12.1 (a) No different from (b) Thomson’s model; Rutherford’s model (c) Rutherford’s model (d) Thomson’s model; Rutherford’s model (e) Both the models

11.3 ZEROTH LAW OF THERMODYNAMICS (a) Imagine two systems A and B, separated by an adiabatic wall, while each is in contact with a third system C, via a conducting wall [Fig. 11.2(a)]. The states of the systems (i.e., their macroscopic variables) will change until both A and B come to thermal equilibrium with C. After this is achieved, suppose that the adiabatic wall between A and B is replaced by a conducting wall and C is insulated from A and B by an adiabatic wall [Fig.11.2(b)]. It is found that the states of A and B change no (b) further i.e. they are found to be in thermal Fig. 11.2 (a) Systems A and B are separated by an equilibrium with each other. This observation adiabatic wall, while each is in contact forms the basis of the Zeroth Law of with a third system C via a conducting Thermodynamics, which states that ‘two wall. (b) The adiabatic wall between A systems in thermal equilibrium with a third and B is replaced by a conducting wall, system separately are in thermal equilibrium while C is insulated from A and B by an adiabatic wall.with each other’. R.H. Fowler formulated this * Both the variables need not change. It depends on the constraints. For instance, if the gases are in containers of fixed volume, only the pressures of the gases would change to achieve thermal equilibrium. Reprint 2025-26 THERMODYNAMICS 229

9.17 (a) sin i¢c = 1.44/1.68 which gives i¢c = 59°. Total internal reflection takes place when i > 59° or when r < rmax = 31°. Now, (sin i /sin r max max ) = 1.68 , which gives imax ~ 60°. Thus, all incident rays of angles in the range 0 < i < 60° will suffer total internal reflections in the pipe. (If the length of the pipe is finite, which it is in practice, there will be a lower limit on i determined by the ratio of the diameter to the length of the pipe.) (b) If there is no outer coating, i¢c = sin–1(1/1.68) = 36.5°. Now, i = 90° will have r = 36.5° and i¢ = 53.5° which is greater than i¢c. Thus, all incident rays (in the range 53.5° < i < 90°) will suffer total internal reflections.