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PhysicsMediumMCQ2010 · Unknown

Q5. The potential energy function for the force between two atoms in a diatomic molecule is approximately given by U(x) = a − b , where a and b are constants and x is the distance between the atoms. If the dissociation x12 x6 energy of the molecule is D = [U(x = ∞) −Uat equilbrium ], D is (1) b2 (2) b2 2a 12a (3) b2 (4) b2 4a 6a

What This Question Tests

This question tests the understanding of potential energy functions, finding equilibrium positions by differentiation, and calculating dissociation energy from the potential energy well.

Concepts Tested

Force from potential energyEquilibrium conditionDissociation energy

Formulas Used

F = -dU/dx

dU/dx = 0 at equilibrium

📚 NCERT Sections This Tests

5.9The Potential Energy Of A Spring

Physics Class 11 · Chapter 5

78% match

5.9 THE POTENTIAL ENERGY OF A SPRING The spring force is an example of a variable force which is conservative. Fig. 5.7 shows a block attached to a spring and resting on a smooth horizontal surface. The other end of the spring is attached to a rigid wall. The spring is light and may be treated as massless. In an ideal spring, the spring force Fs is proportional to x where x is the displacement of the block from the equilibrium position. The displacement could be either positive [Fig. 5.7(b)] or negative [Fig. 5.7(c)]. This force law for the spring is called Hooke’s law and is mathematically stated as Fs = − kx The constant k is called the spring constant. Its unit is N m-1. The spring is said to be stiff if k is large and soft if k is small. Fig. 5.7 Illustration of the spring force with a block Suppose that we pull the block outwards as in attached to the free end of the spring. Fig. 5.7(b). If the extension is xm, the work done by (a) The spring force Fs is zero when the the spring force is displacement x from the equilibrium position is zero. (b) For the stretched spring x > 0 xm xm and Fs < 0 (c) For the compressed spring d x x < 0 and Fs > 0.(d) The plot of Fs versus x. Fs d x = −∫kx W s = ∫ 0 0 The area of the shaded triangle represents the work done by the spring force. Due to the k x m2 opposing signs of Fs and x, this work done is = − (5.15) 2 2 negative, W s = −kx m / 2 . This expression may also be obtained by considering the area of the triangle as in The same is true when the spring is Fig. 5.7(d). Note that the work done by the compressed with a displacement xc (< 0). Theexternal pulling force F is positive since it overcomes the spring force. spring force does work Ws = − kx c2 / 2 while the Reprint 2025-26 WORK, ENERGY AND POWER 81 2 and vice versa, however, the total mechanical external force F does work + kxc / 2. If the block energy remains constant. This is graphically is moved from an initial displacement xi to a depicted in Fig. 5.8. final displacement xf , the work done by the spring force Ws is xf k x 2f k x i2 (5.17) k x d x = − Ws = − ∫ 2 2 x i Thus the work done by the spring force depends only on the end points. Specifically, if the block is pulled from xi and allowed to return to xi ; x i k x i2 k x i2 k x dx = − Ws = − ∫ 2 2 x i = 0 (5.18) Fig. 5.8 Parabolic plots of the potential energy V and The work done by the spring force in a cyclic kinetic energy K of a block attached to a spring obeying Hooke’s law. The two plotsprocess is zero. We have explicitly demonstrated are complementary, one decreasing as the that the spring force (i) is position dependent other increases. The total mechanical only as first stated by Hooke, (Fs = − kx); (ii) energy E = K + V remains constant. does work which only depends on the initial and final positions, e.g. Eq. (5.17). Thus, the spring ⊳ Example 5.8 To simulate car accidents, autoforce is a conservative force. manufacturers study the collisions of moving We define the potential energy V(x) of the spring cars with mounted springs of different springto be zero when block and spring system is in the constants. Consider a typical simulation withequilibrium position. For an extension (or a car of mass 1000 kg moving with a speedcompression) x the above analysis suggests that 18.0 km/h on a smooth road and colliding kx 2 with a horizontally mounted spring of spring