Q46.Two statements are given belwo : Statement I : The melting point of monocarboxylic acid with even number of carbon atoms is higher than that of with odd number of carbon atoms acid immediately below and above it in the series. Statement II : The solubility of monocarboxylic acids in water decreases with increase in molar mass. Choose the most appropriate option : (1) Both Statement I and Statement II are correct. (2) Both Statement I and Statement II are incorrect. (3) Statement I is correct but Statement II is (4) Statement I is incorrect but Statement II is incorrect. correct.
What This Question Tests
This question assesses understanding of physical properties of monocarboxylic acids, specifically trends in melting points (alternation effect) and solubility in water with increasing molar mass.
Concepts Tested
📚 NCERT Sections This Tests
1.31 — The Depression In Freezing Point Of Water Observed For The Same Amount Of
Chemistry Class 11 · Chapter 1
1.31 The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above. Explain briefly.
1.23 — Suggest The Most Important Type Of Intermolecular Attractive Interaction In
Chemistry Class 11 · Chapter 1
1.23 Suggest the most important type of intermolecular attractive interaction in the following pairs. (i) n-hexane and n-octane (ii) I2 and CCl4 (iii) NaClO4 and water (iv) methanol and acetone (v) acetonitrile (CH3CN) and acetone (C3H6O). 1.24 Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain. Cyclohexane, KCl, CH3OH, CH3CN.
1.32 — Calculate The Depression In The Freezing Point Of Water When 10 G Of
Chemistry Class 11 · Chapter 1
1.32 Calculate the depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to 250 g of water. Ka = 1.4 × 10–3, Kf = 1.86 K kg mol–1. 1.33 19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing point of water observed is 1.00 C. Calculate the van’t Hoff factor and dissociation constant of fluoroacetic acid.
📋 Question Details
- Chapter
- Thermodynamics & Thermochemistry
- Topic
- Properties of Carboxylic Acids
- Year
- 2022
- Shift
- 24 Jun Shift 1
- Q Number
- Q46
- Type
- Assertion Reasoning
- NCERT Ref
- Class 12 Chemistry Ch 12: Aldehydes Ketones Carboxylic Acids
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