2.2 A regular hexagon of side 10 cm has a charge 5 mC at each of its vertices. Calculate the potential at the centre of the hexagon.

3.10 In a reaction between A and B, the initial rate of reaction (r0) was measured for different initial concentrations of A and B as given below: A/ mol L–1 0.20 0.20 0.40 B/ mol L–1 0.30 0.10 0.05 r0/mol L–1s–1 5.07 × 10–5 5.07 × 10–5 1.43 × 10–4 What is the order of the reaction with respect to A and B? 3.11 The following results have been obtained during the kinetic studies of the reaction: 2A + B ® C + D Experiment [A]/mol L–1 [B]/mol L–1 Initial rate of formation of D/mol L–1 min–1 I 0.1 0.1 6.0 × 10–3 II 0.3 0.2 7.2 × 10–2 III 0.3 0.4 2.88 × 10–1 IV 0.4 0.1 2.40 × 10–2 Determine the rate law and the rate constant for the reaction. 3.12 The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table: Experiment [A]/ mol L–1 [B]/ mol L–1 Initial rate/ mol L–1 min–1 I 0.1 0.1 2.0 × 10–2 II – 0.2 4.0 × 10–2 III 0.4 0.4 – IV – 0.2 2.0 × 10–2 3.13 Calculate the half-life of a first order reaction from their rate constants given below: (i) 200 s–1 (ii) 2 min–1 (iii) 4 years–1 3.14 The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample. 3.15 The experimental data for decomposition of N2O5 [2N2O5 ® 4NO2 + O2] in gas phase at 318K are given below: t/s 0 400 800 1200 1600 2000 2400 2800 3200 102 × [N2O5]/ 1.63 1.36 1.14 0.93 0.78 0.64 0.53 0.43 0.35 mol L–1 (i) Plot [N2O5] against t. (ii) Find the half-life period for the reaction. (iii) Draw a graph between log[N2O5] and t. (iv) What is the rate law ? Chemistry 86 Reprint 2025-26 (v) Calculate the rate constant. (vi) Calculate the half-life period from k and compare it with (ii).

2.14 COMBINATION OF CAPACITORS We can combine several capacitors of capacitance C1, C2,…, Cn to obtain a system with some effective capacitance C. The effective capacitance depends on the way the individual capacitors are combined. Two simple possibilities are discussed below. 2.14.1 Capacitors in series Figure 2.26 shows capacitors C1 and C2 FIGURE 2.26 Combination of two combined in series. capacitors in series. The left plate of C1 and the right plate of C2 are connected to two terminals of a battery and have charges Q and –Q , respectively. It then follows that the right plate of C1 has charge –Q and the left plate of C2 has charge Q. If this was not so, the net charge on each capacitor would not be zero. This would result in an electric field in the conductor connecting C1and C2. Charge would flow until the net charge on both C1 and C2 is zero and there is no electric field in the conductor connecting C1 and C2. Thus, in the series combination, charges on the two plates FIGURE 2.27 Combination of n (±Q) are the same on each capacitor. The total capacitors in series. 71 Reprint 2025-26 Physics potential drop V across the combination is the sum of the potential drops V1 and V2 across C1 and C2, respectively. Q Q + (2.55) V = V1 + V2 = C1 C 2 V 1 1 i.e., = + , (2.56) Q C1 C 2 Now we can regard the combination as an effective capacitor with charge Q and potential difference V. The effective capacitance of the combination is Q C = (2.57) V We compare Eq. (2.57) with Eq. (2.56), and obtain 1 1 1 = + (2.58) C C1 C 2 The proof clearly goes through for any number of capacitors arranged in a similar way. Equation (2.55), for n capacitors arranged in series, generalises to Q Q Q V = V1 + V 2 + ... + V n = + + ... + (2.59) C1 C 2 C n Following the same steps as for the case of two capacitors, we get the general formula for effective capacitance of a series combination of n capacitors: 1 1 1 1 1 = + + + ... + (2.60) C C1 C 2 C 3 C n 2.14.2 Capacitors in parallel Figure 2.28 (a) shows two capacitors arranged in parallel. In this case, the same potential difference is applied across both the capacitors. But the plate charges (±Q1) on capacitor 1 and the plate charges (±Q2) on the capacitor 2 are not necessarily the same: Q1 = C1V, Q2 = C2V (2.61) The equivalent capacitor is one with charge Q = Q1 + Q2 (2.62) and potential difference V. Q = CV = C1V + C2V (2.63) The effective capacitance C is, from Eq. (2.63), C = C1 + C2 (2.64) The general formula for effective capacitance C for parallel combination of n capacitors [Fig. 2.28 (b)] follows similarly, Q = Q1 + Q2 + ... + Qn (2.65) FIGURE 2.28 Parallel combination of i.e., CV = C1V + C2V + ... CnV(2.66) (a) two capacitors, (b) n capacitors. which gives C = C1 + C2 + ... Cn (2.67) 72 Reprint 2025-26 Electrostatic Potential and Capacitance Example 2.9 A network of four 10 mF capacitors is connected to a 500 V supply, as shown in Fig. 2.29. Determine (a) the equivalent capacitance of the network and (b) the charge on each capacitor. (Note, the charge on a capacitor is the charge on the plate with higher potential, equal and opposite to the charge on the plate with lower potential.) FIGURE 2.29 Solution (a) In the given network, C1, C2 and C3 are connected in series. The effective capacitance C¢ of these three capacitors is given by 1 1 1 1 = + + C ′ C1 C 2 C 3 For C1 = C2 = C3 = 10 mF, C¢ = (10/3) mF. The network has C¢ and C4 connected in parallel. Thus, the equivalent capacitance C of the network is  10  C = C¢ + C4 =  3 + 10 mF =13.3mF (b) Clearly, from the figure, the charge on each of the capacitors, C1, C2 and C3 is the same, say Q. Let the charge on C4 be Q¢. Now, since the potential difference across AB is Q/C1, across BC is Q/C2, across CD is Q/C3 , we have Q Q Q + + = 500 V . C1 C 2 C 3 Also, Q¢/C4 = 500 V. This gives for the given value of the capacitances, 10 −3 Q = 500 V × µ F = 1.7 × 10 C and EXAMPLE 3 Q ′ = 500 V × 10 µ F = 5.0 × 10 −3 C 2.9