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ChemistryHardMCQ2012 · 12 May Online

Q48.A solution containing 0.85 g of ZnCl2 in 125.0 g of water freezes at −0.23∘C. The apparent degree of dissociation of the salt is (Kf for water = 1.86 K kg mol−1 , atomic mass: Zn = 65.3 and Cl = 35.5) (1) 1.36% (2) 73.5% (3) 7.35% (4) 2.47%

What This Question Tests

This question involves calculating the degree of dissociation of an electrolyte using the colligative property of depression in freezing point, requiring calculation of molality and the Van't Hoff factor.

Concepts Tested

Depression in freezing pointMolalityVan't Hoff factor (i)Degree of dissociation

Formulas Used

ΔTf = i * Kf * m

m = moles of solute / kg of solvent

i = 1 + (n-1)α

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