Practice Questions

Q47.Which one the following compounds will readily react with dilute NaOH ? (1) C2H5OH (2) C6H5OH (3) C6H5CH2OH (4) (CH3)3COH

Q47.Identify A and B in the following sequence of reaction (1) (2) (3) (4)

Q47.Given below are two statements: Statement - I: High concentration of strong nucleophilic reagent with secondary alkyl halides which do not have bulky substituents will follow SN2 mechanism. Statement - II: A secondary alkyl halide when treated with a large excess of ethanol follows SN1 mechanism. In the the light of the above statements, choose the most appropriate from the questions given below: (1) Statement I is true but Statement II is false. (2) Statement I is false but Statement II is true. (3) Both statement I and Statement II are false. (4) Both statement I and Statement II are true.

Q47.In which one of the following metal carbonyls, CO forms a bridge between metal atoms? (1) [Co2(CO)8] (2) [Mn2(CO)10] (3) [Os3(CO)12] (4) [Ru3(CO)12]

Q47.The number of unpaired d-electrons in [Co(H2O)6]3+ is (1) 2 (2) 1 (3) 0 (4) 4

Q47.Consider the following complex ions P = [FeF6]3– , Q = [V(H2O) 6]2+ , R = [Fe(H2O)6]2+ The correct order of the complex ions, according to their spin only magnetic moment values (in B.M.) is : JEE Main 2024 (27 Jan Shift 1) JEE Main Previous Year Paper (1) R < Q < P (2) R < P < Q (3) Q < R < P (4) Q < P < R

Q47.Identify the name reaction. (1) Stephen reaction (2) Etard reaction (3) Gatterman-koch reaction (4) Rosenmund reduction

Q47.Phenolic group can be identified by a positive: (1) Phthalein dye test (2) Lucas test (3) Tollen’s test (4) Carbylamine test

Q47.Identify the major product in the following reaction. (1) (2) (3) (4)

Q47.The product A formed in the following reaction is: JEE Main 2024 (29 Jan Shift 2) JEE Main Previous Year Paper (1) (2) (3) (4)

Q47.Identify the major products A and B respectively in the following set of reactions. (1) (2) (3) (4)

Q47.In Reimer - Tiemann reaction, phenol is converted into salicylaldehyde through an intermediate. The structure of intermediate is _____ (1) (2) (3) (4)

Q48. Consider the above reaction sequence and identify the major product P . (1) Methoxymethane (2) Methanoic acid (3) Methanal (4) Methane

Q48.Identify major product ‘𝑃’ formed in the following reaction. JEE Main 2024 (31 Jan Shift 2) JEE Main Previous Year Paper (1) (2) (3) (4)

Q48.The correct statement regarding nucleophilic substitution reaction in a chiral alkyl halide is ; (1) Retention occurs in SNl reaction and inversion (2) Racemisation occurs in SNl reaction and occurs in SN2 reaction. retention occurs in SN2 reaction. (3) Racemisation occurs in both SN1 and SN2 (4) Racemisation occurs in SN1 reaction and reactions. inversion occurs in SN2 reaction.

Q48.During the detection of acidic radical present in a salt, a student gets a pale yellow precipitate soluble with difficulty in NH4OH solution when sodium carbonate extract was first acidified with dil. HNO3 and then AgNO3 solution was added. This indicates presence of : (1) Br− (2) I− (3) Cl− (4) CO32− JEE Main 2024 (06 Apr Shift 2) JEE Main Previous Year Paper

Q48. Identify the product (P) in the following reaction: JEE Main 2024 (08 Apr Shift 1) JEE Main Previous Year Paper (1) (2) (3) (4)

Q48.CoNH36 3 + and CoF6 3 - are respectively known as: (1) Spin free Complex, Spin paired Complex (2) Spin paired Complex, Spin free Complex (3) Outer orbital Complex, Inner orbital Complex (4) Inner orbital Complex, Spin paired Complex

Q48. C2H5OH−CH3 −CH2 −CH2 −Br + NaOH → Product 'A' Consider the above reactions, identify product B and product C . (1) B = 1-Propanol C = 2-Propanol (2) B = C = 2-Propanol (3) B = 2-Propanol C = 1-Propanol (4) B = C = 1-Propanol

Q48. Identify the product in the following reaction : (1) (2) (3) (4)

Q48.Match List-I with List-II. List I (Reaction) List II (Reagent(s)) (A) (I) Na2Cr2O7 / H2SO4 (B) (II) (i) NaOH (ii) CH3Cl (i)NaOH, CHCl3 (C) (III) (ii) NaOH (iii) HCl (i) NaOH (ii) CO2 (D) (IV) (iii) HCl Choose the correct answer from the options given below: (1) (A)-(IV), (B)-(I), (C)-(III), (D)-(II) (2) (A)-(II), (B)-(III), (C)-(I), (D)-(IV) (3) (A)-(II), (B)-(I), (C)-(III), (D)-(IV) (4) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)

Q48.On passing a gas, ' X ', through Nessler's reagent, a brown precipitate is obtained. The gas ' X ' is (1) H2S (2) CO2 (3) NH3 (4) Cl2

Q48.Match List – I with List –II. JEE Main 2024 (01 Feb Shift 1) JEE Main Previous Year Paper Choose the correct answer from options given below: (1) A - III, B - IV, C - I, D - II (2) A - IV, B - II, C - I, D - III (3) A - IV, B - II, C - III, D - I (4) A - III, B - IV, C - II, D - I

Q48.Which among the following aldehydes is most reactive towards nucleophilic addition reactions? JEE Main 2024 (06 Apr Shift 1) JEE Main Previous Year Paper (1) (2) (3) (4)

Q48. (Test) (Identification) (A) Bayer's test MARKS (I) Phenol VIARKS Match List - I with List - II. (B) Ceric ammonium nitrate test (II) Aldehyde (C) Phthalein dye test R K (III) Alcoholic-OH group (D) Schiff's test (IV) Unsaturation Choose the correct answer from the options given below : (1) (A)-(IV), (B)-(III), (C)-(I), (D)-(II) (2) (A)-(II), (B)-(III), (C)-(IV), (D)-(I) (3) (A)-(IV), (B)-(I), (C)-(II), (D)-(III) (4) (A)-(III), (B)-(I), (C)-(IV), (D)-(II) JEE Main 2024 (08 Apr Shift 2) JEE Main Previous Year Paper