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ChemistryMediumMulti concept2020 · 02 Sep Shift 1

Q45.Consider the following reactions : dry HCI x eq. of −−(i) Glucose +ROH → Acetal → acetyl derivative (CH3 CO)2 Ni /H2 y eq. of −−(ii) Glucose → A → acetyl derivative (CH3 CO)2O z eq. of −(iii) Glucose → acetyl derivative ' x' , ' y' and ' z' in these reactions are respectively. (CH3 CO)2O (1) 5, 4 & 6 (2) 4, 6 & 5 (3) 4, 5 & 5 (4) 5, 6 & 5

What This Question Tests

This question tests understanding of the characteristic reactions of glucose, specifically its acetylation in different forms (open chain, cyclic, acetal) and its reduction to sorbitol.

Concepts Tested

Glucose reactionsAcetal formationReduction of glucoseAcetylationOpen chain and cyclic forms of glucose

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