9.5 How will you convert: (i) Ethanoic acid into methanamine (ii) Hexanenitrile into 1-aminopentane (iii) Methanol to ethanoic acid (iv) Ethanamine into methanamine (v) Ethanoic acid into propanoic acid (vi) Methanamine into ethanamine (vii) Nitromethane into dimethylamine (viii) Propanoic acid into ethanoic acid? 9.6 Describe a method for the identification of primary, secondary and tertiary amines. Also write chemical equations of the reactions involved.

9.9 Give the structures of A, B and C in the following reactions: B NaOH  Br 2 C (i) CH 3 CH 2 I NaCN A Partial OHhydrolysis CuCN H 2 O/H  NH 3 (ii) C 6 H 5 N 2 Cl  A  B  C 4 B HNO 2 C (iii) CH 3 CH 2 Br KCN A LiAlH 0  C  2  2 O/H HCl B H C  (iv) C6 H 5 NO 2 Fe/HCl A NaNO273 K 3 A NaOBr B NaNO 2 /HCl C (v) CH 3 COOH NH 2 B C 6 H 5 OH C (vi) C6 H 5 NO 2 Fe/HCl A HNO273K 279 Amines Reprint 2025-26

6.22 What happens when (i) n-butyl chloride is treated with alcoholic KOH, (ii) bromobenzene is treated with Mg in the presence of dry ether, (iii) chlorobenzene is subjected to hydrolysis, (iv) ethyl chloride is treated with aqueous KOH, (v) methyl bromide is treated with sodium in the presence of dry ether, (vi) methyl chloride is treated with KCN? Answers to Some Intext Questions 6.1 6.2 (i) H2SO4 cannot be used along with KI in the conversion of an alcohol to an alkyl iodide as it converts KI to corresponding acid, HI which is then oxidised by it to I2. 6.3 (i) ClCH2CH2CH2Cl (ii) ClCH2CHClCH3 (iii) Cl2CHCH2CH3 (iv) CH3CCl2CH3 191 Haloalkanes and Haloarenes Reprint 2025-26