9.4 Alkynes 1 2 3 4 5 Like alkenes, alkynes are also unsaturated II. H3C–C≡ C– CH2– CH3 Pent–2-yne hydrocarbons. They contain at least one triple 4 3 2 1 bond between two carbon atoms. The number III. H3C–CH–C≡ CH 3-Methyl but–1-yne |of hydrogen atoms is still less in alkynes as CH3compared to alkenes or alkanes. Their general Structures I and II are position isomers formula is CnH2n–2. and structures I and III or II and III are chain The first stable member of alkyne series isomers. is ethyne which is popularly known as acetylene. Acetylene is used for arc welding Problem 9.13 purposes in the form of oxyacetylene flame Write structures of different isomers obtained by mixing acetylene with oxygen corresponding to the 5 th member of gas. Alkynes are starting materials for a large alkyne series. Also write IUPAC names of number of organic compounds. Hence, it all the isomers. What type of isomerism is interesting to study this class of organic is exhibited by different pairs of isomers? compounds. Solution 9.4.1 Nomenclature and Isomerism th 5 member of alkyne has the molecular In common system, alkynes are named as formula C6H10. The possible isomers are: derivatives of acetylene. In IUPAC system, they Table 9.2 Common and IUPAC Names of Alkynes (CnH2n–2) Value of n Formula Structure Common name IUPAC name 2 C2H2 H-C≡CH Acetylene Ethyne 3 C3H4 CH3-C≡CH Methylacetylene Propyne 4 C4H6 CH3CH2-C≡CH Ethylacetylene But-1-yne 4 C4H6 CH3-C≡C-CH3 Dimethylacetylene But-2-yne Reprint 2025-26 Hydrocarbons 315 (a) HC ≡ C – CH2 – CH2 – CH2 – CH3 Hex-1-yne (b) CH3 – C ≡ C – CH2 – CH2 – CH3 Hex-2-yne (c) CH3 – CH2 – C ≡ C – CH2– CH3 Hex-3-yne 3-Methylpent-1-yne 4-Methylpent-1-yne 4-Methylpent-2-yne Fig. 9.6 Orbital picture of ethyne showing (a) sigma overlaps (b) pi overlaps. orbitals of the other carbon atom, which undergo lateral or sideways overlapping to 3,3-Dimethylbut-1-yne form two pi (π) bonds between two carbon atoms. Thus ethyne molecule consists of one Position and chain isomerism shown by C–C σ bond, two C–H σ bonds and two C–C different pairs. π bonds. The strength of C≡C bond (bond enthalpy 823 kJ mol -1) is more than those 9.4.2 Structure of Triple Bond of C=C bond (bond enthalpy 681 kJ mol –1) Ethyne is the simplest molecule of alkyne and C–C bond (bond enthalpy 348 kJ mol–1). series. Structure of ethyne is shown in The C≡C bond length is shorter (120 pm) Fig. 9.6. than those of C=C (133 pm) and C–C (154 pm). Electron cloud between two carbon Each carbon atom of ethyne has two sp atoms is cylindrically symmetrical about thehybridised orbitals. Carbon-carbon sigma (σ) internuclear axis. Thus, ethyne is a linear bond is obtained by the head-on overlapping molecule. of the two sp hybridised orbitals of the two carbon atoms. The remaining sp hybridised 9.4.3 Preparation orbital of each carbon atom undergoes 1. From calcium carbide: On industrial overlapping along the internuclear axis with scale, ethyne is prepared by treating the 1s orbital of each of the two hydrogen calcium carbide with water. Calcium atoms forming two C-H sigma bonds. carbide is prepared by heating quick lime H-C-C bond angle is of 180°. Each carbon with coke. Quick lime can be obtained byhas two unhybridised p orbitals which are heating limestone as shown in the followingperpendicular to each other as well as to the reactions:plane of the C-C sigma bond. The 2p orbitals of one carbon atom are parallel to the 2p CaCO3 ∆ CaO + O2 (9.55) Reprint 2025-26 316 chemistry CaO + 3C CaC2 + CO (9.56) the sp hybridised carbon2 atoms whereas they are attached to sp hybridised carbon Calcium 3 atoms in ethene and sp hybridised carbons carbide in ethane. Due to the maximum percentage of CaC2 + 2H2O Ca(OH)2 + C2H2 (9.57) s character (50%), the sp hybridised orbitals of carbon atoms in ethyne molecules have2. From vicinal dihalides : Vicinal dihalides highest electronegativity; hence, these attract on treatment with alcoholic potassium the shared electron pair of the C-H bond of hydroxide undergo dehydrohalogenation. ethyne to a greater extent than that