Practice Questions

Q40.Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R. Assertion A : Beryllium has less negative value of reduction potential compared to the other alkaline earth metals Reason R : Beryllium has large hydration energy due to small size of Be2+ but relatively large value of atomisation enthalpy. In the light of the above statements, choose the most appropriate answer from the options given below. (1) A is correct but R is not correct (2) Both A and R are correct and R is the correct explanation of A (3) A is not correct but R is correct (4) Both A and R are correct and R is NOT the correct explanation of A

Q40.When a hydrocarbon A undergoes combustion in the presence of air, it requires 9. 5 equivalents of oxygen and produces 3 equivalents of water. What is the molecular formula of A ? JEE Main 2023 (29 Jan Shift 2) JEE Main Previous Year Paper (1) C8H6 (2) C9H9 (3) C6H6 (4) C9H6

Q40.In the given reaction cycle X, Y and Z respectively are (1) X −CaCO3, Y −NaCl, Z −KCl (2) X −CaCO3, Y −NaCl, Z −HCl (3) X −CaO, Y −NaCl + CO2, Z −NaCl (4) X −CaO, Y −NaCl + CO2, Z −KCl

Q40.In Carius tube, an organic compound ' X ' is treated with sodium peroxide to form a mineral acid ' Y '. The solution of BaCl2 is added to ' Y ' to form a precipitate ' Z '. ' Z ' is used for the quantitative estimation of an JEE Main 2023 (10 Apr Shift 2) JEE Main Previous Year Paper extra element. ' X ' could be (1) Cytosine (2) A nucleotide (3) Methionine (4) Chloroxylenol

Q40.Given below are two statements: Statement I: Chlorine can easily combine with oxygen to from oxides: and the product has a tendency to explode. JEE Main 2023 (01 Feb Shift 1) JEE Main Previous Year Paper Statement II: Chemical reactivity of an element can be determined by its reaction with oxygen and halogens. In the light of the above statements, choose the correct answer from the options given below (1) Both the statements I and II are true (2) Statement I is true but Statement II is false (3) Statement I is false but Statement II is true (4) Both the Statements I and II are false

Q40.Given below are two statements: Statement I: In redox titration, the indicators used are sensitive to change in pH of the solution. Statement II: In acid-base titration, the indicators used are sensitive to change in oxidation potential. In the light of the above statements, choose the most appropriate answer from the options given below (1) Statement I is correct but Statement II is (2) Both Statement I and Statement II are incorrect incorrect (3) Statement I is incorrect but Statement II is (4) Both Statement I and Statement II are correct correct

Q40.Which of the following are the Green house gases? A. Water vapour B.Ozone C.I2 D.Molecular hydrogen Choose the most appropriate answer from the options given below : (1) A and D only (2) B and C only (3) A and B only (4) C and D only

Q40. The correct sequence of reagents for the preparation of Q and R is: (1) (i) Cr2 O3, 770 K, 20 atm ; (ii) (2) (i) CrO2 Cl2, H3O+ ; (ii) CrO2 Cl2, H3O+ ; (iii) NaOH ; (iv) H3O+ Cr2 O3, 770 K, 20 atm; (iii) NaOH; (iv) H3O+ (3) (i) KMnO4, OH− ; (ii) Mo2 O3, Δ; (iii) NaOH; (4) (i) Mo2 O3, Δ; (ii) CrO2 Cl2, H3O+ ; (iii) (iv) H3O+ NaOH; (iv) H3O+

Q40.Identify X, Y and Z in the following reaction. (Equation not balanced) H2O Cl ∙O + NO2 →X ⟶Y + Z ¯ ¯ ¯ (1) X = ClONO2, Y = HOCl, Z = NO2 (2) X = ClNO2, Y = HCl, Z = HNO3 (3) X = ClONO2, Y = HOCl, Z = HNO3 (4) X = ClNO3, Y = Cl2, Z = NO2

Q40.The possibility of photochemical smog formation will be minimum at (1) Srinagar, Jammu and Kashmir in January (2) Kolkata in October (3) Mumbai in May (4) New-Delhi in August (Summer)

Q40.The most stable carbocation for the following is: (1) c (2) d (3) b (4) a

Q40.Given below are two statements : Statement-I : If BOD is 4 ppm and dissolved oxygen is 8 ppm , then it is a good quality water. Statement-II : If the concentration of zinc and nitrate salts are 5 ppm each, then it can be a good quality water. In the light of the above statements, choose the most appropriate answer from the options given below : (1) Statement I is correct but Statement II is (2) Statement I is incorrect but Statement II is incorrect correct (3) Both the statements I and II are incorrect (4) Both the statements I and II are correct

Q40.Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R Assertion A :- Carbon forms two important oxides CO and CO2 . CO is neutral whereas CO2 is acidic in nature. Reason R : CO2 can combine with water in a limited way to form carbonic acid, while CO is sparingly soluble in water. In the light of the above statements, choose the most appropriate answer from the options given below :- (1) Both A and R are correct but R is NOT the (2) Both A and R are correct and R is the correct correct explanation of A. explanation of A. (3) A is not correct but R is correct. (4) A is correct but R is not correct.

