Practice Questions

Q41.Which of the following statements are correct about Zn, Cd and Hg ? A. They exhibit high enthalpy of atomization as the d-subshell is full. B. Zn and Cd do not show variable oxidation state while Hg shows +I and + II. C. Compounds of Zn, Cd and Hg are paramagnetic in nature. D. Zn, Cd and Hg are called soft metals. Choose the most appropriate from the options given below: (1) B, D only (2) B, C only (3) A, D only (4) C, D only

Q41.Given below are two statements: Statement I : Nitration of benzene involves the following step - Statement II : Use of Lewis base promotes the electrophilic substitution of benzene. In the light of the above statements, choose the most appropriate answer from the options given below : JEE Main 2024 (05 Apr Shift 1) JEE Main Previous Year Paper (1) Statement I is correct but Statement II is incorrect(2) Statement I is incorrect but Statement II is correct (3) Both Statement I and Statement II are correct (4) Both Statement I and Statement II are incorrect

Q41.Diamagnetic Lanthanoid ions are: (1) Nd3+ and Eu3+ (2) La3+ and Ce4+ (3) Nd3+ and Ce4+ (4) Lu3+ and Eu3+ JEE Main 2024 (30 Jan Shift 1) JEE Main Previous Year Paper

Q41.Highest enol content will be shown by : JEE Main 2024 (27 Jan Shift 1) JEE Main Previous Year Paper (1) (2) (3) (4)

Q41.Given below are two statements : Statement I : PF5 and BrF5 both exhibit sp3 d hybridisation. Statement II : Both SF6 and [Co(NH3)6]3+ exhibit sp3 d2 hybridisation. In the light of the above statements, choose the correct answer from the options given below : (1) Statement I is true but Statement II is false (2) Statement I is false but Statement II is true (3) Both Statement I and Statement II are true (4) Both Statement I and Statement II are false

Q41.Identify 𝐴 and 𝐵 in the following reaction sequence. (1) (2) (3) (4)

Q41.In Kjeldahl's method for estimation of nitrogen, CuSO4 acts as : (1) Reducing agent (2) Catalytic agent (3) Hydrolysis agent (4) Oxidising agent

Q41.The reaction; 1 2 H2( g) + AgCl(s) →H+(aq) + Cl−(aq) + Ag(s) occurs in which of the following galvanic cell : (1) Ag AgCl(s) KCl(soln.) AgNO3 (aq.) Ag (2) Pt H2( g) HCl(soln.) AgCl(s) Ag (3) Pt H2( g) KCl(soln. ) AgCl(s) Ag (4) Pt H2( g) HCl(soln.) AgNO3(aq) Ag −−

Q41.Choose the correct statements about the hydrides of group 15 elements. A. The stability of the hydrides decreases in the order NH3 > PH3 > AsH3 > SbH3 > BiH3 B. The reducing ability of the hydrides increases in the order NH3 < PH3 < AsH3 < SbH3 < BiH3 C. Among the hydrides, NH3 is strong reducing agent while BiH3 is mild reducing agent. D. The basicity of the hydrides increases in the order NH3 < PH3 < AsH3 < SbH3 < BiH3 Choose the most appropriate from the option given below: (1) B and C only (2) C and D only (3) A and B only (4) A and D only

Q41. In the above chemical reaction sequence " A " and " B " respectively are (1) H2O, H+ and KMnO4 (2) O3, Zn/H2O and NaOH(alc) /I2 (3) O3, Zn/H2O and KMnO4 (4) H2O, H+ and NaOH(alc)/I2

Q41.Match List I with List II List - I (Cell) List - II (Use/Property/Reaction) Converts energy of combustion into electrical A. Leclanche cell I. energy Does not involve any ion in solution and is used Choose the correct B. Ni −Cd cell II. in hearing aids C. Fuel cell III. Rechargeable D. Mercury cell IV. Reaction at anode Zn →Zn2+ + 2e− answer from the options given below: (1) A-II, B-III, C-IV, D-I (2) A-I, B-II, C-III, D-IV (3) A-III, B-I, C-IV, D-II (4) A-IV, B-III, C-I, D-II

Q41.Given below are two statements: Statement I : Gallium is used in the manufacturing of thermometers. Statement II : A thermometer containing gallium is useful for measuring the freezing point (256 K) of brine solution. In the light of the above statements, choose the correct answer from the options given below : (1) Both Statement I and Statement II are true (2) Statement I is false but Statement II is true (3) Both Statement I and Statement II are false (4) Statement I is true but Statement II is false

Q42.Match List-I with List-II List I (Species) List II (Electronic distribution) A. Cr+2 i. 3d8 B. Mn+ ii. 3d34s1 C. Ni+2 iii. . 3d4 D. V+ iv. 3d54s1 Choose the correct answer from the options given below: (1) (A)-I, (B)-II, (C)-III, (D)-IV (2) (A)-III, (B) - IV, (C) - I, (D)-II (3) (A)-IV, (B)-III, (C)-I, (D)-II (4) (A)-II, (B)-I, (C)-IV, (D)-III

