Q60.Let A be a 2 × 2 real matrix with entries from {0, 1} and |A| ≠0 . Consider the following two statements; (P) If A ≠l2 , then |A| = −1 (Q) If |A| = 1 , then tr(A) = 2 Where l2 denotes 2 × 2 identity matrix and tr(A) denotes the sum of the diagonal entries of A . Then (1) (P) is false and (Q) is true (2) Both (P) and (Q) are false (3) (P) is true and (Q) is false (4) Both (P) and (Q) are true
What This Question Tests
This question tests a deep understanding of matrix properties, specifically determinants and trace for 2x2 matrices with restricted entries, requiring case analysis to verify the truthfulness of given statements.
Concepts Tested
Formulas Used
|A| = ad-bc for A = [[a,b],[c,d]]
tr(A) = a+d
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3.10 In a reaction between A and B, the initial rate of reaction (r0) was measured for different initial concentrations of A and B as given below: A/ mol L–1 0.20 0.20 0.40 B/ mol L–1 0.30 0.10 0.05 r0/mol L–1s–1 5.07 × 10–5 5.07 × 10–5 1.43 × 10–4 What is the order of the reaction with respect to A and B? 3.11 The following results have been obtained during the kinetic studies of the reaction: 2A + B ® C + D Experiment [A]/mol L–1 [B]/mol L–1 Initial rate of formation of D/mol L–1 min–1 I 0.1 0.1 6.0 × 10–3 II 0.3 0.2 7.2 × 10–2 III 0.3 0.4 2.88 × 10–1 IV 0.4 0.1 2.40 × 10–2 Determine the rate law and the rate constant for the reaction. 3.12 The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table: Experiment [A]/ mol L–1 [B]/ mol L–1 Initial rate/ mol L–1 min–1 I 0.1 0.1 2.0 × 10–2 II – 0.2 4.0 × 10–2 III 0.4 0.4 – IV – 0.2 2.0 × 10–2 3.13 Calculate the half-life of a first order reaction from their rate constants given below: (i) 200 s–1 (ii) 2 min–1 (iii) 4 years–1 3.14 The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample. 3.15 The experimental data for decomposition of N2O5 [2N2O5 ® 4NO2 + O2] in gas phase at 318K are given below: t/s 0 400 800 1200 1600 2000 2400 2800 3200 102 × [N2O5]/ 1.63 1.36 1.14 0.93 0.78 0.64 0.53 0.43 0.35 mol L–1 (i) Plot [N2O5] against t. (ii) Find the half-life period for the reaction. (iii) Draw a graph between log[N2O5] and t. (iv) What is the rate law ? Chemistry 86 Reprint 2025-26 (v) Calculate the rate constant. (vi) Calculate the half-life period from k and compare it with (ii).
📋 Question Details
- Chapter
- Matrices
- Topic
- Properties of matrices
- Year
- 2020
- Shift
- 02 Sep Shift 1
- Q Number
- Q60
- Type
- MCQ
- NCERT Ref
- Class 12 Mathematics Ch 3: Matrices
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