of the One molecule of hydrogen halide is 2 sp hybridised orbitals of carbon in ethene eliminated to form alkenyl halide which 3 and the sp hybridised orbital of carbon in on treatment with sodamide gives alkyne. ethane. Thus in ethyne, hydrogen atoms can be liberated as protons more easily as compared to ethene and ethane. Hence, hydrogen atoms of ethyne attached to triply bonded carbon atom are acidic in nature. You may note that the hydrogen atoms attached to the triply bonded carbons are acidic but not all the hydrogen atoms of alkynes. HC ≡ CH + Na → HC ≡ C–Na++ 1/2 H2 9.4.4 Properties Monosodium Physical properties ethynide Physical properties of alkynes follow the same (9.59) trend of alkenes and alkanes. First three HC ≡ C– Na + Na → Na+ C–Na+ ≡ C–Na++ 1/2 H2members are gases, the next eight are liquids and the higher ones are solids. All alkynes Disodium ethynide are colourless. Ethyene has characteristic (9.60)odour. Other members are odourless. Alkynes are weakly polar in nature. They are lighter CH3 – C ≡ C – H + Na+ NH–2 than water and immiscible with water but ↓ soluble in organic solvents like ethers, carbon CH3 – C ≡ C– Na+ + NH3 tetrachloride and benzene. Their melting Sodium propynide (9.61) point, boiling point and density increase with These reactions are not shown by alkenesincrease in molar mass. and alkanes, hence used for distinction Chemical properties between alkynes, alkenes and alkanes. What Alkynes show acidic nature, addition reactions about the above reactions with but-1-yne and and polymerisation reactions as follows : but-2-yne ? Alkanes, alkenes and alkynes A. Acidic character of alkyne: Sodium follow the following trend in their acidic metal and sodamide (NaNH2) are strong behaviour : bases. They react with ethyne to form sodium i) CH ≡ CH > H2C – CH2 > CH3 –CH3acetylide with the liberation of dihydrogen gas. These reactions have not been observed ii) HC ≡ CH > CH3 –C≡ CH >> CH3 –C≡C–CH3in case of ethene and ethane thus indicating that ethyne is acidic in nature in comparison B. Addition reactions: Alkynes contain a to ethene and ethane. Why is it so ? Has triple bond, so they add up, two molecules of it something to do with their structures dihydrogen, halogen, hydrogen halides etc. and the hybridisation ? You have read that Formation of the addition product takes place hydrogen atoms in ethyne are attached to according to the following steps. Reprint 2025-26 Hydrocarbons 317 The addition product formed depends upon stability of vinylic cation. Addition in unsymmetrical alkynes takes place according to Markovnikov rule. Majority of the reactions of alkynes are the examples of electrophilic addition reactions. A few addition reactions (9.66)are given below: (i) Addition of dihydrogen (iv) Addition of water Pt/Pd/Ni H2 Like alkanes and alkenes, alkynes are alsoHC≡CH+H2 [H2C = CH2] CH3–CH3 immiscible and do not react with water. (9.62) However, one molecule of water adds to alkynes on warming with mercuric sulphate CH3–C≡CH + H2 Pt/Pd/Ni [CH3–CH=CH2] and dilute sulphuric acid at 333 K to form Propyne Propene carbonyl compounds. ↓H2 CH3–CH2–CH3 Propane (9.63) (ii) Addition of halogens (9.67) (9.64) Reddish orange colour of the solution of bromine in carbon tetrachloride is decolourised. This is used as a test for unsaturation. (iii) Addition of hydrogen halides (9.68) Two molecules of hydrogen halides (HCl, HBr, (v) Polymerisation HI) add to alkynes to form gem dihalides (in (a) Linear polymerisation: Under suitable which two halogens are attached to the same conditions, linear polymerisation of ethyne carbon atom) takes place to produce polyacetylene or H–C≡C–H+H–Br [CH2 = CH–Br]→ CHBr2 polyethyne which is a high molecular Bromoethene weight polyene containing repeating units of CH3 (CH = CH – CH = CH ) and can be represented 1,1-Dibromoethane as —(CH = CH – CH = CH)n— Under special (9.65) conditions, this polymer conducts electricity. Reprint 2025-26 318 chemistry Thin film of polyacetylene can be used as but in a majority of reactions of aromatic electrodes in batteries. These