Q60.The number of white coloured salts among the following is ....... A SrSO4 B MgNH4PO4 C BaCrO4 D Mn ( OH ) E PbSO4 F PbCrO4 2 G AgBr H PbI2 I CaC2O4 J Fe ( OH ) 2CH3COO
What This Question Tests
This question requires identifying the white-coloured salts among a given list of inorganic compounds, testing knowledge of precipitate colours commonly encountered in qualitative analysis.
Concepts Tested
📚 NCERT Sections This Tests
4.16 — Describe The Preparation Of Potassium Permanganate. How Does The Acidified
Chemistry Class 11 · Chapter 4
4.16 Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with (i) iron(II) ions (ii) SO2 and (iii) oxalic acid? Write the ionic equations for the reactions. 4.17 For M2+/M and M3+/M 2+ systems the E o values for some metals are as follows: Cr2+/Cr -0.9V Cr3/Cr2+ -0.4 V Mn 2+/Mn -1.2V Mn3+/Mn2+ +1.5 V Fe2+/Fe -0.4V Fe3+/Fe2+ +0.8 V Use this data to comment upon: (i) the stability of Fe3+ in acid solution as compared to that of Cr3+ or Mn3+ and (ii) the ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal. 4.18 Predict which of the following will be coloured in aqueous solution? Ti 3+, V3+, Cu+, Sc3+, Mn 2+, Fe3+ and Co 2+. Give reasons for each. 4.19 Compare the stability of +2 oxidation state for the elements of the first transition series. 4.20 Compare the chemistry of actinoids with that of the lanthanoids with special reference to: (i) electronic configuration (iii) oxidation state (ii) atomic and ionic sizes and (iv) chemical reactivity. 4.21 How would you account for the following: (i) Of the d4 species, Cr2+ is strongly reducing while manganese(III) is strongly oxidising. (ii) Cobalt(II) is stable in aqueous solution but in the presence of complexing reagents it is easily oxidised. (iii) The d1 configuration is very unstable in ions. 4.22 What is meant by ‘disproportionation’? Give two examples of disproportionation reaction in aqueous solution. 4.23 Which metal in the first series of transition metals exhibits +1 oxidation state most frequently and why? 4.24 Calculate the number of unpaired electrons in the following gaseous ions: Mn3+, Cr3+, V3+ and Ti3+. Which one of these is the most stable in aqueous solution? 4.25 Give examples and suggest reasons for the following features of the transition metal chemistry: (i) The lowest oxide of transition metal is basic, the highest is amphoteric/acidic. (ii) A transition metal exhibits highest oxidation state in oxides and fluorides. (iii) The highest oxidation state is exhibited in oxoanions of a metal. 4.26 Indicate the steps in the preparation of: (i) K2Cr2O7 from chromite ore. (ii) KMnO4 from pyrolusite ore. 4.27 What are alloys? Name an important alloy which contains some of the lanthanoid metals. Mention its uses. 4.28 What are inner transition elements? Decide which of the following atomic numbers are the atomic numbers of the inner transition elements : 29, 59, 74, 95, 102, 104. 4.29 The chemistry of the actinoid elements is not so smooth as that of the lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements. 