V(x) = (5.19) constant 5.25 × 103 N m–1. What is the 2 maximum compression of the spring ?You may easily verify that − dV/dx = −k x, the spring force. If the block of mass m in Fig. 5.7 is extended to xm and released from rest, then its Answer At maximum compression the kinetic total mechanical energy at any arbitrary point x, energy of the car is converted entirely into the where x lies between – xm and + xm, will be given by potential energy of the spring. The kinetic energy of the moving car is 1 2 1 2 1 2 k x m = k x + m v 1 2 2 2 K = mv2 2where we have invoked the conservation of mechanical energy. This suggests that the speed 1 3 and the kinetic energy will be maximum at the = × 10 × 5 × 5 2 equilibrium position, x = 0, i.e., K = 1.25 × 104 J 1 2 1 2 m v m = k x m where we have converted 18 km h–1 to 5 m s–1 [It is 2 2 useful to remember that 36 km h–1 = 10 m s–1]. where vm is the maximum speed. At maximum compression xm, the potential energy V of the spring is equal to the kinetic k or v m = x m energy K of the moving car from the principle of m conservation of mechanical energy. Note that k/m has the dimensions of [T-2] and our equation is dimensionally correct. The 1 2 V = k x m kinetic energy gets converted to potential energy 2 Reprint 2025-26 82 PHYSICS = 1.25 × 104 J We obtain xm = 2.00 m We note that we have idealised the situation. The spring is considered to be massless. The surface has been considered to possess negligible friction. ⊳ We conclude this section by making a few Fig. 5.9 The forces acting on the car. remarks on conservative forces. (i) Information on time is absent from the above 1 2 ∆K = Kf − Ki = 0 − m v discussions. In the example considered 2 above, we can calculate the compression, but The work done by the net force is not the time over which the compression 1 2 occurs. A solution of Newton’s Second Law W = − kx m −µm g x m 2 for this system is required for temporal information. Equating we have (ii) Not all forces are conservative. Friction, for 1 2 1 2 example, is a non-conservative force. The m v = k x m + µm g x m 2 2 principle of conservation of energy will have Now µmg = 0.5 × 103 × 10 = 5 × 103 N (taking to be modified in this case. This is illustrated g =10.0 m s-2). After rearranging the above in Example 5.9. equation we obtain the following quadratic(iii) The zero of the potential energy is arbitrary. equation in the unknown xm. It is set according to convenience. For the spring force we took V(x) = 0, at x = 0, i.e. the 2 2 k x m + 2µm g x m − m v = 0 unstretched spring had zero potential energy. For the constant gravitational force mg, we took V = 0 on the earth’s surface. In a later chapter we shall see that for the force where we take the positive square root since due to the universal law of gravitation, the zero is best defined at an infinite distance xm is positive. Putting in numerical values we obtain from the gravitational source. However, once the zero of the potential energy is fixed in a xm = 1.35 m given discussion, it must be consistently which, as expected, is less than the result in adhered to throughout the discussion. You Example 5.8. cannot change horses in midstream ! If the two forces on the body consist of a conservative force Fc and a non-conservative⊳ force Fnc , the conservation of mechanical energy Example 5.9 Consider Example 5.8 taking formula will have to be modified. By the WE the coefficient of friction, µ, to be 0.5 and theorem calculate the maximum compression of the spring. (Fc+ Fnc) ∆x = ∆K But Fc ∆x = − ∆V Answer In presence of friction, both the spring Hence, ∆(K + V) = Fnc ∆x force and the frictional force act so as to oppose ∆E = Fnc ∆x the compression of the spring as shown in where E is the total mechanical energy. Over Fig. 5.9. the path this assumes the form We invoke the work-energy theorem, rather Ef − Ei = Wnc than the conservation of mechanical energy. where Wnc is the total work done by the The change in kinetic energy is non-conservative forces over the path. Note that Reprint 2025-26 WORK, ENERGY AND POWER 83 unlike the conservative force, Wnc depends on Our electricity bills carry the energy the particular path i to f. ⊳ consumption in units of kWh. Note that kWh is a unit of energy and not of power.