Q40.Match List I with List II. List I List II A. Reverberatory furnace I. Pig iron B. Electrolytic cell II. Aluminium C. Blast furnace III. Silicon D. Zone refining furnace IV. Copper JEE Main 2023 (24 Jan Shift 1) JEE Main Previous Year Paper (1) A - IV, B - II, C - I, D - III (2) A - I, B - IV, C - II, D - III (3) A - I, B - III, C - II, D - IV (4) A - III, B - IV, C - I, D - II

Q40.The correct order of bond enthalpy ( kJ mol–1 ) is: (1) Si −Si > C −C > Sn −Sn > Ge −Ge (2) Si −Si > C −C > Ge −Ge > Sn −Sn (3) C −C > Si −Si > Sn −Sn > Ge −Ge (4) C −C > Si −Si > Ge −Ge > Sn −Sn

Q41.The number of s-electrons present in an ion with 55 protons in its unipositive state is (1) 8 (2) 9 (3) 12 (4) 10 JEE Main 2023 (24 Jan Shift 2) JEE Main Previous Year Paper

Q41.Which of the following expressions is correct in case of a CsCl unit cell (edge length ‘ a ’) ? JEE Main 2023 (15 Apr Shift 1) JEE Main Previous Year Paper (1) rCs+ + rCl−= a2 (2) rCs+ + rCl−= √32 a (3) rCs+ + rCl−= a (4) rCs+ + rCl−= a √2

Q41.When 0. 01 mol of an organic compound containing 60% carbon was burnt completely, 4. 4 g of CO2 was produced. The molar mass of compound is _____ gmol−1 (Nearest integer)

Q41.Compound from the following that will not produce precipitate on reaction with AgNO3 is JEE Main 2023 (11 Apr Shift 2) JEE Main Previous Year Paper (1) (2) (3) (4)

Q41.Some reactions of NO2 relevant to photochemical smog formation are Identify A, B, X and Y (1) X = [O], Y = NO, A = O2, B = O3 (2) X = N2O, Y = [O], A = O3, B = NO (3) X = 12 O2, Y = NO2, A = O3, B = O2 (4) X = NO, Y = [O], A = O2, B = N2O3 JEE Main 2023 (25 Jan Shift 1) JEE Main Previous Year Paper

Q41.The difference between electron gain enthalpies will be maximum between : (1) Ne and F (2) Ar and F (3) Ne and Cl (4) Ar and Cl

Q41.Structures of BeCl2 in solid state, vapour phase and at very high temperature respectively are: (1) Monomeric, Dimeric, Polymeric (2) Dimeric, Polymeric, Monomeric (3) Polymeric, Monomeric, Dimeric (4) Polymeric, Dimeric, Monomeric

Q41.Match List I with List II. Choose the correct answer from the options given below :- List I List II Isomeric pairs Type of isomers Propanamine and N- A I Metamers Methylethanamine Hexan-2-one Positional B II Hexan-3-one isomers Ethanamide and C III Functional isomers Hydroxyethanimine D o-nitrophenol and pnitrophenol IV Tautomers (1) A −III, B −IV, C −I, D −II (2) A −IV, B −III, C −I, D −II (3) A −II, B −III, C −I, D −IV (4) A −III, B −I, C −IV, D −II JEE Main 2023 (25 Jan Shift 2) JEE Main Previous Year Paper

Q41.The number of alkali metal(s), from Li, K, Cs, Rb having ionization enthalpy greater than 400 kJ mol−1 and forming stable super oxide is

Q41.When Cu2 + ion is treated with KI, a white precipitate, X appears in solution. The solution is titrated with sodium thiosulphate, the compound Y is formed. X and Y respectively are (1) X = Cu2I2, Y = Na2S4O5 (2) X = Cu2I2, Y = Na2S4O6 (3) X = CuI2, Y = Na2S4O3 (4) X = CuI2, Y = Na2S4O6