Q50.Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so obtained is diazotised and then heated with cuprous bromide. The reaction mixture so formed contains (1) mixture of o− and p-bromotoluenes (2) mixture of o− and p-dibromobenzenes (3) mixture of o - and p-bromoanilines (4) mixture of 0 - and m -bromotoluenes
What This Question Tests
This question evaluates the understanding of a multi-step organic reaction sequence involving nitration, reduction of nitro groups, diazotization, and the Sandmeyer reaction for halogenation.
Concepts Tested
📚 NCERT Sections This Tests
9.8 — Accomplish The Following Conversions:
Chemistry Class 12 · Chapter 9
9.8 Accomplish the following conversions: (i) Nitrobenzene to benzoic acid (ii) Benzene to m-bromophenol (iii) Benzoic acid to aniline (iv) Aniline to 2,4,6-tribromofluorobenzene (v) Benzyl chloride to 2-phenylethanamine (vi) Chlorobenzene to p-chloroaniline (vii) Aniline to p-bromoaniline (viii) Benzamide to toluene (ix) Aniline to benzyl alcohol.
9.9 — Give The Structures Of A, B And C In The Following Reactions:
Chemistry Class 12 · Chapter 9
9.9 Give the structures of A, B and C in the following reactions: B NaOH Br 2 C (i) CH 3 CH 2 I NaCN A Partial OHhydrolysis CuCN H 2 O/H NH 3 (ii) C 6 H 5 N 2 Cl A B C 4 B HNO 2 C (iii) CH 3 CH 2 Br KCN A LiAlH 0 C 2 2 O/H HCl B H C (iv) C6 H 5 NO 2 Fe/HCl A NaNO273 K 3 A NaOBr B NaNO 2 /HCl C (v) CH 3 COOH NH 2 B C 6 H 5 OH C (vi) C6 H 5 NO 2 Fe/HCl A HNO273K 279 Amines Reprint 2025-26
6.22 — What Happens When
Chemistry Class 12 · Chapter 6
6.22 What happens when (i) n-butyl chloride is treated with alcoholic KOH, (ii) bromobenzene is treated with Mg in the presence of dry ether, (iii) chlorobenzene is subjected to hydrolysis, (iv) ethyl chloride is treated with aqueous KOH, (v) methyl bromide is treated with sodium in the presence of dry ether, (vi) methyl chloride is treated with KCN? Answers to Some Intext Questions 6.1 6.2 (i) H2SO4 cannot be used along with KI in the conversion of an alcohol to an alkyl iodide as it converts KI to corresponding acid, HI which is then oxidised by it to I2. 6.3 (i) ClCH2CH2CH2Cl (ii) ClCH2CHClCH3 (iii) Cl2CHCH2CH3 (iv) CH3CCl2CH3 191 Haloalkanes and Haloarenes Reprint 2025-26
📋 Question Details
- Chapter
- Nitrogen Compounds
- Topic
- Diazotization and Sandmeyer Reaction
- Year
- 2008
- Shift
- Unknown
- Q Number
- Q50
- Type
- Multi concept
- NCERT Ref
- Class 12 Chemistry Ch 13: Amines; Class 11 Chemistry Ch 13: Hydrocarbons; Class 12 Chemistry Ch 10: Haloalkanes and Haloarenes
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