3.10 In a reaction between A and B, the initial rate of reaction (r0) was measured for different initial concentrations of A and B as given below: A/ mol L–1 0.20 0.20 0.40 B/ mol L–1 0.30 0.10 0.05 r0/mol L–1s–1 5.07 × 10–5 5.07 × 10–5 1.43 × 10–4 What is the order of the reaction with respect to A and B? 3.11 The following results have been obtained during the kinetic studies of the reaction: 2A + B ® C + D Experiment [A]/mol L–1 [B]/mol L–1 Initial rate of formation of D/mol L–1 min–1 I 0.1 0.1 6.0 × 10–3 II 0.3 0.2 7.2 × 10–2 III 0.3 0.4 2.88 × 10–1 IV 0.4 0.1 2.40 × 10–2 Determine the rate law and the rate constant for the reaction. 3.12 The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table: Experiment [A]/ mol L–1 [B]/ mol L–1 Initial rate/ mol L–1 min–1 I 0.1 0.1 2.0 × 10–2 II – 0.2 4.0 × 10–2 III 0.4 0.4 – IV – 0.2 2.0 × 10–2 3.13 Calculate the half-life of a first order reaction from their rate constants given below: (i) 200 s–1 (ii) 2 min–1 (iii) 4 years–1 3.14 The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample. 3.15 The experimental data for decomposition of N2O5 [2N2O5 ® 4NO2 + O2] in gas phase at 318K are given below: t/s 0 400 800 1200 1600 2000 2400 2800 3200 102 × [N2O5]/ 1.63 1.36 1.14 0.93 0.78 0.64 0.53 0.43 0.35 mol L–1 (i) Plot [N2O5] against t. (ii) Find the half-life period for the reaction. (iii) Draw a graph between log[N2O5] and t. (iv) What is the rate law ? Chemistry 86 Reprint 2025-26 (v) Calculate the rate constant. (vi) Calculate the half-life period from k and compare it with (ii).

11.3 ZEROTH LAW OF THERMODYNAMICS (a) Imagine two systems A and B, separated by an adiabatic wall, while each is in contact with a third system C, via a conducting wall [Fig. 11.2(a)]. The states of the systems (i.e., their macroscopic variables) will change until both A and B come to thermal equilibrium with C. After this is achieved, suppose that the adiabatic wall between A and B is replaced by a conducting wall and C is insulated from A and B by an adiabatic wall [Fig.11.2(b)]. It is found that the states of A and B change no (b) further i.e. they are found to be in thermal Fig. 11.2 (a) Systems A and B are separated by an equilibrium with each other. This observation adiabatic wall, while each is in contact forms the basis of the Zeroth Law of with a third system C via a conducting Thermodynamics, which states that ‘two wall. (b) The adiabatic wall between A systems in thermal equilibrium with a third and B is replaced by a conducting wall, system separately are in thermal equilibrium while C is insulated from A and B by an adiabatic wall.with each other’. R.H. Fowler formulated this * Both the variables need not change. It depends on the constraints. For instance, if the gases are in containers of fixed volume, only the pressures of the gases would change to achieve thermal equilibrium. Reprint 2025-26 THERMODYNAMICS 229

14.3 Carbon, silicon and germanium have four valence electrons each. These are characterised by valence and conduction bands separated 341 Reprint 2025-26 Physics by energy band gap respectively equal to (Eg)C, (Eg)Si and (Eg)Ge. Which of the following statements is true? (a) (Eg)Si < (Eg)Ge < (Eg)C (b) (Eg)C < (Eg)Ge > (Eg)Si (c) (Eg)C > (Eg)Si > (Eg)Ge (d) (Eg)C = (Eg)Si = (Eg)Ge 14.4 In an unbiased p-n junction, holes diffuse from the p-region to n-region because (a) free electrons in the n-region attract them. (b) they move across the junction by the potential difference. (c) hole concentration in p-region is more as compared to n-region. (d) All the above. 14.5 When a forward bias is applied to a p-n junction, it (a) raises the potential barrier. (b) reduces the majority carrier current to zero. (c) lowers the potential barrier. (d) None of the above. 14.6 In half-wave rectification, what is the output frequency if the input frequency is 50 Hz. What is the output frequency of a full-wave rectifier for the same input frequency. Reprint 2025-26 Notes Reprint 2025-26 Physics APPENDICES APPENDIX A 1 THE GREEK ALPHABET APPENDIX A 2 COMMON SI PREFIXES AND SYMBOLS FOR MULTIPLES AND SUB-MULTIPLES Reprint 2025-26 AppendicesAnswers APPENDIX A 3 SOME IMPORTANT CONSTANTS OTHER USEFUL CONSTANTS 345 Reprint 2025-26 Physics ANSWERS CHAPTER 9 9.1 v = –54 cm. The image is real, inverted and magnified. The size of the image is 5.0 cm. As u ® f, v ® ¥; for u < f, image is virtual. 9.2 v = 6.7 cm. Magnification = 5/9, i.e., the size of the image is 2.5 cm. As u ® ¥; v ® f (but never beyond) while m ® 0. 9.3 1.33; 1.7 cm 9.4 nga = 1.51; nwa = 1.32; ngw = 1.144; which gives sin r = 0.6181 i.e., r ~ 38°. 9.5 r = 0.8 × tan ic and sin ci = 1/1.33 ≅ 0.75 , where r is the radius (in m) of the largest circle from which light comes out and ic is the critical angle for water-air interface, Area = 2.6 m2 9.6 n ≅ 1.53 and Dm for prism in water ≅ 10° 9.7 R = 22 cm 9.8 Here the object is virtual and the image is real. u = +12 cm (object on right; virtual) (a) f = +20 cm. Image is real and at 7.5 cm from the lens on its right side. (b) f = –16 cm. Image is real and at 48 cm from the lens on its right side. 9.9 v = 8.4 cm, image is erect and virtual. It is diminished to a size 1.8 cm. As u ® ¥, v ® f (but never beyond f while m ® 0). Note that when the object is placed at the focus of the concave lens (21 cm), the image is located at 10.5 cm (not at infinity as one might wrongly think). 9.10 A diverging lens of focal length 60 cm 9.11 (a) ve = –25 cm and fe = 6.25 cm give ue = –5 cm; vO = (15 – 5) cm = 10 cm, fO = uO = – 2.5 cm; Magnifying power = 20 (b) uO = – 2.59 cm. Magnifying power = 13.5. 9.12 Angular magnification of the eye-piece for image at 25 cm 25 25   1  11; | u e |= cm = 2 .27cm ; vO = 7.2 cm 2.5 11 Separation = 9.47 cm; Magnifying power = 88 9.13 24; 150 cm 9.14 (a) Angular magnification = 1500 346 (b) Diameter of the image = 13.7 cm. Reprint 2025-26 Answers