4.30 Which is the last element in the series of the actinoids? Write the electronic configuration of this element. Comment on the possible oxidation state of this element. Chemistry 116 Reprint 2025-26 4.31 Use Hund’s rule to derive the electronic configuration of Ce3+ ion, and calculate its magnetic moment on the basis of ‘spin-only’ formula. 4.32 Name the members of the lanthanoid series which exhibit +4 oxidation states and those which exhibit +2 oxidation states. Try to correlate this type of behaviour with the electronic configurations of these elements. 4.33 Compare the chemistry of the actinoids with that of lanthanoids with reference to: (i) electronic configuration (ii) oxidation states and (iii) chemical reactivity. 4.34 Write the electronic configurations of the elements with the atomic numbers 61, 91, 101, and 109. 4.35 Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following points: (i) electronic configurations (ii) oxidation states (iii) ionisation enthalpies and (iv) atomic sizes. 4.36 Write down the number of 3d electrons in each of the following ions: Ti 2+, V 2+, Cr3+, Mn 2+, Fe2+, Fe3+, Co2+, Ni2+ and Cu2+. Indicate how would you expect the five 3d orbitals to be occupied for these hydrated ions (octahedral). 4.37 Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements. 4.38 What can be inferred from the magnetic moment values of the following complex species ? Example Magnetic Moment (BM) K4[Mn(CN)6) 2.2 [Fe(H2O)6]2+ 5.3 K2[MnCl4] 5.9 Answers to Some Intext Questions 4.1 Silver (Z = 47) can exhibit +2 oxidation state wherein it will have incompletely filled d-orbitals (4d), hence a transition element. 4.2 In the formation of metallic bonds, no eletrons from 3d-orbitals are involved in case of zinc, while in all other metals of the 3d series, electrons from the d-orbitals are always involved in the formation of metallic bonds. 4.3 Manganese (Z = 25), as its atom has the maximum number of unpaired electrons. 4.5 Irregular variation of ionisation enthalpies is mainly attributed to varying degree of stability of different 3d-configurations (e.g., d 0, d 5, d 10 are exceptionally stable). 4.6 Because of small size and high electronegativity oxygen or fluorine can oxidise the metal to its highest oxidation state. 4.7 Cr 2+ is stronger reducing agent than Fe 2+ Reason: d 4 d 3 occurs in case of Cr 2+ to Cr 3+ But d 6 d 5 occurs in case of Fe2+ to Fe 3+ In a medium (like water) d 3 is more stable as compared to d 5 (see CFSE) 4.9 Cu + in aqueous solution underoes disproportionation, i.e., 2Cu +(aq) ® Cu 2+(aq) + Cu(s) The E0 value for this is favourable.
5.24 — Write Down The Iupac Name For Each Of The Following Complexes And Indicate
Chemistry Class 11 · Chapter 5
5.24 Write down the IUPAC name for each of the following complexes and indicate the oxidation state, electronic configuration and coordination number. Also give stereochemistry and magnetic moment of the complex: (i) K[Cr(H2O)2(C2O4)2].3H2O (iii) [CrCl3(py)3] (v) K4[Mn(CN)6] (ii) [Co(NH3)5Cl-]Cl2 (iv) Cs[FeCl4]
5.29 — Amongst The Following Ions Which One Has The Highest Magnetic Moment Value?
Chemistry Class 11 · Chapter 5