films are good compounds, the unsaturation of benzene ring conductors, lighter and cheaper than the is retained. However, there are examples of metal conductors. aromatic hydrocarbons which do not contain a (b) Cyclic polymerisation: Ethyne on benzene ring but instead contain other highly unsaturated ring. Aromatic compoundspassing through red hot iron tube at 873K containing benzene ring are known asundergoes cyclic polymerization. Three benzenoids and those not containing amolecules polymerise to form benzene, which benzene ring are known as non-benzenoids.is the starting molecule for the preparation of Some examples of arenes are givenderivatives of benzene, dyes, drugs and large below:number of other organic compounds. This is the best route for entering from aliphatic to aromatic compounds as discussed below: Benzene Toluene Naphthalene (9.69) Biphenyl Problem 9.14 How will you convert ethanoic acid into 9.5.1 Nomenclature and Isomerism benzene? The nomenclature and isomerism of aromatic Solution hydrocarbons has already been discussed in Unit 8. All six hydrogen atoms in benzene are equivalent; so it forms one and only one type of monosubstituted product. When two hydrogen atoms in benzene are replaced by two similar or different monovalent atoms or groups, three different position isomers are possible. The 1, 2 or 1, 6 is known as the ortho (o–), the 1, 3 or 1, 5 as meta (m–) and the 1, 4 as para (p–) disubstituted compounds. A few examples of derivatives of benzene are given below:

2.1 Two charges 5 × 10–8 C and –3 × 10–8 C are located 16 cm apart. At what point(s) on the line joining the two charges is the electric potential zero? Take the potential at infinity to be zero.

13.2 PERIODIC AND OSCILLATORY MOTIONS Very often, the body undergoing periodic motion has an equilibrium position somewhereFig. 13.1 shows some periodic motions. Suppose inside its path. When the body is at this positionan insect climbs up a ramp and falls down, it no net external force acts on it. Therefore, if it iscomes back to the initial point and repeats the left there at rest, it remains there forever. If the process identically. If you draw a graph of its body is given a small displacement from the height above the ground versus time, it would position, a force comes into play which tries to look something like Fig. 13.1 (a). If a child climbs bring the body back to the equilibrium point, up a step, comes down, and repeats the process giving rise to oscillations or vibrations. For identically, its height above the ground would example, a ball placed in a bowl will be in look like that in Fig. 13.1 (b). When you play the equilibrium at the bottom. If displaced a little game of bouncing a ball off the ground, between from the point, it will perform oscillations in the your palm and the ground, its height versus time bowl. Every oscillatory motion is periodic, but graph would look like the one in Fig. 13.1 (c). every periodic motion need not be oscillatory. Note that both the curved parts in Fig. 13.1 (c) Circular motion is a periodic motion, but it is are sections of a parabola given by the Newton’s not oscillatory. equation of motion (see section 2.6), There is no significant difference between 1 2 oscillations and vibrations. It seems that when h = ut + gt for downward motion, and 2 the frequency is small, we call it oscillation (like, the oscillation of a branch of a tree), while when 1 2 h = ut – gt for upward motion, the frequency is high, we call it vibration (like, 2 the vibration of a string of a musical instrument). with different values of u in each case. These Simple harmonic motion is the simplest form are examples of periodic motion. Thus, a motion of oscillatory motion. This motion arises when that repeats itself at regular intervals of time is the force on the oscillating body is directly called periodic motion. proportional to its displacement from the mean position, which is also the equilibrium position. Further, at any point in its oscillation, this force is directed towards the mean position. In