Q56.The cell potential for ZnZn2 + (aq)‖Snx + Sn is 0 . 801V at 298 K. The reaction quotient for the above reaction is 10-2. The number of electrons involved in the given electrochemical cell reaction is _____ . 0 0 2 . 303RT = + 0 . 008 V and = 0 . 06 V) = - 0 . 763 V, ESnx + | Sn (Given EZn2 + ∣Zn F
What This Question Tests
This question requires the application of the Nernst equation to determine the number of electrons involved (n) in an electrochemical cell reaction, given the cell potential, standard electrode potentials, and the reaction quotient.
Concepts Tested
Formulas Used
E_cell = E°_cell - (0.0592/n) log Q
E°_cell = E°_cathode - E°_anode
📚 NCERT Sections This Tests
2.4 — Calculate The Standard Cell Potentials Of Galvanic Cell In Which The Following
Chemistry Class 11 · Chapter 2
2.4 Calculate the standard cell potentials of galvanic cell in which the following reactions take place: (i) 2Cr(s) + 3Cd2+(aq) ® 2Cr3+(aq) + 3Cd (ii) Fe2+(aq) + Ag+(aq) ® Fe3+(aq) + Ag(s) Calculate the DrGo and equilibrium constant of the reactions. 2.5 Write the Nernst equation and emf of the following cells at 298 K: (i) Mg(s)|Mg2+(0.001M)||Cu2+(0.0001 M)|Cu(s) (ii) Fe(s)|Fe2+(0.001M)||H+(1M)|H2(g)(1bar)| Pt(s) (iii) Sn(s)|Sn2+(0.050 M)||H+(0.020 M)|H2(g) (1 bar)|Pt(s) (iv) Pt(s)|Br–(0.010 M)|Br2(l )||H+(0.030 M)| H2(g) (1 bar)|Pt(s).
2.6 — In The Button Cells Widely Used In Watches And Other Devices The Following
Chemistry Class 11 · Chapter 2
2.6 In the button cells widely used in watches and other devices the following reaction takes place: Zn(s) + Ag2O(s) + H2O(l) ® Zn2+(aq) + 2Ag(s) + 2OH–(aq) Determine DrGo and Eo for the reaction.
2.3 — Depict The Galvanic Cell In Which The Reaction
Chemistry Class 11 · Chapter 2
2.3 Depict the galvanic cell in which the reaction Zn(s)+2Ag+(aq) ®Zn2+(aq)+2Ag(s) takes place. Further show: (i) Which of the electrode is negatively charged? (ii) The carriers of the current in the cell. (iii) Individual reaction at each electrode.
📋 Question Details
- Chapter
- Electrochemistry
- Topic
- Nernst Equation
- Year
- 2022
- Shift
- 25 Jul Shift 1
- Q Number
- Q56
- Type
- Numerical
- NCERT Ref
- Class 12 Chemistry Ch 3: Electrochemistry
More from this Chapter
Q58.The mass of product liberated on anode in an electrochemical cell depends on (where t is the time period, for which the current is passed) (1) (It)1/2 (2) IT (3) I/t (4) I2t
Q48.The negative Zn pole of a Daniell cell, sending a constant current through a circuit, decreases in mass by 0.13 g in 30 minutes. If the electrochemical equivalent of Zn and Cu are 32.5 and 31.5 respectively, the increase in the mass of the positive Cu pole in this time is (1) 0.180 g (2) 0.141 g (3) 0.126 g (4) 0.242 g
Q49.The electrochemical equivalent of a metal is 3.3 × 10−7 kg per coulomb. The mass of the metal liberated at the cathode when a 3 A current is passed for 2 seconds will be (1) 19.8 × 10−7 kg (2) 9.9 × 10−7 kg (3) 6.6 × 10−7 kg (4) 1.1 × 10−7 kg
Q46.Two voltameters one of copper and another of silver, are joined in parallel. When a total charge q flows through the voltameters, equal amount of metals are deposited. If the electrochemical equivalents of copper and silver are z1 and z2 respectively the charge which flows through the silver voltameter is (1) q z1 (2) q z2 1+ 1+ z2 z1 (3) q z1 (4) q z2 z2 z1