1.14 APPLICATIONS OF GAUSS’S LAW The electric field due to a general charge distribution is, as seen above, given by Eq. (1.27). In practice, except for some special cases, the summation (or integration) involved in this equation cannot be carried out to give electric field at every point in space. For some symmetric charge configurations, however, it is possible to obtain the electric field in a simple way using the Gauss’s law. This is best understood by some examples. 1.14.1 Field due to an infinitely long straight uniformly charged wire Consider an infinitely long thin straight wire with uniform linear charge density l. The wire is obviously an axis of symmetry. Suppose we take the radial vector from O to P and rotate it around the wire. The points P, P¢, P¢¢ so obtained are completely equivalent with respect to the charged wire. This implies that the electric field must have the same magnitude at these points. The direction of electric field at every point must be radial (outward if l > 0, inward if l < 0). This is clear from Fig. 1.26. Consider a pair of line elements P1 and P2 of the wire, as shown. The electric fields produced by the two elements of the pair when summed give a resultant electric field which is radial (the components normal to the radial vector cancel). This is true for any such pair and hence the total field at any point P is radial. Finally, since the wire is infinite, electric field does not depend on the position of P along the length of the wire. In short, the electric field is everywhere radial in the plane cutting the wire normally, and its magnitude depends only on the radial distance r. To calculate the field, imagine a cylindrical Gaussian surface, as shown in the Fig. 1.26(b). Since the field is everywhere radial, flux through the two ends of the cylindrical Gaussian surface is zero. At the cylindrical FIGURE 1.26 (a) Electric field due to an part of the surface, E is normal to the surface infinitely long thin straight wire is radial, at every point, and its magnitude is constant, (b) The Gaussian surface for a long thin since it depends only on r. The surface area wire of uniform linear charge density. of the curved part is 2prl, where l is the length of the cylinder. 33 Reprint 2025-26 Physics Flux through the Gaussian surface = flux through the curved cylindrical part of the surface = E × 2prl The surface includes charge equal to l l. Gauss’s law then gives E × 2prl = ll/e0 λ i.e.,E = 2 πε0r Vectorially, E at any point is given by λ E = nˆ (1.32) 2 πε0r where ˆn is the radial unit vector in the plane normal to the wire passing through the point. E is directed outward if l is positive and inward if l is negative. Note that when we write a vector A as a scalar multiplied by a unit vector, i.e., as A = A ˆa , the scalar A is an algebraic number. It can be negative or positive. The direction of A will be the same as that of the unit vector ˆa if A > 0 and opposite to ˆa if A < 0. When we want to restrict to non-negative values, we use the symbol A and call it the modulus of A. Thus, A ≥ 0 . Also note that though only the charge enclosed by the surface (ll) was included above, the electric field E is due to the charge on the entire wire. Further, the assumption that the wire is infinitely long is crucial. Without this assumption, we cannot take E to be normal to the curved part of the cylindrical Gaussian surface. However, Eq. (1.32) is approximately true for electric field around the central portions of a long wire, where the end effects may be ignored. 1.14.2 Field due to a uniformly charged infinite plane sheet Let s be the uniform surface charge density of an infinite plane sheet (Fig. 1.27). We take the x-axis normal to the given plane. By symmetry, the electric field will not depend on y and z coordinates and its direction at every point must be parallel to the x-direction. We can take the Gaussian surface to be a rectangular parallelepiped of cross-sectional area A, as shown. (A cylindrical surface will also do.) As seen from the figure, only the two faces 1 and 2 will contribute to the flux; electric field lines are parallel to the other faces and they, therefore, do not contribute to the total flux. The unit vector normal to surface 1 is in –x direction while the unit vector normal to surface 2 is in the +x direction. Therefore, flux E.DS through both the surfaces are