practice, oscillating bodies eventually (a) come to rest at their equilibrium positions because of the damping due to friction and other dissipative causes. However, they can be forced to remain oscillating by means of some external periodic agency. We discuss the phenomena of damped and forced oscillations later in the chapter. Any material medium can be pictured as a (b) collection of a large number of coupled oscillators. The collective oscillations of the constituents of a medium manifest themselves as waves. Examples of waves include water waves, seismic waves, electromagnetic waves. We shall study the wave phenomenon in the next chapter. (c) 13.2.1 Period and frequency We have seen that any motion that repeats itself at regular intervals of time is called periodic motion. The smallest interval of time after which the motion is repeated is called its Fig. 13.1 Examples of periodic motion. The period T period. Let us denote the period by the symbol is shown in each case. T. Its SI unit is second. For periodic motions, Reprint 2025-26 OSCILLATIONS 261 which are either too fast or too slow on the scale as a displacement variable [see Fig.13.2(b)]. The of seconds, other convenient units of time are term displacement is not always to be referred used. The period of vibrations of a quartz crystal is expressed in units of microseconds (10–6 s) abbreviated as µs. On the other hand, the orbital period of the planet Mercury is 88 earth days. The Halley’s comet appears after every 76 years. The reciprocal of T gives the number of repetitions that occur per unit time. This quantity is called the frequency of the periodic motion. It is represented by the symbol ν. The relation between ν and T is Fig. 13.2(a) A block attached to a spring, the other ν = 1/T (13.1) end of which is fixed to a rigid wall. The block moves on a frictionless surface. The The unit of ν is thus s–1. After the discoverer of motion of the block can be described in radio waves, Heinrich Rudolph Hertz (1857–1894), terms of its distance or displacement x a special name has been given to the unit of from the equilibrium position. frequency. It is called hertz (abbreviated as Hz). Thus, 1 hertz = 1 Hz =1 oscillation per second =1 s–1 (13.2) Note, that the frequency, ν, is not necessarily an integer. u Example 13.1 On an average, a human heart is found to beat 75 times in a minute. Calculate its frequency and period. Fig.13.2(b) An oscillating simple pendulum; its Answer The beat frequency of heart = 75/(1 min) motion can be described in terms of = 75/(60 s) angular displacement θ from the vertical. = 1.25 s–1 = 1.25 Hz in the context of position only. There can be The time period T = 1/(1.25 s–1) many other kinds of displacement variables. The = 0.8 s ⊳ voltage across a capacitor, changing with time in an AC circuit, is also a displacement variable.13.2.2 Displacement In the same way, pressure variations in time inIn section 3.2, we defined displacement of a the propagation of sound wave, the changingparticle as the change in its position vector. In electric and magnetic fields in a light wave arethis chapter, we use the term displacement examples of displacement in different contexts.in a more general sense. It refers to change The displacement variable may take bothwith time of any physical property under positive and negative values. In experiments onconsideration. For example, in case of rectilinear oscillations, the displacement is measured formotion of a steel ball on a surface, the distance different times.from the starting point as a function of time is The displacement can be represented by a its position displacement. The choice of origin mathematical function of time. In case of periodic is a matter of convenience. Consider a block motion, this function is periodic in time. One of attached to a spring, the other end of the spring the simplest periodic functions is given by is fixed to a rigid wall [see Fig.13.2(a)]. Generally, it is convenient to measure displacement of the f (t) = A cos ωt (13.3a) body from its equilibrium position. For