5.8The Conservation Of Mechanical A Ball Of Mass M Being Dropped From A Cliff Of

Physics Class 11 · Chapter 5

78% match

5.8 THE CONSERVATION OF MECHANICAL a ball of mass m being dropped from a cliff of ENERGY height H. For simplicity we demonstrate this important principle for one-dimensional motion. Suppose that a body undergoes displacement ∆x under the action of a conservative force F. Then from the WE theorem we have, ∆K = F(x) ∆x If the force is conservative, the potential energy function V(x) can be defined such that − ∆V = F(x) ∆x The above equations imply that Fig. 5.5 The conversion of potential energy to kinetic ∆K + ∆V = 0 energy for a ball of mass m dropped from a ∆(K + V ) = 0 (5.10) height H. Reprint 2025-26 WORK, ENERGY AND POWER 79 The total mechanical energies E0, Eh, and EH Answer (i) There are two external forces on of the ball at the indicated heights zero (ground the bob : gravity and the tension (T ) in the level), h and H, are string. The latter does no work since the displacement of the bob is always normal to the EH = mgH (5.11 a) string. The potential energy of the bob is thus 1 2 E h = mgh + mv h (5.11 b) associated with the gravitational force only. The 2 2 total mechanical energy E of the system is E0 = (1/2) mvf (5.11 c) conserved. We take the potential energy of the The constant force is a special case of a spatially system to be zero at the lowest point A. Thus, dependent force F(x). Hence, the mechanical at A : energy is conserved. Thus EH = E0 1 2 1 2 E = mv0 (5.12) or, mgH = mv f 2 2 v f = 2 gH [Newton’s Second Law] a result that was obtained in section 5.7 for a where TA is the tension in the string at A. At thefreely falling body. highest point C, the string slackens, as the Further, tension in the string (TC) becomes zero. EH = Eh Thus, at Cwhich implies, 2 1 2 v h = 2 g(H − h) (5.11 d) E = mv c + 2mgL (5.13) 2 and is a familiar result from kinematics. At the height H, the energy is purely potential. mvc2It is partially converted to kinetic at height h and mg = [Newton’s Second Law] (5.14) L is fully kinetic at ground level. This illustrates the conservation of mechanical energy. where vC is the speed at C. From Eqs. (5.13) ⊳ and (5.14) Example 5.7 A bob of mass m is suspended 5 by a light string of length L . It is imparted a E = mgL horizontal velocity vo at the lowest point A 2 such that it completes a semi-circular Equating this to the energy at A trajectory in the vertical plane with the string 5 m 2 becoming slack only on reaching the topmost mgL = v 0 point, C. This is shown in Fig. 5.6. Obtain an 2 2 expression for (i) vo; (ii) the speeds at points or, v 0 = 5 gL B and C; (iii) the ratio of the kinetic energies (ii) It is clear from Eq. (5.14) (KB/KC) at B and C. Comment on the nature of the trajectory of the bob after it reaches vC = gL the point C. At B, the energy is 1 2 E = mv B + mgL 2 Equating this to the energy at A and employing the result from (i), namely v 02 = 5 gL , 1 2 1 2 mv B + mgL = mv 0 2 2 5 = m g L Fig. 5.6 2 Reprint 2025-26 80 PHYSICS ∴ vB = 3 gL k x m2 W = + (5.16) 2 (iii) The ratio of the kinetic energies at B and C is : 1 2 mv B K B 2 3 = = 2 1 K C 1 mvC 2 At point C, the string becomes slack and the velocity of the bob is horizontal and to the left. If the connecting string is cut at this instant, the bob will execute a projectile motion with horizontal projection akin to a rock kicked horizontally from the edge of a cliff. Otherwise the bob will continue on its circular path and complete the revolution. ⊳

