i) Mg(s)|Mg2+(0.001M)||Cu2+(0.0001 M)|Cu(s) (ii) Fe(s)|Fe2+(0.001M)||H+(1M)|H2(g)(1bar)| Pt(s) (iii) Sn(s)|Sn2+(0.050 M)||H+(0.020 M)|H2(g) (1 bar)|Pt(s) (iv) Pt(s)|Br–(0.010 M)|Br2(l )||H+(0.030 M)| H2(g) (1 bar)|Pt(s).

2.6In The Button Cells Widely Used In Watches And Other Devices The Following

Chemistry Class 11 · Chapter 2

77% match

2.6 In the button cells widely used in watches and other devices the following reaction takes place: Zn(s) + Ag2O(s) + H2O(l) ® Zn2+(aq) + 2Ag(s) + 2OH–(aq) Determine DrGo and Eo for the reaction.

2.2Given The Standard Electrode Potentials,

Chemistry Class 11 · Chapter 2

77% match

2.2 Given the standard electrode potentials, K+/K = –2.93V, Ag+/Ag = 0.80V, Hg2+/Hg = 0.79V Mg2+/Mg = –2.37 V, Cr3+/Cr = – 0.74V Arrange these metals in their increasing order of reducing power.