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ChemistryMediumNumerical2022 · 27 Jul Shift 2

Q54.A gas ( Molar mass = 280 g mol−1 ) was burnt in excess O2 in a constant volume calorimeter and during combustion the temperature of calorimeter increased from 298. 0 K to 298. 45 K . If the heat capacity of calorimeter is 2. 5 kJ K−1 and enthalpy of combustion of gas is 9 kJ mol−1 then amount of gas burnt is____ g .

What This Question Tests

This question tests the application of the Van der Waals equation for real gases, specifically using the compressibility factor at high pressure to calculate the 'b' constant.

Concepts Tested

Van der Waals equationCompressibility factorReal gases

Formulas Used

Z = PV/nRT

PV_m = RT(1 + b/V_m) (at high pressure)

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