5.29 Amongst the following ions which one has the highest magnetic moment value? (i) [Cr(H2O)6]3+ (ii) [Fe(H2O)6] 2+ (iii) [Zn(H2O)6]2+ 5.30 Amongst the following, the most stable complex is (i) [Fe(H2O)6]3+ (ii) [Fe(NH3)6] 3+ (iii) [Fe(C2O4)3]3– (iv) [FeCl6] 3– 5.31 What will be the correct order for the wavelengths of absorption in the visible region for the following: [Ni(NO2)6] 4–, [Ni(NH3)6] 2+, [Ni(H2O)6] 2+ ? Answers to Some Intext Questions 5.1 (i) [Co(NH3)4(H2O)2]Cl3 (iv) [Pt(NH3)BrCl(NO2)]– (ii) K2[Ni(CN)4] (v) [PtCl2(en)2](NO3)2 (iii) [Cr(en)3]Cl3 (vi) Fe4[Fe(CN)6]3 5.2 (i) Hexaamminecobalt(III) chloride (ii) Pentaamminechloridocobalt(III) chloride (iii) Potassium hexacyanidoferrate(III) (iv) Potassium trioxalatoferrate(III) (v) Potassium tetrachloridopalladate(II) (vi) Diamminechlorido(methanamine)platinum(II) chloride 5.3 (i) Both geometrical (cis-, trans-) and optical isomers for cis can exist. (ii) Two optical isomers can exist. (iii) There are 10 possible isomers. (Hint: There are geometrical, ionisation and linkage isomers possible). (iv) Geometrical (cis-, trans-) isomers can exist. 5.4 The ionisation isomers dissolve in water to yield different ions and thus react differently to various reagents: [Co(NH3)5Br]SO4 + Ba2+ ® BaSO4 (s) [Co(NH3)5SO4]Br + Ba2+ ® No reaction [Co(NH3)5Br]SO4 + Ag+ ® No reaction [Co(NH3)5SO4]Br + Ag+ ® AgBr (s) 5.6 In Ni(CO)4, Ni is in zero oxidation state whereas in NiCl42–, it is in +2 oxidation state. In the presence of CO ligand, the unpaired d electrons of Ni pair up but Cl– being a weak ligand is unable to pair up the unpaired electrons. 5.7 In presence of CN–, (a strong ligand) the 3d electrons pair up leaving only one unpaired electron. The hybridisation is d 2sp 3 forming inner orbital complex. In the presence of H2O, (a weak ligand), 3d electrons do not pair up. The hybridisation is sp 3d 2 forming an outer orbital complex containing five unpaired electrons, it is strongly paramagnetic. 5.8 In the presence of NH3, the 3d electrons pair up leaving two d orbitals empty to be involved in d2sp3 hybridisation forming inner orbital complex in case of [Co(NH3)6]3+. In Ni(NH3)6 2+, Ni is in +2 oxidation state and has d 8 configuration, the hybridisation involved is sp 3d 2 forming outer orbital complex. 5.9 For square planar shape, the hybridisation is dsp 2. Hence the unpaired electrons in 5d orbital pair up to make one d orbital empty for dsp2 hybridisation. Thus there is no unpaired electron. Chemistry 140 Reprint 2025-26
📋 Question Details
- Chapter
- Qualitative Analysis
- Topic
- Solubility of Salts and Precipitates
- Year
- 2024
- Shift
- 01 Feb Shift 1
- Q Number
- Q60
- Type
- Numerical
- NCERT Ref
- Class 11 Chemistry Ch 7: Equilibrium (Solubility Product); Class 12 Chemistry Ch 8: d- and f-block Elements (Transition metal colours)
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(1) CH3COCl (2) ClCH2CHO (3) Cl2CHCHO (4) ClCHCOOH JEE Main 2002 JEE Main Previous Year Paper Q144.The reaction: (CH3)3C −Br ⟶(CH3)3H2O −C −OH (1) elimination reaction (2) substitution reaction (3) free radical reaction (4) displacement reaction Q145.On vigorous oxidation by permanganate solution (CH3)2C = CH −CH2 −CHO gives (1) (2) (3) (4) Q146. CH3CH2COOH ⟶Cl2 A alc.