an If the argument of this function, ωt, is oscillating simple pendulum, the angle from the increased by an integral multiple of 2π radians, vertical as a function of time may be regarded the value of the function remains the same. The Reprint 2025-26 262 PHYSICS function f (t) is then periodic and its period, T, (ii) This is an example of a periodic motion. It is given by can be noted that each term represents a 2 π periodic function with a different angular T = (13.3b) frequency. Since period is the least interval ω of time after which a function repeats its Thus, the function f (t) is periodic with period T, value, sin ωt has a period T0= 2π/ω ; cos 2 ωt f (t) = f (t+T ) has a period π/ω =T0/2; and sin 4 ωt has a period 2π/4ω = T0/4. The period of the firstThe same result is obviously correct if we term is a multiple of the periods of the lastconsider a sine function, f (t ) = A sin ωt. Further, two terms. Therefore, the smallest intervala linear combination of sine and cosine functions of time after which the sum of the threelike, terms repeats is T0, and thus, the sum is a f (t) = A sin ωt + B cos ωt (13.3c) periodic function with a period 2π/ω. is also a periodic function with the same period (iii) The function e–ωt is not periodic, itT. Taking, decreases monotonically with increasing A = D cos φ and B = D sin φ time and tends to zero as t → ∞ and thus, Eq. (13.3c) can be written as, never repeats its value. (iv) The function log(ωt) increases f (t) = D sin (ωt + φ ) , (13.3d) monotonically with time t. It, therefore, Here D and φ are constant given by never repeats its value and is a non- periodic function. It may be noted that as  B  t → ∞, log(ωt) diverges to ∞. It, therefore, 2 2 – 1 D = A + B and φ= tan  A  cannot represent any kind of physical displacement. ⊳ The great importance of periodic sine and cosine functions is due to a remarkable result 13.3 SIMPLE HARMONIC MOTION proved by the French mathematician, Jean Consider a particle oscillating back and forth Baptiste Joseph Fourier (1768–1830): Any about the origin of an x-axis between the limits periodic function can be expressed as a +A and –A as shown in Fig. 13.3. This oscillatory superposition of sine and cosine functions motion is said to be simple harmonic if the of different time periods with suitable displacement x of the particle from the origin coefficients. varies with time as : x (t) = A cos (ω t + φ) (13.4) u Example 13.2 Which of the following functions of time represent (a) periodic and (b) non-periodic motion? Give the period for each case of periodic motion [ω is any positive constant]. (i) sin ωt + cos ωt Fig. 13.3 A particle vibrating back and forth about the origin of x-axis, between the limits +A (ii) sin ωt + cos 2 ωt + sin 4 ωt and –A. (iii) e–ωt (iv) log (ωt) where A, ω and φ are constants. Thus, simple harmonic motion (SHM) is not Answer any periodic motion but one in which displacement is a sinusoidal function of time.(i) sin ωt + cos ωt is a periodic function, it can Fig. 13.4 shows the positions of a particle also be written as 2 sin (ωt + π/4). executing SHM at discrete value of time, each Now 2 sin (ωt + π/4)= 2 sin (ωt + π/4+2π) interval of time being T/4, where T is the period of motion. Fig. 13.5 plots the graph of x versus t, = 2 sin [ω (t + 2π/ω) + π/4] which gives the values of displacement as a The periodic time of the function is 2π/ω. continuous function of time. The quantities A, Reprint 2025-26 OSCILLATIONS 263 any loss of generality]. As the cosine function of time varies from +1 to –1, the displacement varies between the extremes A and – A. Two simple harmonic motions may have same ω and φ but different amplitudes A and B, as shown in Fig. 13.7 (a). While the amplitude A is fixed for a given SHM, the state of motion (position and velocity) of the particle at any time t is determined by the Fig. 13.4 The location of the particle in SHM at the discrete values t = 0, T/4, T/2, 3T/4, T, 5T/4. The time after which motion repeats itself is T. T will remain fixed, no matter what location you choose as