Practice Questions

Q35. List - I List - II (Compound/Species) (Shape/Geometry) A. SF4 I. Tetrahedral Match List I with List II Choose the correct B. BrF3 II. Pyramidal C. BrO−3 III. See saw D. NH+4 +KS IV. Bent T-Shape answer from the options given below: (1) A-II, B-III, C-I, D-IV (2) A-II, B-IV, C-III, D-I (3) A-III, B-IV, C-II, D-I (4) A-III, B-II, C-IV, D-I

Q35.Methods used for purification of organic compounds are based on : (1) nature of compound and presence of impurity. (2) neither on nature of compound nor on the impurity present. (3) nature of compound only. (4) presence of impurity only.

Q35.The incorrect statement regarding conformations of ethane is: (1) Ethane has infinite number of conformations (2) The dihedral angle in staggered conformation is 60° (3) Eclipsed conformation is the most stable (4) The conformations of ethane are interconvertible conformation. to one-another

Q35. KMnO4 decomposes on heating at 513 K to form O2 along with (1) MnO2 & K2O2 (2) K2 MnO4 & Mn (3) Mn & KO2 (4) K2 MnO4 & MnO2

Q35.Choose the correct option for free expansion of an ideal gas under adiabatic condition from the following : (1) q = 0, ΔT ≠0, w = 0 (2) q = 0, ΔT < 0, w ≠0 (3) q ≠0, ΔT < 0, w = 0 (4) q = 0, ΔT = 0, w = 0

Q35.Evaluate the following statements related to group 14 elements for their correctness. (A) Covalent radius decreases down the group from C to Pb in a regular manner. (B) Electronegativity decreases from C to Pb down the group gradually. (C) Maximum covalance of C is 4 whereas other elements can expand their covalance due to presence of d orbitals. (D) Heavier elements do not form pπ −pπ bonds. (E) Carbon can exhibit negative oxidation states. Choose the correct answer from the options given below : (1) (A), (B) and (C) Only (2) (C), (D) and (E) Only (3) (C) and (D) Only (4) (A) and (B) Only

Q36.Match List - I with List - II. List - I Compound List-II Use (A) Carbon tetrachloride (I) Paint remover (B) Methylene chloride (II) Refrigerators and air conditioners (C) DDT (III) Fire extinguisher (D) Freons (IV) Non Biodegradable insecticide Choose the correct answer from the options given below: (1) (A)-(I), (B), (II), (C)-(III), (D)-(IV) (2) (A)-(III), (B)-(I), (C)-(IV), (D)-( II) (3) (A)-(IV), (B)-(III), (C)-(II), (D)-(I) (4) (A)-( II), (B)-(III), (C)-(I), (D)-(IV)

Q36.The correct sequence of acidic strength of the following aliphatic acids in their decreasing order is: CH3CH2COOH, CH3COOH, CH3CH2CH2COOH, HCOOH JEE Main 2024 (08 Apr Shift 2) JEE Main Previous Year Paper (1) CH3CH2CH2COOH > CH3CH2COOH > CH3COOH > HCOOH (2) CH3COOH > CH3CH2COOH > CH3CH2CH2COOH > HCOOH (3) HCOOH > CH3COOH > CH3CH2COOH > CH3CH2CH2COOH (4) HCOOH > CH3CH2CH2COOH > CH3CH2COOH > CH3COOH

Q36.The incorrect statement regarding ethyne is (1) The C −C bonds in ethyne is shorter than that in (2) Both carbons are sp hybridised ethene (3) Ethyne is linear (4) The corbon - carbon bonds in ethyne is weaker than that in ethene

Q36. Correct order of basic strength of Pyrrole , Pyridine , and Piperidine is: (1) Pyrrole > Piperidine > Pyridine (2) Pyrrole > Pyridine > Piperidine (3) Pyridine > Piperidine > Pyrrole (4) Piperidine > Pyridine > Pyrrole

Q36.The correct statements from the following are : (A) The decreasing order of atomic radii of group 13 elements is Tl > In > Ga > Al > B . (B) Down the group 13 electronegativity decreases from top to bottom. (C) Al dissolves in dil. HCl and liberates H2 but conc. HNO3 renders Al passive by forming a protective oxide layer JEE Main 2024 (05 Apr Shift 2) JEE Main Previous Year Paper on the surface. (D) All elements of group 13 exhibits highly stable +1 oxidation state. (E) Hybridisation of Al in [Al(H2O)6]3+ ion is sp3 d2 . Choose the correct answer from the options given below : (1) (A), (C) and (E) only (2) (A) and (C) only (3) (C) and (E) only (4) (A), (B), (C) and (E) only

Q36.Which of the following nitrogen containing compound does not give Lassaigne's test? JEE Main 2024 (04 Apr Shift 1) JEE Main Previous Year Paper (1) Urea (2) Phenyl hydrazine (3) Glycene (4) Hydrazine

Q36.The correct statement among the following, for a "chromatography" purification method is : (1) Organic compounds run faster than solvent in the (2) Rf is an integral value. thin layer chromatographic plate. (3) Rf of a polar compound is smaller than that of a (4) Non-polar compounds are retained at top and non-polar compound. polar compounds come down in column chromatography.