⟶KOH B . What is B ? red P (1) CH3CH2COCl (2) CH3CH2CHO (3) CH2 = CHCOOH (4) ClCH2CH2COOH Q147.When primary amine reacts with chloroform in ethanoic KOH then the product is (1) an isocyanide (2) an aldehyde (3) a cyanide (4) an alcohol Q148.Polymer formation from monomers starts by (1) condensation reaction between monomers (2) coordinate reaction between monomers (3) conversion of monomer to monomer ions by (4) hydrolysis of monomers protons Q149. The compound is used as (1) antiseptic (2) antibiotic (3) analgesic (4) pesticide Q150.RNA is different from DNA because RNA contains (1) ribose sugar and thymine (2) ribose sugar and uracil (3) deoxyribose sugar and thymine (4) deoxyribose sugar and uracil JEE Main 2002 JEE Main Previous Year Paper Q151.The functional group, which is found in amino acid is (1) COOH group (2) NH2 group (3) CH3 group (4) both (a) and (b) Q152.If a, b, c are distinct +ve real numbers and a2 + b2 + c2 = 1 then ab + bc + ca is (1) less than 1 (2) equal to 1 (3) greater than 1 (4) any real no. 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The common ratio of GP is (1) 5 (2) 3/5 (3) 8/5 (4) 1/5 Q168. 13 −23 + 33 −43 + … . +93 = (1) 425 (2) -425 (3) 475 (4) -475 Q169.The sum of integers from 1 to 100 that are divisible by 2 or 5 is (1) 3000 (2) 3050 (3) 3600 (4) 3250 Q170.If an = √7 + √7 + √7 + … . having n radical signs then by methods of mathematical induciton which is true (1) an > 7∀n ≥1 (2) an > 7∀n ≥1 (3) an < 4∀n ≥1 (4) an < 3∀n ≥1 Q171.The coefficients of xp and xq in the expansion of (1 + x)p+q are (1) equal (2) equal with opposite signs (3) reciprocals of each other (4) none of these Q172.If the sum of the coefficients in the expansion of (a + b)n is 4096 , then the greatest coefficient in the expansion is (1) 1594 (2) 792 (3) 924 (4) 2924 Q173.The positive integer just greater than (1 + 0.0001)10000 is JEE Main 2002 JEE Main Previous Year Paper (1) 4 (2) 5 (3) 2 (4) 3 Q174. r and n are positive integers r > 1, n > 2 and coefficient of (r + 2)th term and 3rth term in the expansion of (1 + x)2n are equal, then n equals (1) 3r (2) 3r + 1 (3) 2r (4) 2r + 1 Q175.The period of sin2 θ is (1) π2 (2) π (3) 2π (4) π/2 Q176.The number of solution of tan x + sec x = 2 cos x in [0, 2π) is (1) 2 (2) 3 (3) 0 (4) 1 Q177.A triangle with vertices (4, 0), (-1, -1), (3, 5) is (1) isosceles and right angled (2) isosceles but not right angled (3) right angled but not isosceles (4) neither right angled nor isoceles Q178.The sides of a triangle are 3x + 4y, 4x+37 and 5x + 57 where x, y > 0 then the triangle is (1) right angled (2) obtuse angled (3) equilateral (4) none of these Q179.If the pair of lines ax2 + 2hxy + by2 + 2gx + 2fy + c = 0 intersect on the y - axis then (1) 2fgh = bg2 + ch2 (2) bg2 ≠ch2 (3) abc = 2fgh (4) none of these Q180.The point of lines represented by 3ax2 + 5xy + (a2 −2)y2 = 0 and perpendicular to each other for (1) two values of a (2) ∀a (3) for one value of a (4) for no values of a Q181.Locus of mid point of the portion between the axes of x cos α + y sin α = p where p is constant is (1) x2 + y2 = 4 (2) x2 + y2 = 4p2 p2 (3) 1 + 1 = 2 (4) 1 + 1 = 4 x2 y2 p2 x2 y2 p2 Q182.If the chord y = mx + 1 of the circle x2 + y2 = 1 subtends an angle of measure 450 at the major segment of the circle then value of m is (1) 2 ± √2 (2) −2 ± √2 (3) −1 ± √2 (4) none of these Q183.The centres of a set of