Q42.The orange colour of K2Cr2O7 and purple colour of KMnO4 is due to (1) Charge transfer transition in both. (2) d →d transition in KMnO4 and charge transfer transitions in K2Cr2O7. (3) d →d transition in K2Cr2O7 and charge transfer (4) d →d transition in both. transitions in KMnO4. Q43.𝐴 and 𝐵 formed in the following reactions are: CrO2Cl2 + 4NaOH →A + 2NaCl + 2H2O A + 2HCl + 2H2O2 →B + 3H2O (1) A = Na2CrO4, B = CrO5 (2) A = Na2Cr2O4, B = CrO4 (3) A = Na2Cr2O7, B = CrO3 (4) A = Na2Cr2O7, B = CrO5

Q42.On reaction of Lead Sulphide with dilute nitric acid which of the following is not formed? JEE Main 2024 (09 Apr Shift 1) JEE Main Previous Year Paper (1) Nitric oxide (2) Nitrous oxide (3) Lead nitrate (4) Sulphur Q43. 0.05MCuSO4 when treated with 0.01MK2Cr2O7 gives green colour solution of Cu2Cr2O7 . The two solutions are separated as shown below : [SPM : Semi Permeable Membrane] Due to osmosis : (1) Molarity of CuSO4 solution is lowered. (2) Molarity of K2Cr2O7 solution is lowered. (3) Green colour formation observed on side Y. (4) Green colour formation observed on side X.

Q42.For the electro chemical cell If E0 = 0.46 V and E0 = 0.34 V. Which of the following is correct? (M2+/M) (x/X2−) (1) M + X →M2+ + X2− is a spontaneous reaction (2) Ecell = 0.80 V (3) Ecell = −0.80 V (4) M2+ + X2−→M + X is a spontaneous reaction

Q42.The arenium ion which is not involved in the bromination of Aniline is (1) (2) (3) (4)

Q42. List - I List - II Reaction Type of redox reaction (A) TiCl4 (I) e2, t02 Match List - I with List - II. Choose the correct answer from the (B) [FeO4]2− (II) e4, t32 (C) [FeCl4]− (III) e0, t02 (D) [CoCl4]2− (IV) e2, t32 options given below : (1) (A)-(III), (B)-(IV), (C)-(II), (D)-(I) (2) (A)-(IV), (B)-(III), (C)-(I), (D)-(II) (3) (A)-(III), (B)-(I), (C)-(IV), (D)-(II) (4) (A)-(I), (B)-(III), (C)-(IV), (D)-(II)

Q42.Choose the correct statements from the following A. All group 16 elements form oxides of general formula 𝐸𝑂2 and 𝐸𝑂3 where 𝐸= 𝑆, 𝑆𝑒, 𝑇𝑒 and 𝑃𝑜. Both the types of oxides are acidic in nature. B. 𝑇𝑒𝑂2 is an oxidising agent while 𝑆𝑂2 is reducing in nature. C. The reducing property decreases from 𝐻2𝑆 to 𝐻2𝑇𝑒 down the group. D. The ozone molecule contains five lone pairs of electrons. Choose the correct answer from the options given below: (1) A and D only (2) B and C only (3) C and D only (4) A and B only JEE Main 2024 (31 Jan Shift 2) JEE Main Previous Year Paper

Q42.In the given reactions identify A and B . (1) 𝐴 : 2–Pentyne B : trans – 2 – butene (2) A : n – Pentane B : trans – 2 – butene (3) A : 2 – Pentyne B : Cis – 2 – butene (4) A : n – Pentane B : Cis – 2 – butene

Q42.For a reaction A K1→ B K2→ C If the rate of formation of B is set to be zero then the concentration of B is given by : (1) (K1 + K2)[A] (2) (K1/K2)[A] (3) (K1 −K2)[A] (4) K1 K2[ A]

Q42.What will be the decreasing order of basic strength of the following conjugate bases? –– −OH, RO, CH3COO, C–I –––– (1) RO > −OH > CH3COO > C–I (2) C–l > RO > −OH > CH3COO –––– (3) −OH > RO > CH3COO > C–1 (4) C–I > −OH > RO > CH3COO

Q42.For a strong electrolyte, a plot of molar conductivity against (concentration) 1/2 is a straight line, with a negative slope, the correct unit for the slope is (1) Scm2 mol−3/2 L−1/2 (2) Scm2 mol−3/2 L1/2 (3) Scm2 mol−3/2 L (4) Scm2 mol−1 L1/2

Q42.Identify the factor from the following that does not affect electrolytic conductance of a solution. (1) The nature of the electrolyte added. (2) The nature of the electrode used. (3) Concentration of the electrolyte. (4) The nature of solvent used.

Q42.Give below are two statements: Statement I : The higher oxidation states are more stable down the group among transition elements unlike p-block elements. Statement II : Copper can not liberate hydrogen from weak acids. In the light of the above statements, choose the correct answer from the options given below : (1) Both Statement I and Statement II are true (2) Statement I is false but Statement II is true (3) Both Statement I and Statement II are false (4) Statement I is true but Statement II is false