5.29 Amongst the following ions which one has the highest magnetic moment value? (i) [Cr(H2O)6]3+ (ii) [Fe(H2O)6] 2+ (iii) [Zn(H2O)6]2+ 5.30 Amongst the following, the most stable complex is (i) [Fe(H2O)6]3+ (ii) [Fe(NH3)6] 3+ (iii) [Fe(C2O4)3]3– (iv) [FeCl6] 3– 5.31 What will be the correct order for the wavelengths of absorption in the visible region for the following: [Ni(NO2)6] 4–, [Ni(NH3)6] 2+, [Ni(H2O)6] 2+ ? Answers to Some Intext Questions 5.1 (i) [Co(NH3)4(H2O)2]Cl3 (iv) [Pt(NH3)BrCl(NO2)]– (ii) K2[Ni(CN)4] (v) [PtCl2(en)2](NO3)2 (iii) [Cr(en)3]Cl3 (vi) Fe4[Fe(CN)6]3 5.2 (i) Hexaamminecobalt(III) chloride (ii) Pentaamminechloridocobalt(III) chloride (iii) Potassium hexacyanidoferrate(III) (iv) Potassium trioxalatoferrate(III) (v) Potassium tetrachloridopalladate(II) (vi) Diamminechlorido(methanamine)platinum(II) chloride 5.3 (i) Both geometrical (cis-, trans-) and optical isomers for cis can exist. (ii) Two optical isomers can exist. (iii) There are 10 possible isomers. (Hint: There are geometrical, ionisation and linkage isomers possible). (iv) Geometrical (cis-, trans-) isomers can exist. 5.4 The ionisation isomers dissolve in water to yield different ions and thus react differently to various reagents: [Co(NH3)5Br]SO4 + Ba2+ ® BaSO4 (s) [Co(NH3)5SO4]Br + Ba2+ ® No reaction [Co(NH3)5Br]SO4 + Ag+ ® No reaction [Co(NH3)5SO4]Br + Ag+ ® AgBr (s) 5.6 In Ni(CO)4, Ni is in zero oxidation state whereas in NiCl42–, it is in +2 oxidation state. In the presence of CO ligand, the unpaired d electrons of Ni pair up but Cl– being a weak ligand is unable to pair up the unpaired electrons. 5.7 In presence of CN–, (a strong ligand) the 3d electrons pair up leaving only one unpaired electron. The hybridisation is d 2sp 3 forming inner orbital complex. In the presence of H2O, (a weak ligand), 3d electrons do not pair up. The hybridisation is sp 3d 2 forming an outer orbital complex containing five unpaired electrons, it is strongly paramagnetic. 5.8 In the presence of NH3, the 3d electrons pair up leaving two d orbitals empty to be involved in d2sp3 hybridisation forming inner orbital complex in case of [Co(NH3)6]3+. In Ni(NH3)6 2+, Ni is in +2 oxidation state and has d 8 configuration, the hybridisation involved is sp 3d 2 forming outer orbital complex. 5.9 For square planar shape, the hybridisation is dsp 2. Hence the unpaired electrons in 5d orbital pair up to make one d orbital empty for dsp2 hybridisation. Thus there is no unpaired electron. Chemistry 140 Reprint 2025-26

6.2 Use Lenz’s law to determine the direction of induced current in the situations described by Fig. 6.16: (a) A wire of irregular shape turning into a circular shape; 175 Reprint 2025-26 Physics (b) A circular loop being deformed into a narrow straight wire. FIGURE 6.16 6.3 A long solenoid with 15 turns per cm has a small loop of area 2.0 cm2 placed inside the solenoid normal to its axis. If the current carried by the solenoid changes steadily from 2.0 A to 4.0 A in 0.1 s, what is the induced emf in the loop while the current is changing? 6.4 A rectangular wire loop of sides 8 cm and 2 cm with a small cut is moving out of a region of uniform magnetic field of magnitude 0.3 T directed normal to the loop. What is the emf developed across the cut if the velocity of the loop is 1 cm s–1 in a direction normal to the (a) longer side, (b) shorter side of the loop? For how long does the induced voltage last in each case? 6.5 A 1.0 m long metallic rod is rotated with an angular frequency of 400 rad s–1 about an axis normal to the rod passing through its one end. The other end of the rod is in contact with a circular metallic ring. A constant and uniform magnetic field of 0.5 T parallel to the axis exists everywhere. Calculate the emf developed between the centre and the ring. 6.6 A horizontal straight wire 10 m long extending from east to west is falling with a speed of 5.0 m s–1, at right angles to the horizontal component of the earth’s magnetic field, 0.30 ´ 10–4 Wb m–2. (a) What is the instantaneous value of the emf induced in the wire? (b) What is the direction of the emf? (c) Which end of the wire is at the higher electrical potential? 6.7 Current in a circuit falls from 5.0 A to 0.0 A in 0.1 s. If an average emf of 200 V induced, give an estimate of the self-inductance of the circuit. 