equal and add up. Therefore FIGURE 1.27 Gaussian surface for a the net flux through the Gaussian surface is 2 EA. uniformly charged infinite plane sheet. The charge enclosed by the closed surface is sA. 34 Therefore by Gauss’s law, Reprint 2025-26 Electric Charges and Fields 2 EA = sA/e0 or, E = s/2e0 Vectorically, σ E = nˆ (1.33) 2ε0 where ˆn is a unit vector normal to the plane and going away from it. E is directed away from the plate if s is positive and toward the plate if s is negative. Note that the above application of the Gauss’ law has brought out an additional fact: E is independent of x also. For a finite large planar sheet, Eq. (1.33) is approximately true in the middle regions of the planar sheet, away from the ends. 1.14.3 Field due to a uniformly charged thin spherical shell Let s be the uniform surface charge density of a thin spherical shell of radius R (Fig. 1.28). The situation has obvious spherical symmetry. The field at any point P, outside or inside, can depend only on r (the radial distance from the centre of the shell to the point) and must be radial (i.e., along the radius vector). (i) Field outside the shell: Consider a point P outside the shell with radius vector r. To calculate E at P, we take the Gaussian surface to be a sphere of radius r and with centre O, passing through P. All points on this sphere are equivalent relative to the given charged configuration. (That is what we mean by spherical symmetry.) The electric field at each point of the Gaussian surface, therefore, has the same magnitude E and is along the radius vector at each point. Thus, E and DS at every point are parallel and the flux through each element is E DS. Summing over all DS, the flux through the Gaussian surface is E × 4 p r 2. The charge enclosed is s × 4 p R 2. By Gauss’s law σ 2 E × 4 p r 2 = 4 π R ε0 σ R 2 q Or, E = 2 = 2 ε0 r 4 π ε0 r where q = 4 p R2 s is the total charge on the spherical shell. Vectorially, q FIGURE 1.28 Gaussian E = 2 rˆ (1.34) 4 πε0 r surfaces for a point with (a) r > R, (b) r < R. The electric field is directed outward if q > 0 and inward if q < 0. This, however, is exactly the field produced by a charge q placed at the centre O. Thus for points outside the shell, the field due to a uniformly charged shell is as if the entire charge of the shell is concentrated at its centre. (ii) Field inside the shell: In Fig. 1.28(b), the point P is inside the shell. The Gaussian surface is again a sphere through P centred at O. 35 Reprint 2025-26 Physics The flux through the Gaussian surface, calculated as before, is E × 4 p r2. However, in this case, the Gaussian surface encloses no charge. Gauss’s law then gives E × 4 p r2 = 0 i.e., E = 0 (r < R ) (1.35) that is, the field due to a uniformly charged thin shell is zero at all points inside the shell*. This important result is a direct consequence of Gauss’s law which follows from Coulomb’s law. The experimental verification of this result confirms the 1/r2 dependence in Coulomb’s law. Example 1.12 An early model for an atom considered it to have a positively charged point nucleus of charge Ze, surrounded by a uniform density of negative charge up to a radius R. The atom as a whole is neutral. For this model, what is the electric field at a distance r from the nucleus? FIGURE 1.29 Solution The charge distribution for this model of the atom is as shown in Fig. 1.29. The total negative charge in the uniform spherical charge distribution of radius R must be –Z e, since the atom (nucleus of charge Z e + negative charge) is neutral. This immediately gives us the negative charge density r, since we must have 4 π R 3 ρ= 0– Ze 3 3 Ze or ρ= − 3 4 π R To find the electric field E(r) at a point P which is a distance r away from the nucleus, we use Gauss’s law. Because of the spherical symmetry of the charge distribution, the magnitude of the electric field E(r) depends only on the radial distance, no matter what the direction of r. Its direction is along (or opposite to) the radius vector r from the origin to the point P. The obvious Gaussian surface is a spherical surface centred at the nucleus. We consider two situations, 1.12 namely, r < R and r > R. (i) r < R : The electric flux f enclosed by the spherical surface is f = E (r) × 4 p r 2 EXAMPLE * Compare this with a uniform mass shell discussed in Section 7.5 of Class XI 36 Textbook of Physics. Reprint 