3.10 In a reaction between A and B, the initial rate of reaction (r0) was measured for different initial concentrations of A and B as given below: A/ mol L–1 0.20 0.20 0.40 B/ mol L–1 0.30 0.10 0.05 r0/mol L–1s–1 5.07 × 10–5 5.07 × 10–5 1.43 × 10–4 What is the order of the reaction with respect to A and B? 3.11 The following results have been obtained during the kinetic studies of the reaction: 2A + B ® C + D Experiment [A]/mol L–1 [B]/mol L–1 Initial rate of formation of D/mol L–1 min–1 I 0.1 0.1 6.0 × 10–3 II 0.3 0.2 7.2 × 10–2 III 0.3 0.4 2.88 × 10–1 IV 0.4 0.1 2.40 × 10–2 Determine the rate law and the rate constant for the reaction. 3.12 The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table: Experiment [A]/ mol L–1 [B]/ mol L–1 Initial rate/ mol L–1 min–1 I 0.1 0.1 2.0 × 10–2 II – 0.2 4.0 × 10–2 III 0.4 0.4 – IV – 0.2 2.0 × 10–2 3.13 Calculate the half-life of a first order reaction from their rate constants given below: (i) 200 s–1 (ii) 2 min–1 (iii) 4 years–1 3.14 The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample. 3.15 The experimental data for decomposition of N2O5 [2N2O5 ® 4NO2 + O2] in gas phase at 318K are given below: t/s 0 400 800 1200 1600 2000 2400 2800 3200 102 × [N2O5]/ 1.63 1.36 1.14 0.93 0.78 0.64 0.53 0.43 0.35 mol L–1 (i) Plot [N2O5] against t. (ii) Find the half-life period for the reaction. (iii) Draw a graph between log[N2O5] and t. (iv) What is the rate law ? Chemistry 86 Reprint 2025-26 (v) Calculate the rate constant. (vi) Calculate the half-life period from k and compare it with (ii).

5.2 lists the kinetic energies for various x i objects. where the summation is from the initial position ⊳ xi to the final position xf. Example 5.4 In a ballistics demonstration a police officer fires a bullet of mass 50.0 g If the displacements are allowed to approach with speed 200 m s-1 (see Table 5.2) on soft zero, then the number of terms in the sum plywood of thickness 2.00 cm. The bullet increases without limit, but the sum approaches emerges with only 10% of its initial kinetic a definite value equal to the area under the curve energy. What is the emergent speed of the in Fig. 5.3(b). Then the work done is bullet ? xf W = lim F (x )∆xAnswer The initial kinetic energy of the bullet ∆ x → 0 ∑ x i is mv2/2 = 1000 J. It has a final kinetic energy xfof 0.1×1000 = 100 J. If vf is the emergent speed x ) d x (5.7)of the bullet, = ∫F ( i 1 2 x mv f = 100 J where ‘lim’ stands for the limit of the sum when 2 ∆x tends to zero. Thus, for a varying force 2 × 100 J the work done can be expressed as a definite v f = 0. 05 kg integral of force over displacement (see also Appendix 3.1). = 63.2 m s–1 The speed is reduced by approximately 68% (not 90%). ⊳

8.2 A parallel plate capacitor (Fig. 8.6) made of circular plates each of radius R = 6.0 cm has a capacitance C = 100 pF. The capacitor is connected to 213 a 230 V ac supply with a (angular) frequency of 300 rad s–1. Reprint 2025-26 Physics (a) What is the rms value of the conduction current? (b) Is the conduction current equal to the displacement current? (c) Determine the amplitude of B at a point 3.0 cm from the axis between the plates. FIGURE 8.6 8.3 What physical quantity is the same for X-rays of wavelength 10–10 m, red light of wavelength 6800 Å and radiowaves of wavelength 500m? 8.4 A plane electromagnetic wave travels in vacuum along z-direction. What can you say about the directions of its electric and magnetic field vectors? If the frequency of the wave is 30 MHz, what is its wavelength? 8.5 A radio can tune in to any station in the 7.5 MHz to 12 MHz band. What is the corresponding wavelength band? 8.6 A charged particle oscillates about its mean equilibrium position with a frequency of 10 9 Hz. What is the frequency of the electromagnetic waves produced by the oscillator? 8.7 The amplitude of the magnetic field part of a harmonic electromagnetic wave in vacuum is B0 = 510 nT. What is the amplitude of the electric field part of the wave? 8.8 Suppose that the electric field amplitude of an electromagnetic wave is E0 = 120 N/C and that its frequency is n = 50.0 MHz. (a) Determine, B0,w, k, and l. (b) Find expressions for E and B. 8.9 The terminology of different parts of the electromagnetic spectrum is given in the text. Use the formula E = hn (for energy of a quantum of radiation: photon) and obtain the photon energy in units of eV for different parts of the electromagnetic spectrum. In what way are the different scales of photon energies that you obtain related to the sources of electromagnetic radiation? 8.10 In a plane electromagnetic wave, the electric field oscillates sinusoidally at a frequency of 2.0 × 1010 Hz and amplitude 48 V m–1. (a) What is the wavelength of the wave? (b) What is the amplitude of the oscillating magnetic field? (c) Show that the average energy density of the E field equals the average energy density of the B field. [c = 3 × 108 m s–1.] Reprint 2025-26