the initial (t = Fig. 13.7 (a) A plot of displacement as a function of 0) location. The speed is maximum for zero time as obtained from Eq. (14.4) with displacement (at x = 0) and zero at the φ = 0. The curves 1 and 2 are for two extremes of motion. different amplitudes A and B. ω and φ which characterize a given SHM have standard names, as summarised in Fig. 13.6. argument (ωt + φ) in the cosine function. This Let us understand these quantities. time-dependent quantity, (ωt + φ) is called the The amplitutde A of SHM is the magnitude phase of the motion. The value of plase at t = 0 of maximum displacement of the particle. is φ and is called the phase constant (or phase [Note, A can be taken to be positive without angle). If the amplitude is known, φ can be determined from the displacement at t = 0. Two simple harmonic motions may have the same A and ω but different phase angle φ, as shown in Fig. 13.7 (b). Finally, the quantity ω can be seen to be related to the period of motion T. Taking, for simplicity, φ = 0 in Eq. (13.4), we have Fig. 13.5 Displacement as a continuous function of time for simple harmonic motion. x (t) : displacement x as a function of time t A : amplitude ω : angular frequency ωt + φ : phase (time-dependent) φ : phase constant Fig. 13.7 (b) A plot obtained from Eq. (13.4). The curves 3 and 4 are for φ = 0 and -π/4 respectively. The amplitude A is same for Fig. 13.6 The meaning of standard symbols both the plots. in Eq. (13.4) Reprint 2025-26 264 PHYSICS x(t) = A cos ωt (13.5) This function represents a simple harmonic motion having a period T = 2π/ω and a Since the motion has a period T, x (t) is equal to phase angle (–π/4) or (7π/4) x (t + T). That is, (b) sin2 ωt = ½ – ½ cos 2 ωt A cos ωt = A cos ω (t + T ) (13.6) The function is periodic having a period Now the cosine function is periodic with period T = π/ω. It also represents a harmonic 2π, i.e., it first repeats itself when the argument motion with the point of equilibrium ½ instead of zero. ⊳changes by 2π. Therefore, occurring at ω(t + T ) = ωt + 2π 13.4 SIMPLE HARMONIC MOTION AND UNIFORM CIRCULAR MOTION that is ω = 2π/ T (13.7) In this section, we show that the projection of uniform circular motion on a diameter of the ω is called the angular frequency of SHM. Its circle follows simple harmonic motion. A S.I. unit is radians per second. Since the simple experiment (Fig. 13.9) helps us visualise frequency of oscillations is simply 1/T, ω is 2π this connection. Tie a ball to the end of a string times the frequency of oscillation. Two simple and make it move in a horizontal plane about harmonic motions may have the same A and φ, a fixed point with a constant angular speed. but different ω, as seen in Fig. 13.8. In this plot The ball would then perform a uniform circular the curve (b) has half the period and twice the motion in the horizontal plane. Observe the frequency of the curve (a). ball sideways or from the front, fixing your attention in the plane of motion. The ball will appear to execute to and fro motion along a horizontal line with the point of rotation as the midpoint. You could alternatively observe the shadow of the ball on a wall which is perpendicular to the plane of the circle. In this process what we are observing is the motion of the ball on a diameter of the circle normal to the direction of viewing. Fig. 13.8 Plots of Eq. (13.4) for φ = 0 for two different periods. u Example 13.3 Which of the following functions of time represent (a) simple Fig. 13.9 Circular motion of a ball in a plane viewed harmonic motion and (b) periodic but not edge-on is SHM. simple harmonic? Give the period for each case. Fig. 13.10 describes the same situation (1) sin ωt – cos ωt mathematically. Suppose a particle P is moving (2) sin2 ωt uniformly on a circle of radius A with angular Answer speed ω. The sense of rotation is anticlockwise. (a) sin ωt – cos ωt The initial position vector of the particle, i.e., = sin ωt – sin (π/2 – ωt) the vector OP at t = 0 makes an angle of φ with = 2 cos (π/4) sin (ωt – π/4) the positive direction of