2025-26 Electric Charges and Fields where E (r) is the magnitude of the electric field at r. This is because the field at any point on the spherical Gaussian surface has the same direction as the normal to the surface there, and has the same magnitude at all points on the surface. The charge q enclosed by the Gaussian surface is the positive nuclear charge and the negative charge within the sphere of radius r, 4 π r 3 i.e., q = Z e + ρ 3 Substituting for the charge density r obtained earlier, we have r 3 q = Z e − Z e 3 R Gauss’s law then gives, Z e 1 r E (r ) = 2 − 3 ; r < R 4 π ε0 r R The electric field is directed radially outward. (ii) r > R: In this case, the total charge enclosed by the Gaussian spherical surface is zero since the atom is neutral. Thus, from Gauss’s law, EXAMPLE E (r) × 4 p r 2 = 0 or E (r) = 0; r > R At r = R, both cases give the same result: E = 0. 1.12 SUMMARY 1. Electric and magnetic forces determine the properties of atoms, molecules and bulk matter. 2. From simple experiments on frictional electricity, one can infer that there are two types of charges in nature; and that like charges repel and unlike charges attract. By convention, the charge on a glass rod rubbed with silk is positive; that on a plastic rod rubbed with fur is then negative. 3. Conductors allow movement of electric charge through them, insulators do not. In metals, the mobile charges are electrons; in electrolytes both positive and negative ions are mobile. 4. Electric charge has three basic properties: quantisation, additivity and conservation. Quantisation of electric charge means that total charge (q) of a body is always an integral multiple of a basic quantum of charge (e) i.e., q = n e, where n = 0, ±1, ±2, ±3, .... Proton and electron have charges +e, –e, respectively. For macroscopic charges for which n is a very large number, quantisation of charge can be ignored. Additivity of electric charges means that the total charge of a system is the algebraic sum (i.e., the sum taking into account proper signs) of all individual charges in the system. Conservation of electric charges means that the total charge of an isolated system remains unchanged with time. This means that when 37 Reprint 2025-26 Physics bodies are charged through friction, there is a transfer of electric charge from one body to another, but no creation or destruction of charge. 5. Coulomb’s Law: The mutual electrostatic force between two point charges q1 and q2 is proportional to the product q1q2 and inversely proportional to the square of the distance r21 separating them. Mathematically, k (q1q 2 ) F21 = force on q2 due to q1 = 2 rˆ21 r21 1 where ˆr21 is a unit vector in the direction from q1 to q2 and k = 4 πε0 is the constant of proportionality. In SI units, the unit of charge is coulomb. The experimental value of the constant e0 is e0 = 8.854 × 10–12 C2 N–1 m–2 The approximate value of k is k = 9 × 109 N m2 C–2 6. The ratio of electric force and gravitational force between a proton and an electron is k e 2 39 ≅ 2 . 4 × 10 G m e m p 7. Superposition Principle: The principle is based on the property that the forces with which two charges attract or repel each other are not affected by the presence of a third (or more) additional charge(s). For an assembly of charges q1, q2, q3, ..., the force on any charge, say q1, is the vector sum of the force on q1 due to q2, the force on q1 due to q3, and so on. For each pair, the force is given by the Coulomb’s law for two charges stated earlier. 8. The electric field E at a point due to a charge configuration is the force on a small positive test charge q placed at the point divided by the magnitude of the charge. Electric field due to a point charge q has a magnitude |q|/4pe0r2; it is radially outwards from q, if q is positive, and radially inwards if q is negative. Like Coulomb force, electric field also satisfies superposition principle. 9. An electric field line is a curve drawn in such a way that the tangent at each point on the curve gives the direction of electric field at that point. The relative closeness of field lines indicates the relative strength of electric field at different points; they crowd near each other in regions of strong electric field and are far apart where the electric field is weak. In regions of constant electric field, the field lines are uniformly spaced parallel straight lines. 