6.8 A pair of adjacent coils has a mutual inductance of 1.5 H. If the current in one coil changes from 0 to 20 A in 0.5 s, what is the change of flux linkage with the other coil? Reprint 2025-26 Chapter Seven ALTERNATING CURRENT 7.1 INTRODUCTION We have so far considered direct current (dc) sources and circuits with dc sources. These currents do not change direction with time. But voltages and currents that vary with time are very common. The electric mains supply in our homes and offices is a voltage that varies like a sine function with time. Such a voltage is called alternating voltage (ac voltage) and the current driven by it in a circuit is called the alternating current (ac current)*. Today, most of the electrical devices we use require ac voltage. This is mainly because most of the electrical energy sold by power companies is transmitted and distributed as alternating current. The main reason for preferring use of ac voltage over dc voltage is that ac voltages can be easily and efficiently converted from one voltage to the other by means of transformers. Further, electrical energy can also be transmitted economically over long distances. AC circuits exhibit characteristics which are exploited in many devices of daily use. For example, whenever we tune our radio to a favourite station, we are taking advantage of a special property of ac circuits – one of many that you will study in this chapter. * The phrases ac voltage and ac current are contradictory and redundant, respectively, since they mean, literally, alternating current voltage and alternating current current. Still, the abbreviation ac to designate an electrical quantity displaying simple harmonic time dependance has become so universally accepted that we follow others in its use. Further, voltage – another phrase commonly used means potential difference between two points. Reprint 2025-26 Physics 7.2 AC VOLTAGE APPLIED TO A RESISTOR Figure 7.1 shows a resistor connected to a source ε of ac voltage. The symbol for an ac source in a circuit diagram is . We consider a source which produces sinusoidally varying potential difference across its terminals. Let this potential difference, also called ac voltage, be given by v = vm sin ωt (7.1) where vm is the amplitude of the oscillating potential difference and ω is its angular frequency. Nicola Tesla (1856 – 1943) Serbian-American scientist, inventor and genius. He conceived the idea of the rotating1943) magnetic field, which is the – basis of practically all alternating current machinery, and which(1856 helped usher in the age of FIGURE 7.1 AC voltage applied to a resistor. electric power. He also invented among other To find the value of current through the resistor, we things the induction motor, ε()t = 0 (refer to Section the polyphase system of ac apply Kirchhoff’s loop rule ∑TESLA power, and the high 3.12), to the circuit shown in Fig. 7.1 to get frequency induction coil v m sin ωt = i R (the Tesla coil) used in radio and television sets and v m i = sin ωtNICOLA other electronic equipment. or R The SI unit of magnetic field is named in his honour. Since R is a constant, we can write this equation as i = i m sin ωt (7.2) where the current amplitude im is given by v m i m = (7.3) R Equation (7.3) is Ohm’s law, which for resistors, works equally well for both ac and dc voltages. The voltage across a pure resistor and the current through it, given by Eqs. (7.1) and (7.2) are plotted as a function of time in Fig. 7.2. Note, in particular that both v and i reach zero, minimum and maximum values at the same time. Clearly, the voltage and current are in phase with FIGURE 7.2 In a pure resistor, the voltage and each other. current are in phase. The We see that, like the applied voltage, the current varies minima, zero and maxima sinusoidally and has corresponding positive and negative values occur at the same during each cycle. Thus, the sum of the instantaneous current respective times. values over one complete cycle is zero, and the average current 178 is zero. The fact that the average current is zero, however, does Reprint 2025-26 Alternating Current not mean that the average power consumed is zero and that there is no dissipation of electrical energy. As you know, Joule heating is given by i2R and depends on i2 (which is always positive whether i is positive or negative) and not on i. Thus, there is Joule heating and dissipation of electrical energy when an ac current passes through a resistor. The instantaneous power dissipated in the resistor is p = i 2 R = i m2 R sin 2 ωt (7.4) The average value of p over a cycle is* p = < i 2 R > = < i m2 R sin 2 ωt > [7.5(a)] where the bar over a letter (here, p) denotes its average George Westinghouse value and <......