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ChemistryHardMCQ2013 · 22 Apr Online

Q42.Arrange in the correct order of stability (decreasing order) for the following molecules: (I) (II) (III) (IV) (1) (I) > (II) > (III) > (IV) (2) (IV) > (III) > (II) ≈ (I) (3) (I) > (II) ≈ (III) > (IV) (4) (III) > (I) ≈ (II) > (IV)

What This Question Tests

This question evaluates the ability to determine the relative stability of various carbocations, requiring analysis of resonance effects (allyl), hyperconjugation, and the high instability of carbocations on sp2 hybridized carbons (vinyl, phenyl), as well as special stabilization mechanisms (cyclopropylmethyl).

Concepts Tested

Carbocation stabilityResonance stabilizationHyperconjugationAromaticity/Antiaromaticity (related to stability)Bent bond conjugation

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