10. Some of the important properties of field lines are: (i) Field lines are continuous curves without any breaks. (ii) Two field lines cannot cross each other. (iii) Electrostatic field lines start at positive charges and end at negative charges —they cannot form closed loops. 11. An electric dipole is a pair of equal and opposite charges q and –q separated by some distance 2a. Its dipole moment vector p has magnitude 2qa and is in the direction of the dipole axis from –q to q. Reprint 2025-26 Electric Charges and Fields 12. Field of an electric dipole in its equatorial plane (i.e., the plane perpendicular to its axis and passing through its centre) at a distance r from the centre: − p 1 E = 2 2 3/2 4 πεo (a + r ) − p ≅ 3 , for r >> a 4 πεo r Dipole electric field on the axis at a distance r from the centre: 2 p r E = 2 2 2 4 πε0 (r − a ) 2 p ≅ 3 for r >> a 4 πε0 r The 1/r3 dependence of dipole electric fields should be noted in contrast to the 1/r 2 dependence of electric field due to a point charge. 13. In a uniform electric field E, a dipole experiences a torque τ given by τ = p × E but experiences no net force. 14. The flux Df of electric field E through a small area element DS is given by Df = E.DS The vector area element DS is DS = DS ˆn where DS is the magnitude of the area element and ˆn is normal to the area element, which can be considered planar for sufficiently small DS. For an area element of a closed surface, ˆn is taken to be the direction of outward normal, by convention. 15. Gauss’s law: The flux of electric field through any closed surface S is 1/e0 times the total charge enclosed by S. The law is especially useful in determining electric field E, when the source distribution has simple symmetry: (i) Thin infinitely long straight wire of uniform linear charge density l λ E = nˆ 2 πε0 r where r is the perpendicular distance of the point from the wire and ˆn is the radial unit vector in the plane normal to the wire passing through the point. (ii) Infinite thin plane sheet of uniform surface charge density s σ E = nˆ 2 ε0 where ˆn is a unit vector normal to the plane, outward on either side. 39 Reprint 2025-26 Physics (iii) Thin spherical shell of uniform surface charge density s q E = 2 rˆ (r ≥ R ) 4 πε0 r E = 0 (r < R) where r is the distance of the point from the centre of the shell and R the radius of the shell. q is the total charge of the shell: q = 4pR2s. The electric field outside the shell is as though the total charge is concentrated at the centre. The same result is true for a solid sphere of uniform volume charge density. The field is zero at all points inside the shell. Physical quantity Symbol Dimensions Unit Remarks Vector area element D S [L2] m2 DS = DS ˆn Electric field E [MLT–3A–1] V m–1 Electric flux f [ML3 T–3A–1] V m Df = E.DS Dipole moment p [LTA] C m Vector directed from negative to positive charge Charge density: linear l [L–1 TA] C m–1 Charge/length surface s [L–2 TA] C m–2 Charge/area volume r [L–3 TA] C m–3 Charge/volume POINTS TO PONDER 1. You might wonder why the protons, all carrying positive charges, are compactly residing inside the nucleus. Why do they not fly away? You will learn that there is a third kind of a fundamental force, called the strong force which holds them together. The range of distance where this force is effective is, however, very small ~10-14 m. This is precisely the size of the nucleus. Also the electrons are not allowed to sit on top of the protons, i.e. inside the nucleus, due to the laws of quantum mechanics. This gives the atoms their structure as they exist in nature. 2. Coulomb force and gravitational force follow the same inverse-square law. But gravitational force has only one sign (always attractive), while Reprint 2025-26 Electric Charges and Fields Coulomb force can be of both signs (attractive and repulsive), allowing possibility of cancellation of electric forces. This is how gravity, despite being a much weaker force, can be a dominating and more pervasive force in nature. 3. The constant of proportionality k in Coulomb’s law is a matter of choice if the unit of charge is to be defined using Coulomb’s law. In SI units, however, what is defined is the unit of current (A) via its magnetic effect (Ampere’s law) and the unit of charge (coulomb) is simply defined by (1C = 1 A s). In this case, the value of k is no longer arbitrary; it is approximately 9 × 109 N m2 C–2. 