> denotes taking average of the quantity (1846 – 1914) A leading inside the bracket. Since, i2m and R are constants, proponent of the use of p = i m2 R < sin 2 ωt > [7.5(b)] alternating current overUsing the trigonometric identity, sin2 wt = direct current. Thus, GEORGE he came into conflict 1/2 (1– cos 2wt), we have < sin2 wt > = (1/2) (1– < cos 2wt >) with Thomas Alva Edison, and since < cos2wt > = 0**, we have, an advocate of direct 2 1 current. Westinghouse < sin ωt > = was convinced that the 2 technology of alternating Thus, current was the key to 1 2 the electrical future. p = i m R [7.5(c)] He founded the famous 2 Company named after him WESTINGHOUSE To express ac power in the same form as dc power and enlisted the services (P = I2R), a special value of current is defined and used. of Nicola Tesla and It is called, root mean square (rms) or effective current other inventors in the (1846(Fig. 7.3) and is denoted by Irms or I. development of alternating current motors and – apparatus for the transmission of high tension current, pioneering 1914) in large scale lighting. FIGURE 7.3 The rms current I is related to the peak current im by I = mi / 2 = 0.707 im. 1 T F (t ) d t* The average value of a function F (t) over a period T is given by F (t ) = T ∫0 1 T 1  sin 2ωt  T 1 < cos 2ωt > = ∫ cos 2ω t dt = = [ sin 2ω T − 0 ] = 0** T 0 T  2ω  0 2ωT 179 Reprint 2025-26 Physics It is defined by 2 1 2 i m I = i = i m = 2 2 = 0.707 im (7.6) In terms of I, the average power, denoted by P is 1 2 2 P = p = i m R = I R (7.7) 2 Similarly, we define the rms voltage or effective voltage by v m V = = 0.707 vm (7.8) 2 From Eq. (7.3), we have vm = imR v m i m or, = R 2 2 or, V = IR (7.9) Equation (7.9) gives the relation between ac current and ac voltage and is similar to that in the dc case. This shows the advantage of introducing the concept of rms values. In terms of rms values, the equation for power [Eq. (7.7)] and relation between current and voltage in ac circuits are essentially the same as those for the dc case. It is customary to measure and specify rms values for ac quantities. For example, the household line voltage of 220 V is an rms value with a peak voltage of vm = 2 V = (1.414)(220 V) = 311 V In fact, the I or rms current is the equivalent dc current that would produce the same average power loss as the alternating current. Equation (7.7) can also be written as P = V2 / R = I V (since V = I R) Example 7.1 A light bulb is rated at 100W for a 220 V supply. Find (a) the resistance of the bulb; (b) the peak voltage of the source; and (c) the rms current through the bulb. Solution (a) We are given P = 100 W and V = 220 V. The resistance of the bulb is 2 V 2 ( 220 V ) R = = = 484 Ω P 100 W (b) The peak voltage of the source is V 7.1 v m = 2V = 311 (c) Since, P = I V P 100 W I 0.454A EXAMPLE V 220 V Reprint 2025-26 Alternating Current

3.10 In a reaction between A and B, the initial rate of reaction (r0) was measured for different initial concentrations of A and B as given below: A/ mol L–1 0.20 0.20 0.40 B/ mol L–1 0.30 0.10 0.05 r0/mol L–1s–1 5.07 × 10–5 5.07 × 10–5 1.43 × 10–4 What is the order of the reaction with respect to A and B? 3.11 The following results have been obtained during the kinetic studies of the reaction: 2A + B ® C + D Experiment [A]/mol L–1 [B]/mol L–1 Initial rate of formation of D/mol L–1 min–1 I 0.1 0.1 6.0 × 10–3 II 0.3 0.2 7.2 × 10–2 III 0.3 0.4 2.88 × 10–1 IV 0.4 0.1 2.40 × 10–2 Determine the rate law and the rate constant for the reaction. 3.12 The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table: Experiment [A]/ mol L–1 [B]/ mol L–1 Initial rate/ mol L–1 min–1 I 0.1 0.1 2.0 × 10–2 II – 0.2 4.0 × 10–2 III 0.4 0.4 – IV – 0.2 2.0 × 10–2 3.13 Calculate the half-life of a first order reaction from their rate constants given below: (i) 200 s–1 (ii) 2 min–1 (iii) 4 years–1 3.14 The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample. 3.15 The experimental data for decomposition of N2O5 [2N2O5 ® 4NO2 + O2] in gas phase at 318K are given below: t/s 0 400 800 1200 1600 2000 2400 2800 3200 102 × [N2O5]/ 1.63 1.36 1.14 0.93 0.78 0.64 0.53 0.43 0.35 mol L–1 (i) Plot [N2O5] against t. (ii) Find the half-life period for the reaction. (iii) Draw a graph between log[N2O5] and t. (iv) What is the rate law ? Chemistry 86 Reprint 2025-26 (v) Calculate the rate constant. (vi) Calculate the half-life period from k and compare it with (ii).