x-axis. In time t, it will = √2 sin (ωt – π/4) cover a further angle ωt and its position vector Reprint 2025-26 OSCILLATIONS 265 u Example 13.4 The figure given below depicts two circular motions. The radius of the circle, the period of revolution, the initial position and the sense of revolution are indicated in the figures. Obtain the simple harmonic motions of the x-projection of the radius vector of the rotating particle P in each case. Fig. 13.10 will make an angle of ωt + φ with the +ve x-axis. Next, consider the projection of the position vector OP on the x-axis. This will be Answer OP′. The position of P′ on the x-axis, as the (a) At t = 0, OP makes an angle of 45o = π/4 rad particle P moves on the circle, is given by with the (positive direction of) x-axis. After x(t) = A cos (ωt + φ ) 2 π time t, it covers an angle t in thewhich is the defining equation of SHM. This T shows that if P moves uniformly on a circle, anticlockwise sense, and makes an angle its projection P′ on a diameter of the circle executes SHM. The particle P and the circle of 2 πt + π with the x-axis. on which it moves are sometimes referred to T 4 as the reference particle and the reference circle, The projection of OP on the x-axis at time t respectively. is given by, We can take projection of the motion of P on any diameter, say the y-axis. In that case, the  2π π  x (t) = A cos t +displacement y(t) of P′ on the y-axis is given by  T 4  y = A sin (ωt + φ) For T = 4 s, which is also an SHM of the same amplitude as that of the projection on x-axis, but differing  2π π  x(t) = A cos t +by a phase of π/2.  4 4  In spite of this connection between circular motion and SHM, the force acting on a particle which is a SHM of amplitude A, period 4 s, in linear simple harmonic motion is very πdifferent from the centripetal force needed to and an initial phase* = . keep a particle in uniform circular motion. 4 * The natural unit of angle is radian, defined through the ratio of arc to radius. Angle is a dimensionless quantity. Therefore it is not always necessary to mention the unit ‘radian’ when we use π, its multiples or submultiples. The conversion between radian and degree is not similar to that between metre and centimetre or mile. If the argument of a trigonometric function is stated without units, it is understood that the unit is radian. On the other hand, if degree is to be used as the unit of angle, then it must be shown explicitly. For example, sin(150) means sine of 15 degree, but sin(15) means sine of 15 radians. Hereafter, we will often drop ‘rad’ as the unit, and it should be understood that whenever angle is mentioned as a numerical value, without units, it is to be taken as radians. Reprint 2025-26 266 PHYSICS (b) In this case at t = 0, OP makes an angle of where the negative sign shows that v (t) has a π direction opposite to the positive direction of 90o = with the x-axis. After a time t, it x-axis. Eq. (13.9) gives the instantaneous 2 2π velocity of a particle executing SHM, where covers an angle of t in the clockwise T displacement is given by Eq. (13.4). We can, of  π 2π  course, obtain this equation without using sense and makes an angle of  2 − T t  geometrical argument, directly by differentiating (Eq. 13.4) with respect of t: with the x-axis. The projection of OP on the x-axis at time t is given by d v(t) = x (t ) (13.10)  π 2π  d t x(t) = B cos  2 − T t  The method of reference circle can be similarly used for obtaining instantaneous acceleration  2π  of a particle undergoing SHM. We know that the = B sin  T t  centripetal acceleration of a particle P in uniform For T = 30 s, circular motion has a magnitude v2/A or ω2A, and it is directed towards the centre i.e., the  π  direction is along PO. The instantaneous x(t) = B sin  15 t  acceleration of the projection particle P′ is then (See Fig. 13.12)  π π  a (t) = –ω2A cos (ωt + φ) Writing this as x (t) = B cos  15 t − 2 , and comparing with Eq. (13.4). We find that this = –ω2x (t) (13.11) represents a SHM of amplitude B, period 30 s, π and an initial phase of − . ⊳ 2