2.7Potential Energy Of A System Of Charges

Physics Class 11 · Chapter 2

77% match

2.7 POTENTIAL ENERGY OF A SYSTEM OF CHARGES Consider first the simple case of two charges q1and q2 with position vector r1 and r2 relative to some origin. Let us calculate the work done (externally) in building up this configuration. This means that we consider the charges q1 and q2 initially at infinity and determine the work done by an external agency to bring the charges to the given locations. Suppose, first the charge q1 is brought from infinity to the point r1. There is no external field against which work needs to be done, so work done in bringing q1 from infinity to r1 is zero. This charge produces a potential in space given by 1 q1 V1 = 4 πε0 r1P where r1P is the distance of a point P in space from the location of q1. From the definition of potential, work done in bringing charge q2 from infinity to the point r2 is q2 times the potential at r2 due to q1: 1 q1q 2 work done on q2 = 4 πε0 r12 55 Reprint 2025-26 Physics where r12 is the distance between points 1 and 2. Since electrostatic force is conservative, this work gets stored in the form of potential energy of the system. Thus, the potential energy of a system of two charges q1 and q2 is FIGURE 2.13 Potential energy of a 1 q1q 2 U = system of charges q1 and q2 is 4 πε0 r12 (2.22) directly proportional to the product of charges and inversely to the Obviously, if q2 was brought first to its present location and distance between them. q1 brought later, the potential energy U would be the same. More generally, the potential energy expression, Eq. (2.22), is unaltered whatever way the charges are brought to the specified locations, because of path-independence of work for electrostatic force. Equation (2.22) is true for any sign of q1and q2. If q1q2 > 0, potential energy is positive. This is as expected, since for like charges (q1q2 > 0), electrostatic force is repulsive and a positive amount of work is needed to be done against this force to bring the charges from infinity to a finite distance apart. For unlike charges (q1 q2 < 0), the electrostatic force is attractive. In that case, a positive amount of work is needed against this force to take the charges from the given location to infinity. In other words, a negative amount of work is needed for the reverse path (from infinity to the present locations), so the potential energy is negative. Equation (2.22) is easily generalised for a system of any number of point charges. Let us calculate the potential energy of a system of three charges q1, q2 and q3 located at r1, r2, r3, respectively. To bring q1 first from infinity to r1, no work is required. Next we bring q2 from infinity to r2. As before, work done in this step is 1 q1q 2 q 2 V1 ( r2 ) = (2.23) 4 πε0 r12 The charges q1 and q2 produce a potential, which at any point P is given by 1  q1 q 2  V1, 2 = + (2.24) 4 πε0  r1P r2 P  Work done next in bringing q3 from infinity to the point r3 is q3 times V1, 2 at r3 1  q1q 3 q 2 q 3  q 3 V1, 2 ( r3 ) = + (2.25) 4 πε0  r13 r23  The total work done in assembling the charges at the given locations is obtained by adding the work done in different steps [Eq. (2.23) and Eq. (2.25)], 1  q1q 2 q1q 3 q 2 q 3  U = + + (2.26) FIGURE 2.14 Potential energy of a 4 πε0  r12 r13 r23  system of three charges is given by Again, because of the conservative nature of the Eq. (2.26), with the notation given electrostatic force (or equivalently, the path in the figure. independence of work done), the final expression for U, Eq. (2.26), is independent of the manner in which 56 the configuration is assembled. The potential energy Reprint 2025-26 Electrostatic Potential and Capacitance is characteristic of the present state of configuration, and not the way the state is achieved. Example 2.4 Four charges are arranged at the corners of a square ABCD of side d, as shown in Fig. 2.15.(a) Find the work required to put together this arrangement. (b) A charge q0 is brought to the centre E of the square, the four charges being held fixed at its corners. How much extra work is needed to do this? FIGURE 2.15 Solution (a) Since the work done depends on the final arrangement of the charges, and not on how they are put together, we calculate work needed for one way of putting the charges at A, B, C and D. Suppose, first the charge +q is brought to A, and then the charges –q, +q, and –q are brought to B, C and D, respectively. The total work needed can be calculated in steps: (i) Work needed to bring charge +q to A when no charge is present elsewhere: this is zero. (ii) Work needed to bring –q to B when +q is at A. This is given by (charge at B) × (electrostatic potential at B due to charge +q at A)  q  q 2 = −q × − ε  4 πε0 d = 4 π 0 d (iii) Work needed to bring charge +q to C when +q is at A and –q is at B. This is given by (charge at C) × (potential at C due to charges at A and B)  + q −q  = + q + ε 0 d   4 πε0 d 2 4 π −q 2  1  = 4 πε0 d 1 − 2  (iv) Work needed to bring –q to D when +q at A,–q at B, and +q at C. This is given by (charge at D) × (potential at D due to charges at A, B and C)  + q −q q  = −q + + ε  4 π 0 d 4 πε0 d 2 4 πε0 d  EXAMPLE −q 2  1  = 4 πε0 d  2 − 2  2.4 57 Reprint 2025-26 Physics Add the work done in steps (i), (ii), (iii) and (iv). The total work required is −q 2   1   1   =  4 πε0 d ( 0 ) + (1) + 1 − 2 +  2 − 2    −q 2 = 4 − 2 ( ) 4 πε0 d The work done depends only on the arrangement of the charges, and not how they are assembled. By definition, this is the total electrostatic energy of the charges. (Students may try calculating same work/energy by taking charges in any other order they desire and convince themselves that the energy will remain the same.) 2.4 the(b) Thefourextrachargesworkarenecessaryat A, B, CtoandbringD ais chargeq0 × (electrostaticq0 to the pointpotentialE whenat E due to the charges at A, B, C and D). The electrostatic potential at E is clearly zero since potential due to A and C is cancelled by that due to B and D. Hence, no work is required to bring any charge to EXAMPLE point E. 2.8 POTENTIAL ENERGY IN AN EXTERNAL FIELD 2.8.1 Potential energy of a single charge In Section 2.7, the source of the electric field was specified – the charges and their locations - and the potential energy of the system of those charges was determined. In this section, we ask a related but a distinct question. What is the potential energy of a charge q in a given field? This question was, in fact, the starting point that led us to the notion of the electrostatic potential (Sections 2.1 and 2.2). But here we address this question again to clarify in what way it is different from the discussion in Section 2.7. The main difference is that we are now concerned with the potential energy of a charge (or charges) in an external field. The external field E is not produced by the given charge(s) whose potential energy we wish to calculate. E is produced by sources external to the given charge(s).The external sources may be known, but often they are unknown or unspecified; what is specified is the electric field E or the electrostatic potential V due to the external sources. We assume that the charge q does not significantly affect the sources producing the external field. This is true if q is very small, or the external sources are held fixed by other unspecified forces. Even if q is finite, its influence on the external sources may still be ignored in the situation when very strong sources far away at infinity produce a finite field E in the region of interest. Note again that we are interested in determining the potential energy of a given charge q (and later, a system of charges) in the external field; we are not interested in the potential energy of the sources producing the external electric field. The external electric field E and the corresponding external potential V may vary from point to point. By definition, V at a point P is the work 58 done in bringing a unit positive charge from infinity to the point P. Reprint 2025-26 Electrostatic Potential and Capacitance (We continue to take potential at infinity to be zero.) Thus, work done in bringing a charge q from infinity to the point P in the external field is qV. This work is stored in the form of potential energy of q. If the point P has position vector r relative to some origin, we can write: Potential energy of q at r in an external field = qV(r) (2.27) where V(r) is the external potential at the point r. Thus, if an electron with charge q = e = 1.6×10–19 C is accelerated by a potential difference of DV = 1 volt, it would gain energy of qDV = 1.6 × 10–19J. This unit of energy is defined as 1 electron volt or 1eV, i.e., 1 eV=1.6 × 10–19J. The units based on eV are most commonly used in atomic, nuclear and particle physics, (1 keV = 103eV = 1.6 × 10–16J, 1 MeV = 106eV = 1.6 × 10–13J, 1 GeV = 109eV = 1.6 × 10–10J and 1 TeV = 1012eV = 1.6 × 10–7J). [This has already been defined on Page 117, XI 2.8.2 Potential energy of a system of two charges in an external field Next, we ask: what is the potential energy of a system of two charges q1 and q2 located at r1and r2, respectively, in an external field? First, we calculate the work done in bringing the charge q1 from infinity to r1. Work done in this step is q1 V(r1), using Eq. (2.27). Next, we consider the work done in bringing q2 to r2. In this step, work is done not only against the external field E but also against the field due to q1. Work done on q2 against the external field = q2 V (r2) Work done on