4. The rather large value of k, i.e., the large size of the unit of charge (1C) from the point of view of electric effects arises because (as mentioned in point 3 already) the unit of charge is defined in terms of magnetic forces (forces on current–carrying wires) which are generally much weaker than the electric forces. Thus while 1 ampere is a unit of reasonable size for magnetic effects, 1 C = 1 A s, is too big a unit for electric effects. 5. The additive property of charge is not an ‘obvious’ property. It is related to the fact that electric charge has no direction associated with it; charge is a scalar. 6. Charge is not only a scalar (or invariant) under rotation; it is also invariant for frames of reference in relative motion. This is not always true for every scalar. For example, kinetic energy is a scalar under rotation, but is not invariant for frames of reference in relative motion. 7. Conservation of total charge of an isolated system is a property independent of the scalar nature of charge noted in point 6. Conservation refers to invariance in time in a given frame of reference. A quantity may be scalar but not conserved (like kinetic energy in an inelastic collision). On the other hand, one can have conserved vector quantity (e.g., angular momentum of an isolated system). 8. Quantisation of electric charge is a basic (unexplained) law of nature; interestingly, there is no analogous law on quantisation of mass. 9. Superposition principle should not be regarded as ‘obvious’, or equated with the law of addition of vectors. It says two things: force on one charge due to another charge is unaffected by the presence of other charges, and there are no additional three-body, four-body, etc., forces which arise only when there are more than two charges. 10. The electric field due to a discrete charge configuration is not defined at the locations of the discrete charges. For continuous volume charge distribution, it is defined at any point in the distribution. For a surface charge distribution, electric field is discontinuous across the surface. 11. The electric field due to a charge configuration with total charge zero is not zero; but for distances large compared to the size of the configuration, its field falls off faster than 1/r 2, typical of field due to a single charge. An electric dipole is the simplest example of this fact. 41 Reprint 2025-26 Physics EXERCISES 1.1 What is the force between two small charged spheres having charges of 2 × 10–7C and 3 × 10–7C placed 30 cm apart in air? 1.2 The electrostatic force on a small sphere of charge 0.4 mC due to another small sphere of charge –0.8 mC in air is 0.2 N. (a) What is the distance between the two spheres? (b) What is the force on the second sphere due to the first? 1.3 Check that the ratio ke2/G memp is dimensionless. Look up a Table of Physical Constants and determine the value of this ratio. What does the ratio signify? 1.4 (a) Explain the meaning of the statement ‘electric charge of a body is quantised’. (b) Why can one ignore quantisation of electric charge when dealing with macroscopic i.e., large scale charges? 1.5 When a glass rod is rubbed with a silk cloth, charges appear on both. A similar phenomenon is observed with many other pairs of bodies. Explain how this observation is consistent with the law of conservation of charge. 1.6 Four point charges qA = 2 mC, qB = –5 mC, qC = 2 mC, and qD = –5 mC are located at the corners of a square ABCD of side 10 cm. What is the force on a charge of 1 mC placed at the centre of the square? 1.7 (a) An electrostatic field line is a continuous curve. That is, a field line cannot have sudden breaks. Why not? (b) Explain why two field lines never cross each other at any point? 1.8 Two point charges qA = 3 mC and qB = –3 mC are located 20 cm apart in vacuum. (a) What is the electric field at the midpoint O of the line AB joining the two charges? (b) If a negative test charge of magnitude 1.5 × 10–9 C is placed at this point, what is the force experienced by the test charge? 1.9 A system has two charges qA = 2.5 × 10–7 C and qB = –2.5 × 10–7 C located at points A: (0, 0, –15 cm) and B: (0,0, +15 cm), respectively. What are the total charge and electric dipole moment of the system? 