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ChemistryMediumMCQ2018 Β· 16 Apr Online

Q56.Which of the following compounds will most readily be dehydrated to give alkene under acidic condition? (1) 4 - Hydroxypentan - 2-one (2) 3- Hydroxypentan-2-one (3) 1-Pentanol (4) 2-Hydroxycyclopentanone

What This Question Tests

This question assesses the ease of acid-catalyzed dehydration. The stability of the carbocation intermediate formed determines the reaction rate. 4-Hydroxypentan-2-one can form a stable tertiary carbocation, leading to the most facile dehydration.

Concepts Tested

Acid-catalyzed dehydrationCarbocation stabilitySaytzeff's rule vs. regioselectivity in cyclic systems

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