Q36. X ⇌Y; K1 = 1.0 For the given hypothetical reactions, the equilibrium constants are as follows : Y ⇌Z; K2 = 2.0 The Z ⇌W; K3 = 4.0 equilibrium constant for the reaction X ⇌W is (1) 6.0 (2) 12.0 (3) 7.0 (4) 8.0

Q36. List - I List - II (Molecule/Species) (Property/Shape) A. SO2Cl2 I. Paramagnetic Match List I with List II Choose the correct answer B. NO II. Diamagnetic C. NO−2 III. Tetrahedral D. I−3 IV. Linear from the options given below: (1) A-II, B-III, C-I, D-IV (2) A-III, B-I, C-II, D-IV (3) A-IV, B-I, C-III, D-II (4) A-III, B-IV, C-II, D-I

Q36.The following reaction occurs in the Blast furnance where iron ore is reduced to iron metal Fe2O3( s) + 3CO(g) ⇌Fe(l) + 3CO2( g) Using the Le-chatelier's principle, predict which one of the following will not disturb the equilibrium. (1) Addition of CO2 (2) Removal of CO2 (3) Addition of Fe2O3 (4) Removal of CO

Q36.The equilibrium constant for the reaction SO3(g) ⇌SO2( g) + 12 O2( g) is Kc = 4.9 × 10−2 . The value of Kc for the reaction given below is 2SO2( g) + O2( g) ⇌2SO3( g) is : (1) 4.9 (2) 49 (3) 41.6 (4) 416

Q36.The correct stability order of carbocations is (1) + + + (2) + + + + CH33C+ > CH3 - CH2 > CH32 CH > CH3 CH3 > CH32 CH > CH3 - CH2 > CH33 C (3) + + + + (4) $\stackrel{+\quad} CH33 C > CH32 CH > CH3 - CH2 > CH3 {\mathrm{C}\mathrm{H}_3}>\mathrm{CH}_3- \stackrel{+ \quad}{\mathrm{C} \mathrm{H}_2}>\mathrm{CH}_3-\underset{| \atop \stackrel{ \atop }{\huge \mathrm{CH}_3}} {\stackrel{+ \quad}{\mathrm{C} \mathrm{H}}}>\left(\mathrm{CH}_3\right) \mathrm{C}^{+}$

Q36.Match List I with List II Choose the correct answer from the options given below: (1) A-I, B-II, C-III, D-IV (2) A-IV, B-I, C-II, D-III (3) A-III, B-IV, C-I, D-II (4) A-II, B-I, C-IV, D-III

Q36.The technique used for purification of steam volatile water immiscible substance is: (1) Fractional distillation (2) Fractional distillation under reduced pressure (3) Distillation (4) Steam distillation

Q36.Given below are two statements : Statement I: S8 solid undergoes disproportionation reaction under alkaline conditions to form S2 − and S2O32 − Statement II: ClO4− can undergo disproportionation reaction under acidic condition. In the light of the above statements, choose the most appropriate answer from the options given below: (1) Statement I is correct but statement II is (2) Statement I is incorrect but statement II is correct incorrect. (3) Both statement I and statement II are incorrect (4) Both statement I and statement II are correct JEE Main 2024 (31 Jan Shift 2) JEE Main Previous Year Paper

Q36.Which of the following reactions are disproportionation reactions? 1 Cu+ →Cu2 + + Cu 2 3MnO42 - + 4H+ →2MnO4- + MnO2 + 2H2O 3 2KMnO4 →K2MnO4 + MnO2 + O2 4 2MnO4- + 3Mn2 + + 2H2O →5MnO2 + 4H+ Choose the correct answer from the options given below: (1) 1, 2 (2) 2, 3, 4 (3) 1, 2, 4 (4) 1, 4

Q37. IUPAC name of following hydrocarbon (X) is : (1) 2-Ethyl-3,6-dimethylheptane (2) 2,5,6-Trimethyloctane (3) 3,4,7-Trimethyloctane (4) 2-Ethyl-2,6-diethylheptane

Q37.Which among the following is incorrect statement? (1) Electromeric effect dominates over inductive (2) The electromeric effect is, temporary effect effect (3) Hydrogen ion (H+)shows negative electromeric (4) The organic compound shows electromeric effect effect in the presence of the reagent only.

Q37. For the given compounds, the correct order of increasing pKa value : Choose the correct answer from the options given below : (1) (B) < (D) < (C) < (A) < (E) (2) (D) < (E) < (C) < (B) < (A) (3) (E) < (D) < ( C ) < ( B ) < ( A ) (4) (E) < (D) < (B) < (A) < (C) JEE Main 2024 (09 Apr Shift 1) JEE Main Previous Year Paper