1.10 An electric dipole with dipole moment 4 × 10–9 C m is aligned at 30° with the direction of a uniform electric field of magnitude 5 × 104 NC–1. Calculate the magnitude of the torque acting on the dipole. 1.11 A polythene piece rubbed with wool is found to have a negative charge of 3 × 10–7 C. (a) Estimate the number of electrons transferred (from which to which?) (b) Is there a transfer of mass from wool to polythene? 1.12 (a) Two insulated charged copper spheres A and B have their centres separated by a distance of 50 cm. What is the mutual force of electrostatic repulsion if the charge on each is 6.5 × 10–7 C? The radii of A and B are negligible compared to the distance of separation. (b) What is the force of repulsion if each sphere is charged double the above amount, and the distance between them is halved? 1.13 Figure 1.30 shows tracks of three charged particles in a uniform electrostatic field. Give the signs of the three charges. Which particle 42 has the highest charge to mass ratio? Reprint 2025-26 Electric Charges and Fields FIGURE 1.30

2.4 A spherical conductor of radius 12 cm has a charge of 1.6 × 10–7C distributed uniformly on its surface. What is the electric field (a) inside the sphere (b) just outside the sphere (c) at a point 18 cm from the centre of the sphere?

1.20 A conducting sphere of radius 10 cm has an unknown charge. If the electric field 20 cm from the centre of the sphere is 1.5 × 103 N/C and points radially inward, what is the net charge on the sphere? 43 Reprint 2025-26 Physics 1.21 A uniformly charged conducting sphere of 2.4 m diameter has a surface charge density of 80.0 mC/m2. (a) Find the charge on the sphere. (b) What is the total electric flux leaving the surface of the sphere? 1.22 An infinite line charge produces a field of 9 × 104 N/C at a distance of 2 cm. Calculate the linear charge density. 1.23 Two large, thin metal plates are parallel and close to each other. On their inner faces, the plates have surface charge densities of opposite signs and of magnitude 17.0 × 10–22 C/m2. What is E: (a) in the outer region of the first plate, (b) in the outer region of the second plate, and (c) between the plates? Reprint 2025-26 Chapter Two ELECTROSTATIC POTENTIAL AND CAPACITANCE 2.12.12.12.12.1 IIINTRODUCTIONIINTRODUCTIONNTRODUCTIONNTRODUCTIONNTRODUCTION In Chapters 5 and 7 (Class XI), the notion of potential energy was introduced. When an external force does work in taking a body from a point to another against a force like spring force or gravitational force, that work gets stored as potential energy of the body. When the external force is removed, the body moves, gaining kinetic energy and losing an equal amount of potential energy. The sum of kinetic and potential energies is thus conserved. Forces of this kind are called conservative forces. Spring force and gravitational force are examples of conservative forces. Coulomb force between two (stationary) charges is also a conservative force. This is not surprising, since both have inverse-square dependence on distance and differ mainly in the proportionality constants – the masses in the gravitational law are replaced by charges in Coulomb’s law. Thus, like the potential energy of a mass in a gravitational field, we can define electrostatic potential energy of a charge in an electrostatic field. Consider an electrostatic field EEEEE due to some charge configuration. First, for simplicity, consider the field E due to a charge Q placed at the origin. Now, imagine that we bring a test charge q from a point R to a point P against the repulsive force on it due to the charge Q. With reference Reprint 2025-26 Physics to Fig. 2.1, this will happen if Q and q are both positive or both negative. For definiteness, let us take Q, q > 0. Two remarks may be made here. First, we assume that the test charge q is so small that it does not disturb the original configuration, namely the charge Q at the origin (or else, we keep Q fixed at the origin by some unspecified force). Second, in bringing the charge q fromFIGURE 2.1 A test charge q (> 0) is moved from the point R to the R to P, we apply an external force Fext just enough to point P against the repulsive counter the repulsive electric force FE (i.e, Fext= –FE). force on it by the charge Q (> 0) This means there is no net force on or acceleration of placed at the origin. the charge q when it is brought from R to P, i.e., it is brought with infinitesimally slow