q2 against the field due to q1 q1q 2 = 4 πεo r12 where r12 is the distance between q1 and q2. We have made use of Eqs. (2.27) and (2.22). By the superposition principle for fields, we add up the work done on q2 against the two fields (E and that due to q1): Work done in bringing q2 to r2 q1q 2 = q 2 V ( r2 ) + (2.28) 4 πεo r12 Thus, Potential energy of the system = the total work done in assembling the configuration q1q 2 = q1V ( r1 ) + q 2 V ( r2 ) + (2.29) 4 πε0r12 Example 2.5 (a) Determine the electrostatic potential energy of a system consisting of two charges 7 mC and –2 mC (and with no external field) placed at (–9 cm, 0, 0) and (9 cm, 0, 0) respectively. EXAMPLE (b) How much work is required to separate the two charges infinitely 2.5 away from each other? 59 Reprint 2025-26 Physics (c) Suppose that the same system of charges is now placed in an external electric field E = A (1/r 2); A = 9 × 105 NC–1 m2. What would the electrostatic energy of the configuration be? Solution 1 q1q 2 9 7 × ( −2) × 10 −12 (a) U = = 9 × 10 × = –0.7 J. 4 πε0 r 0.18 (b) W = U2 – U1 = 0 – U = 0 – (–0.7) = 0.7 J. (c) The mutual interaction energy of the two charges remains unchanged. In addition, there is the energy of interaction of the two charges with the external electric field. We find, 7 µ C −µ2 C q1V ( r1 ) + q 2 V ( r2 ) = A + A 0.09m 0.09m 2.5 and the net electrostatic energy is q1q 2 7 µC −µ2 C q1V ( r1 ) + q 2 V ( r2 ) + = A + A − 0.7 J 4 πε0r12 0.09 m 0.09 m EXAMPLE = 70 − 20 − 0.7 = 49.3 J 2.8.3 Potential energy of a dipole in an external field Consider a dipole with charges q1 = +q and q2 = –q placed in a uniform electric field E, as shown in Fig. 2.16. As seen in the last chapter, in a uniform electric field, the dipole experiences no net force; but experiences a torque ttttt given by ttttt ===== p × E (2.30) which will tend to rotate it (unless p is parallel or antiparallel to E). Suppose an external torque text is applied in such a manner that it just neutralises this torque and rotates it in the plane of paper from angle q0 to angle q1 at an infinitesimal angular speed and without angular acceleration. The amount of work done by the external torque will be given by FIGURE 2.16 Potential energy of a dipole in a uniform external field. = pE ( cosθ0 − cosθ1 ) (2.31) This work is stored as the potential energy of the system. We can then associate potential energy U(q) with an inclination q of the dipole. Similar to other potential energies, there is a freedom in choosing the angle where the potential energy U is taken to be zero. A natural choice is to take q0 = p / 2. (An explanation for it is provided towards the end of discussion.) We can then write, (2.32) 60 Reprint 2025-26 Electrostatic Potential and Capacitance This expression can alternately be understood also from Eq. (2.29). We apply Eq. (2.29) to the present system of two charges +q and –q. The potential energy expression then reads q 2 U ′ (θ) = q [V ( r1 ) − V ( r2 )] − (2.33) 4 πε0 × 2a Here, r1 and r2 denote the position vectors of +q and –q. Now, the potential difference between positions r1 and r2 equals the work done in bringing a unit positive charge against field from r2 to r1. The displacement parallel to the force is 2a cosq. Thus, [V(r1)–V (r2)] = –E × 2a cosq . We thus obtain, q 2 q 2 U ′ (θ) = − pE cosθ− = − p.E − (2.34) 4 πε0 × 2a 4 πε0 × 2a We note that U¢(q) differs from U(q ) by a quantity which is just a constant for a given dipole. Since a constant is insignificant for potential energy, we can drop the second term in Eq. (2.34) and it then reduces to Eq. (2.32). We can now understand why we took q0=p/2. In this case, the work done against the external field E in bringing +q and – q are equal and opposite and cancel out, i.e., q [V (r1) – V (r2)]=0. Example 2.6 A molecule of a substance has a permanent electric dipole moment of magnitude 10–29 C m. A mole of this substance is polarised (at low temperature) by applying a strong electrostatic field of magnitude 106 V m–1. The direction of the field is suddenly changed by an angle of 60º. Estimate the heat released by the substance in aligning its dipoles along the new direction of the field. For simplicity, assume 100% polarisation of the sample. Solution Here, dipole moment of each molecules = 10–29 C m As 1 mole of the substance contains 6 × 1023 molecules, total dipole moment of all the molecules, p = 6 × 1023 × 10–29 C m = 6 × 10–6 C m Initial potential energy, Ui = –pE cos q = –6×10–6×106 cos 0° = –6 J Final potential energy (when q = 60°), Uf = –6 × 10–6 × 106 cos 60° = –3 J Change in potential energy = –3 J – (–6J) = 3 J EXAMPLE So, there is loss in potential energy. This must be the energy released by the substance in the form of heat in aligning its dipoles. 2.6