circles, each of radius 3 , lie on the circle x2 + y2 = 25. The locus of any point in the set is (1) 4 ≤x2 + y2 ≤64 (2) x2 + y2 ≤25 (3) x2 + y2 ≥25 (4) 3 ≤x2 + y2 ≤9 Q184.The centre of the circle passing through (0, 0) and (1, 0) and touching the circle x2 + y2 = 9 is JEE Main 2002 JEE Main Previous Year Paper , −√2) (1) ( 21 , 12 ) (2) ( 12 (3) ( 23 , 12 ) (4) ( 12 , 32 ) Q185.Two common tangents to the circle x2 + y2 = 2a2 and parabola y2 = 8ax are (1) x = ±(y + 2a) (2) y = ±(x + 2a) (3) x = ±(y + a) (4) y = ±(x + a) Q186. (1) 1 (2) -1 (3) zero (4) does not exist Q187. (1) e4 (2) e2 (3) e3 (4) 1 Q188.Let f(x) = 4 and f ′(x) = 4. Then Limx→2 xf(2)−2f(x)x−2 is given by (1) 2 (2) -2 (3) -4 (4) 3 Q189. 1p + 2p + 3p + … + np Limn→∞ np+1 is (1) 1 (2) 1 p+1 1−p (3) p 1 − p−11 (4) p+21 denotes greatest integer less than or equal to x) Q190. Limx→0 log xn−[x][x] , n ∈N([x] (1) has value -1 (2) has value 0 (3) has value 1 (4) does not exist Q191.If f(1) = 1, f ′(1) = 2, then Limx→1 √f(x)−1 is √x−1 (1) 2 (2) 4 (3) 1 (4) 1/2 Q192.In a class of 100 students there are 70 boys whose average marks in a subject are 75. If the average marks of the complete class is 72, then what is the average of the girls? (1) 73 (2) 65 (3) 68 (4) 74 Q193.The equation of a circle with origin as a centre and passing through equilateral triangle whose median is of length 3a is JEE Main 2002 JEE Main Previous Year Paper (1) x2 + y2 = 9a2 (2) x2 + y2 = 16a2 (3) x2 + y2 = 4a2 (4) x2 + y2 = a2 Q194.In a triangle with sides a, b, c, r1 > r2 > r3 (which are the ex-radii) then (1) a > b > c (2) a < b < c (3) a > b and b < c (4) a < b and b > c Q195. log l p 1 l, m, n are the pth , qth and rth term of a G.P. all positive, then log m q 1 equals log n r 1 (1) -1 (2) 2 (3) 1 (4) 0 Q196. a b ax + b If a > 0 discriminant of ax2 + 2bx + c is -ve, then b c bx + c is ax + b bx + c 0 (1) +ve (2) (ac −b2) (ax2 + 2bx + c) (3) -ve (4) 0 Q197. cot−1(√cos α) = tan−1(√cos α) = x, then sin x = (1) tan2 ( α2 ) (2) cot2 ( α2 ) (3) tan α (4) cot ( α2 ) Q198.The domain of sin−1 [log3(x/3)] is (1) [1, 9] (2) [-1,9] (3) [-9, 1] (4) [-9, -1] Q199.Which one is not periodic (1) |sin 3x| + sin2 x (2) cos √x + cos2 x (3) cos 4x + tan2 x (4) cos 2x + sin x Q200.If f(x + y) = f(x) ⋅f(y)∀x ⋅y and f(5) = 2, f ′(0) = 3 then f ′(5) is (1) 0 (2) 1 (3) 6 (4) 2 Q201.f is defined in [-5, 5] as f(x) = x if x is rational and = -x is irrational. Then (1) f(x) is continuous at every x, except x = 0 (2) f(x) is discontinuous at every x, except x = 0 (3) f(x) is continuous everywhere (4) f(x) is discontinuous everywhere n d2y dy (1 + x2) dx2 + x dx is Q202.If y = (x + √1 + x2) , then (1) n2y (2) −n2y (3) −y (4) 2x2y Q203.The maximum distance from origin of a point on the curve x = a sin t −b sin ( atb ) y = a cos t −b cos ( atb ), both a, b > 0 is (1) a - b (2) a + b (3) √a2 + b2 (4) √a2 −b2 JEE Main 2002 JEE Main Previous Year Paper Q204. ∫10π0 | sin x|dx is (1) 20 (2) 8 (3) 10 (4) 18 xdx then Limn→∞n [In + In−2] equals Q205. In = ∫π/40 tann (1) 1/2 (2) 1 (3) ∞ (4) zero is Q206. ∫ 0√2 [x2]dx (1) 2 −√2 (2) 2 + √2 (3) √2 −1 (4) √2 −2 Q207. ∫π−π 2x(1+sin1+cos2 xx) dx is (1) π2 (2) π2 4 (3) zero (4) π 2 Q208.If y = f(x) makes +ve intercept of 2 and 