constant speed. In this situation, work done by the external force is the negative of the work done by the electric force, and gets fully stored in the form of potential energy of the charge q. If the external force is removed on reaching P, the electric force will take the charge away from Q – the stored energy (potential energy) at P is used to provide kinetic energy to the charge q in such a way that the sum of the kinetic and potential energies is conserved. Thus, work done by external forces in moving a charge q from R to P is WRP = – = (2.1) This work done is against electrostatic repulsive force and gets stored as potential energy. At every point in electric field, a particle with charge q possesses a certain electrostatic potential energy, this work done increases its potential energy by an amount equal to potential energy difference between points R and P. Thus, potential energy difference ∆U = U P − U R = W RP (2.2) (Note here that this displacement is in an opposite sense to the electric force and hence work done by electric field is negative, i.e., –WRP .) Therefore, we can define electric potential energy difference between two points as the work required to be done by an external force in moving (without accelerating) charge q from one point to another for electric field of any arbitrary charge configuration. Two important comments may be made at this stage: (i) The right side of Eq. (2.2) depends only on the initial and final positions of the charge. It means that the work done by an electrostatic field in moving a charge from one point to another depends only on the initial and the final points and is independent of the path taken to go from one point to the other. This is the fundamental characteristic of a conservative force. The concept of the potential energy would not be meaningful if the work depended on the path. The path-independence of work done by an electrostatic field can be proved using the 46 Coulomb’s law. We omit this proof here. Reprint 2025-26 Electrostatic Potential and Capacitance (ii) Equation (2.2) defines potential energy difference in terms of the physically meaningful quantity work. Clearly, potential energy so defined is undetermined to within an additive constant.What this means is that the actual value of potential energy is not physically significant; it is only the difference of potential energy that is significant. We can always add an arbitrary constant a to potential energy at every point, since this will not change the potential energy difference: (U P + α) − (U R + α) = U P − U R Put it differently, there is a freedom in choosing the point where potential energy is zero. A convenient choice is to have electrostatic potential energy zero at infinity. With this choice, if we take the point R at infinity, we get from Eq. (2.2) Count Alessandro Volta (1745 – 1827) Italian W ∞ P = U P − U ∞ = U P (2.3) physicist, professor at Since the point P is arbitrary, Eq. (2.3) provides us with a Pavia. Volta established that the animal electri- COUNTdefinition of potential energy of a charge q at any point. city observed by LuigiPotential energy of charge q at a point (in the presence of field Galvani, 1737–1798, indue to any charge configuration) is the work done by the experiments with frog external force (equal and opposite to the electric force) in muscle tissue placed in bringing the charge q from infinity to that point. contact with dissimilar metals, was not due to 2.2 ELECTROSTATIC POTENTIAL any exceptional property of animal tissues but ALESSANDROConsider any general static charge configuration. We define was also generated potential energy of a test charge q in terms of the work done whenever any wet body on the charge q. This work is obviously proportional to q, since was sandwiched between the force at any point is qE, where E is the electric field at that dissimilar metals. This VOLTA point due to the given charge configuration. It is, therefore, led him to develop the convenient to divide the work by the amount of charge q, so first voltaic pile, orthat the resulting quantity is independent of q. In other words, battery, consisting of a (1745 work done per unit test charge is characteristic of the electric large stack of moist disks of cardboard (electro-field associated with the charge configuration. This leads to lyte) sandwiched the idea of electrostatic potential V due to a given charge between disks of metal –1827) configuration. From Eq. (2.1), we get: (electrodes). Work done by external force in bringing a unit positive charge from point R to P  U P − U R  = VP – VR = (2.4)  q  where VP and VR are the electrostatic potentials at P and R, respectively. Note, as before, that it is not the actual value of potential but the potential difference that is physically significant. If, as before, we choose the potential to be zero at infinity, Eq. (2.4) implies: Work done by an external force in bringing a unit positive charge from infinity to a point = electrostatic potential (V ) at that point. 