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ChemistryMediumMCQ2014 ยท 09 Apr Online

Q44.The standard electrode potentials (EoM+/M) of four metals โˆ’0.76 V, respectively. The sequence of deposition of metals on applying potential is (1) B > D > C > A (2) A > C > B > D (3) C > B > D > A (4) D > A > B > C

What This Question Tests

This question tests the understanding that in electrolysis, the species with the more positive (or less negative) standard reduction potential will be preferentially reduced and deposited at the cathode.

Concepts Tested

Standard electrode potentialReduction potentialElectrochemical seriesSelective deposition in electrolysis

๐Ÿ“š NCERT Sections This Tests

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2.1 โ€” Arrange The Following Metals In The Order In Which They Displace Each Other

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2.4 Calculate the standard cell potentials of galvanic cell in which the following reactions take place: (i) 2Cr(s) + 3Cd2+(aq) ยฎ 2Cr3+(aq) + 3Cd (ii) Fe2+(aq) + Ag+(aq) ยฎ Fe3+(aq) + Ag(s) Calculate the DrGo and equilibrium constant of the reactions. 2.5 Write the Nernst equation and emf of the following cells at 298 K: (i) Mg(s)|Mg2+(0.001M)||Cu2+(0.0001 M)|Cu(s) (ii) Fe(s)|Fe2+(0.001M)||H+(1M)|H2(g)(1bar)| Pt(s) (iii) Sn(s)|Sn2+(0.050 M)||H+(0.020 M)|H2(g) (1 bar)|Pt(s) (iv) Pt(s)|Brโ€“(0.010 M)|Br2(l )||H+(0.030 M)| H2(g) (1 bar)|Pt(s).