Q47.For a reaction X + Y = 2Z, 1. 0 mol of X, 1. 5 mol of Y and 0. 5 mol of Z were taken in a 1L vessel and allowed to react. At equilibrium, the concentration of Z was 1. 0 molL−1. the equilibrium constant of the reaction is … … … … 15x . The value of x is … … .
What This Question Tests
This question requires setting up an ICE (Initial, Change, Equilibrium) table to find equilibrium concentrations of all species given initial amounts and one equilibrium concentration, and then calculating the equilibrium constant.
Concepts Tested
Formulas Used
Kc = [Z]² / ([X][Y])
📚 NCERT Sections This Tests
3.10 — In A Reaction Between A And B, The Initial Rate Of Reaction (R0) Was Measured
Chemistry Class 11 · Chapter 3
3.10 In a reaction between A and B, the initial rate of reaction (r0) was measured for different initial concentrations of A and B as given below: A/ mol L–1 0.20 0.20 0.40 B/ mol L–1 0.30 0.10 0.05 r0/mol L–1s–1 5.07 × 10–5 5.07 × 10–5 1.43 × 10–4 What is the order of the reaction with respect to A and B? 3.11 The following results have been obtained during the kinetic studies of the reaction: 2A + B ® C + D Experiment [A]/mol L–1 [B]/mol L–1 Initial rate of formation of D/mol L–1 min–1 I 0.1 0.1 6.0 × 10–3 II 0.3 0.2 7.2 × 10–2 III 0.3 0.4 2.88 × 10–1 IV 0.4 0.1 2.40 × 10–2 Determine the rate law and the rate constant for the reaction. 3.12 The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table: Experiment [A]/ mol L–1 [B]/ mol L–1 Initial rate/ mol L–1 min–1 I 0.1 0.1 2.0 × 10–2 II – 0.2 4.0 × 10–2 III 0.4 0.4 – IV – 0.2 2.0 × 10–2 3.13 Calculate the half-life of a first order reaction from their rate constants given below: (i) 200 s–1 (ii) 2 min–1 (iii) 4 years–1 3.14 The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample. 3.15 The experimental data for decomposition of N2O5 [2N2O5 ® 4NO2 + O2] in gas phase at 318K are given below: t/s 0 400 800 1200 1600 2000 2400 2800 3200 102 × [N2O5]/ 1.63 1.36 1.14 0.93 0.78 0.64 0.53 0.43 0.35 mol L–1 (i) Plot [N2O5] against t. (ii) Find the half-life period for the reaction. (iii) Draw a graph between log[N2O5] and t. (iv) What is the rate law ? Chemistry 86 Reprint 2025-26 (v) Calculate the rate constant. (vi) Calculate the half-life period from k and compare it with (ii).
3.24 — Consider A Certain Reaction A ® Products With K = 2.0 × 10 –2S–1. Calculate
Chemistry Class 11 · Chapter 3
3.24 Consider a certain reaction A ® Products with k = 2.0 × 10 –2s–1. Calculate the concentration of A remaining after 100 s if the initial concentration of A is 1.0 mol L–1.
1.27 — If The Solubility Product Of Cus Is 6 × 10–16, Calculate The Maximum Molarity Of
Chemistry Class 11 · Chapter 1
1.27 If the solubility product of CuS is 6 × 10–16, calculate the maximum molarity of CuS in aqueous solution.
📋 Question Details
- Chapter
- Chemical Equilibrium
- Topic
- Equilibrium constant calculation
- Year
- 2020
- Shift
- 05 Sep Shift 2
- Q Number
- Q47
- Type
- Numerical
- NCERT Ref
- Class 11 Chemistry Ch 7: Equilibrium
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