47 Reprint 2025-26 Physics In other words, the electrostatic potential (V ) at any point in a region with electrostatic field is the work done in bringing a unit positive charge (without acceleration) from infinity to that point. The qualifying remarks made earlier regarding potential energy also apply to the definition of potential. To obtain the work done per unit test charge, we should take an infinitesimal test charge FIGURE 2.2 Work done on a test charge q dq, obtain the work done dW in bringing it from by the electrostatic field due to any given infinity to the point and determine the ratio charge configuration is independent dW/dq. Also, the external force at every point of the of the path, and depends only on path is to be equal and opposite to the electrostatic its initial and final positions. force on the test charge at that point. 2.3 POTENTIAL DUE TO A POINT CHARGE Consider a point charge Q at the origin (Fig. 2.3). For definiteness, take Q to be positive. We wish to determine the potential at any point P with position vector r from the origin. For that we must calculate the work done in bringing a unit positive test charge from infinity to the point P. For Q > 0, the work done against the repulsive force on the test charge is positive. Since work done is independent of the path, we choose a convenient path – along the radial direction from infinity to the point P. At some intermediate point P¢ on the path, the electrostatic force on a unit positive charge is FIGURE 2.3 Work done in bringing a unit positive test charge from infinity to the Q × 1 rˆ ′ (2.5) point P, against the repulsive force of 2 4 πε0r ' charge Q (Q > 0), is the potential at P due to the charge Q. where ˆ′r is the unit vector along OP¢. Work done against this force from r¢ to r¢ + Dr¢ is Q ∆W = − 2 ∆′r (2.6) 4 πε0r ' The negative sign appears because for Dr¢ < 0, DW is positive. Total work done (W) by the external force is obtained by integrating Eq. (2.6) from r¢ = ¥ to r¢ = r, r Q Q r Q = dr ′ = ε 0r ′ 2 4 πε0r ′ ∞ 4 πε0r (2.7) W = − ∫4∞ π This, by definition is the potential at P due to the charge Q Q V (r ) = (2.8) 48 4 πε0r Reprint 2025-26 Electrostatic Potential and Capacitance Equation (2.8) is true for any sign of the charge Q, though we considered Q > 0 in its derivation. For Q < 0, V < 0, i.e., work done (by the external force) per unit positive test charge in bringing it from infinity to the point is negative. This is equivalent to saying that work done by the electrostatic force in bringing the unit positive charge form infinity to the point P is positive. [This is as it should be, since for Q < 0, the force on a unit positive test charge is attractive, so that the electrostatic force and the displacement (from infinity to P) are FIGURE 2.4 Variation of potential V with r [in units of in the same direction.] Finally, we (Q/4pe0) m-1] (blue curve) and field with r [in units of (Q/4pe0) m-2] (black curve) for a point charge Q.note that Eq. (2.8) is consistent with the choice that potential at infinity be zero. Figure (2.4) shows how the electrostatic potential ( 1/r) and the electrostatic field (1/r 2 ) varies with r. Example 2.1 (a) Calculate the potential at a point P due to a charge of 4 × 10–7C located 9 cm away. (b) Hence obtain the work done in bringing a charge of 2 × 10–9 C from infinity to the point P. Does the answer depend on the path along which the charge is brought? Solution (a) = 4 × 104 V (b) W = qV = 2 × 10–9C × 4 × 104V = 8 × 10–5 J No, work done will be path independent. Any arbitrary infinitesimal path can be resolved into two perpendicular displacements: One along EXAMPLE r and another perpendicular to r. The work done corresponding to the later will be zero. 2.1