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ChemistryMediumNumerical2013 · 22 Apr Online

Q47.A molecule M associates in a given solvent according to the equation M ⇌(M)n . For a certain concentration of M, the van't Hoff factor was found to be 0.9 and the fraction of associated molecules was 0.2. The value of n is: (1) 3 (2) 5 (3) 2 (4) 4

What This Question Tests

This question requires applying the formula for the van't Hoff factor in the case of molecular association to calculate the aggregation number 'n'.

Concepts Tested

Van't Hoff factor (i)Degree of association (α)Colligative properties

Formulas Used

i = 1 - α + α/n

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