0 unit on x and y axes and encloses an area of 3/4 square unit with the axes then ∫20 xf ′(x)dx is (1) 3/2 (2) 1 (3) 5/4 (4) -3/4 Q209.The area bounded by the curves y = ln x, y = ln |x|, y = | ln x| and y = | ln ||x| is (1) 4 sq. units (2) 6 sq. units (3) 10 sq. units (4) none of these d3y Q210.The order and degree of the differential equation 2/3 are + 3 dx = 4 dx3 (1 dy ) (1) (1, 32 ) (2) (3, 1) (3) (3, 3) (4) (1, 2) Q211.The solution of the equation d2y = e−2x dx2 (1) e−2x (2) e−2x 4 4 + cx + d (3) 4 1 e−2x + cx2 + d (4) 14 e−4x + cx + d Q212. f(x) and g(x) are two differentiable functions on [0, 2] such that f ′′(x) −g′′(x) = 0 f ′(1) = 2g′(1) = 4f(2) = 3g(2) = 9 then f(x) −g(x) at x = 3/2 is (1) 0 (2) 2 (3) 10 (4) 5 Q213.If |→a| = 4, |→b| = 2 and the angle between →a and →b is π/6 then (→a × →b)2 = 2 is equal to (1) 48 (2) 16 (3) →a (4) none of these Q214. If →a,→b, →c are vectors such that |→a→b→c| = 4 then (1) 16 (2) 64 (3) 4 (4) 8 JEE Main 2002 JEE Main Previous Year Paper Q215.If →a,→b, →c are vectors such that →a + →b + →c = 0 and |→a| = 7, |→b| = 5, |→c| = 3 then angle between vector →b and →c is (1) 60∘ (2) 30∘ (3) 45∘ (4) 90∘ Q216.If |a| = 5, |b| = 4, |c| = 3 thus what will be the value of |a ⋅b + b. c + c. a| , given that →a + →b + →c = 0 (1) 25 (2) 50 (3) -25 (4) -50 Q217. 3λ→c + 2μ(→a × →b) = 0 then (1) 3λ + 2μ = 0 (2) 3λ = 2μ (3) λ = μ (4) λ + μ = 0 Q218. →a = 3^i −5^j and →b = 6^i + 3^j are two vectors and →c is a vector such that →c = →a × →b then |→a| : |→b| : |→c| (1) √34 : √45 : √39 (2) √34 : √45 : 39 (3) 34 : 39 : 45 (4) 39 : 35 : 34 Q219.If →a × →b = →b × →c = →c × →a then →a + →b + →c = (1) abc (2) -1 (3) 0 (4) 2 Q220.The sum of two forces is 18 N and resultant whose direction is at right angles to the smaller force is 12 N. The magnitude of the two forces are (1) 13, 5 (2) 12, 6 (3) 14, 4 (4) 11, 7 Q221.A plane which passes through the point (3, 2, 0) and the line x−41 = y−75 = z−44 is (1) x - y + z = 1 (2) x + y + z = 5 (3) x + 2y - z = 1 (4) 2x - y + z = 5 Q222.The d.r. of normal to the plane through (1, 0, 0), (0, 1, 0) which makes an angle π/4 with plane x + y = 3 are (1) 1, √2, 1 (2) 1, 1, √2 (3) 1, 1, 2 (4) √2, 1, 1 Q223.A problem in mathematics is given to three students A, B, C and their respective probability of solving the problem is 2 1 , 13 and 14 . Probability that the problem is solved is (1) 3 (2) 1 4 2 (3) 2 (4) 1 3 3 Q224. A and B are events such that P(A ∪B) = 3/4, P(A ∩B) = 1/4, P(¯A) = 2/3 then P(¯A ∩B) is (1) 5/12 (2) 3/8 (3) 5/8 (4) 1/4 Q225.A die is tossed 5 times. Getting an odd number is considered a success. Then the variance of distribution of success is JEE Main 2002 JEE Main Previous Year Paper (1) 8/3 (2) 3/8 (3) 4/5 (4) 5/4 JEE Main 2002 JEE Main Previous Year Paper
Q40.The correct order of increasing basicity of the given conjugate bases (R = CH3) is –––––– (1) RCOO < HC = C < R < NH2 (2) R < HC ≡C < RCOO < NH2 ––––– (3) RCOO < NH2 < HC ≡C < R (4) RCOO < HC ≡C < NH2 < R
Q43.Copper wire test for halogens is known as (1) Duma's Test (2) Beilstein's Test (3) Liebig's Test (4) Lassigne's Test
Q45.Beilstein test is used for the estimation of which one of the following elements? (1) S (2) Cl (3) C and H (4) N