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ChemistryHardNumerical2025 · 23 Jan Shift 1

Q54.The element that does not belong to the same period of the remaining elements (modern periodic table) is: 2025 (23 Jan Shift 1) JEE Main Previous Year Paper (1) Iridium (2) Platinum (3) Osmium (4) Palladium

What This Question Tests

This question tests the ability to calculate the standard electrode potential for a multi-step redox reaction by combining the ΔG° values of individual steps.

Concepts Tested

Standard electrode potentialRedox reactionsGibbs free energy change (ΔG°)Relation between ΔG° and E°

Formulas Used

ΔG° = -nFE°

ΔG°_overall = ΔG°₁ + ΔG°₂

📚 NCERT Sections This Tests

2.2Given The Standard Electrode Potentials,

Chemistry Class 11 · Chapter 2

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2.2 Given the standard electrode potentials, K+/K = –2.93V, Ag+/Ag = 0.80V, Hg2+/Hg = 0.79V Mg2+/Mg = –2.37 V, Cr3+/Cr = – 0.74V Arrange these metals in their increasing order of reducing power.

2.4Calculate The Standard Cell Potentials Of Galvanic Cell In Which The Following

Chemistry Class 11 · Chapter 2

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2.4 Calculate the standard cell potentials of galvanic cell in which the following reactions take place: (i) 2Cr(s) + 3Cd2+(aq) ® 2Cr3+(aq) + 3Cd (ii) Fe2+(aq) + Ag+(aq) ® Fe3+(aq) + Ag(s) Calculate the DrGo and equilibrium constant of the reactions. 2.5 Write the Nernst equation and emf of the following cells at 298 K: (i) Mg(s)|Mg2+(0.001M)||Cu2+(0.0001 M)|Cu(s) (ii) Fe(s)|Fe2+(0.001M)||H+(1M)|H2(g)(1bar)| Pt(s) (iii) Sn(s)|Sn2+(0.050 M)||H+(0.020 M)|H2(g) (1 bar)|Pt(s) (iv) Pt(s)|Br–(0.010 M)|Br2(l )||H+(0.030 M)| H2(g) (1 bar)|Pt(s).

2.6In The Button Cells Widely Used In Watches And Other Devices The Following

Chemistry Class 11 · Chapter 2

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2.6 In the button cells widely used in watches and other devices the following reaction takes place: Zn(s) + Ag2O(s) + H2O(l) ® Zn2+(aq) + 2Ag(s) + 2OH–(aq) Determine DrGo and Eo for the reaction.