1.23 Suggest the most important type of intermolecular attractive interaction in the following pairs. (i) n-hexane and n-octane (ii) I2 and CCl4 (iii) NaClO4 and water (iv) methanol and acetone (v) acetonitrile (CH3CN) and acetone (C3H6O). 1.24 Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain. Cyclohexane, KCl, CH3OH, CH3CN.

4.11 Explain giving reasons: (i) Transition metals and many of their compounds show paramagnetic behaviour. (ii) The enthalpies of atomisation of the transition metals are high. (iii) The transition metals generally form coloured compounds. (iv) Transition metals and their many compounds act as good catalyst.

12.1 Choose the correct alternative from the clues given at the end of the each statement: (a) The size of the atom in Thomson’s model is .......... the atomic size in Rutherford’s model. (much greater than/no different from/much less than.) (b) In the ground state of .......... electrons are in stable equilibrium, while in .......... electrons always experience a net force. (Thomson’s model/ Rutherford’s model.) (c) A classical atom based on .......... is doomed to collapse. (Thomson’s model/ Rutherford’s model.) (d) An atom has a nearly continuous mass distribution in a .......... but has a highly non-uniform mass distribution in .......... (Thomson’s model/ Rutherford’s model.) (e) The positively charged part of the atom possesses most of the mass in .......... (Rutherford’s model/both the models.)