Practice Questions

Q56.One Faraday of electricity liberates x × 10 – 1 gram atom of copper from copper sulphate, x is______.

Q56.Consider the following single step reaction in gas phase at constant temperature. 2 A(g) + B(g) →C(g) The initial rate of the reaction is recorded as r1 when the reaction starts with 1.5 atm pressure of A and 0.7 atm pressure of B . After some time, the rate r2 is recorded when the pressure of C becomes 0.5 atm. The ratio r1 : r2 is ______ ×10−1 . (Nearest integer) JEE Main 2024 (05 Apr Shift 2) JEE Main Previous Year Paper

Q56.r = kA for a reaction, 50% of A is decomposed in 120 minutes. The time taken for 90% decomposition of A is ______ minutes.

Q56.Consider the following reaction A + B →C The time taken for A to become 1/4th of its initial concentration is twice the time taken to become 1/2 of the same. Also, when the change of concentration of B is plotted against time, the resulting graph gives a straight JEE Main 2024 (08 Apr Shift 1) JEE Main Previous Year Paper line with a negative slope and a positive intercept on the concentration axis. The overall order of the reaction is _______

Q56.The vapour pressure of pure benzene and methyl benzene at 27∘C is given as 80 Torr and 24 Torr, respectively. The mole fraction of methyl benzene in vapour phase, in equilibrium with an equimolar mixture of those two liquids (ideal solution) at the same temperature is _______ ×10−2 (nearest integer)

Q56.During Kinetic study of reaction 2A + B →C + D , the following results were obtained : A [M] B [M] initial rate of formation of D I 0.1 0.1 6.0 × 10−3 II 0.3 0.2 7.20 × 10−2 Based on above data, overall order of the reaction is III 0.3 0.4 2.88 × 10−1 IV 0.4 0.1 2.40 × 10−2 ______

Q56.If 50 mL of 0. 5M oxalic acid is required to neutralise 25 mL of NaOH solution, the amount of NaOH in 50 mL of given NaOH solution is_______g. JEE Main 2024 (29 Jan Shift 2) JEE Main Previous Year Paper

Q56.A solution of H2 SO4 is 31. 4% H2 SO4 by mass and has a density of 1. 25 g/ mL. The molarity of the H2 SO4 solution is M (nearest integer) [Given molar mass of H2 SO4 = 98 g mol−1 ]

Q56.Consider the following reaction, the rate expression of which is given below A + B →C rate = k[A]1/2[ B]1/2 The reaction is initiated by taking 1M concentration of A and B each. If the rate constant (k) is 4.6 × 10−2 s−1 , then the time taken for A to become 0.1M is ______ sec. (nearest integer)

Q57.Consider the following transformation involving first order elementary reaction in each step at constant Step 2 −temperature as shown below. A + B Step 1C → P Some details of the above reactions are listed below. Step 3 Step Rate constant (sec−1) Activation energy (kJ mol−1) 1 k1 300 If the overall rate constant of the above 2 k2 200 3 k3 Ea3 transformation (k) is given as k = k1k2 and the overall activation energy (Ea) is 400 kJ mol−1 , then the value k3 of Ea3 is kJmol−1 (nearest integer)

Q57.Number of moles of H+ ions required by 1 mole of MnO4− to oxidise oxalate ion to CO2 is ______.

Q57.Total number of compounds with Chiral carbon atoms from following is CH3 - CH2 - CHNO2 - COOH CH3 - CH ( I ) - CH2 - NO2 CH3 - CH2 - CHBr - CH2 - CH3 CH3 - CH2 - CH ( OH ) - CH2OH JEE Main 2024 (27 Jan Shift 2) JEE Main Previous Year Paper

Q57.Among CrO, Cr2O3 and CrO3 , the sum of spin-only magnetic moment values of basic and amphoteric oxides is _______ 10−2BM (nearest integer). (Given atomic number of Cr is 24)

Q57.Molality of 0. 8M H2 SO4 solution (density 1. 06 g cm−3 ) is _______ ×10−3 m . Round off your answer to the nearest integer.

Q57.Number of carbocations from the following that are not stabilized by hyperconjugation is _______

Q57.The potential for the given half cell at 298K is - ............ × 10-2V . 2H + + 2e- →H2 ( g) ( aq ) H+ = 1M, PH2 = 2 atm (Given2 . 303 RT / F = 0 . 06 V, log2 = 0 . 3)

Q57.Molality of an aqueous solution of urea is 4.44 m. Mole fraction of urea in solution is x × 10−3 . Value of x is - (Integer answer)

Q57.The osmotic pressure of a dilute solution is 7 × 105 Pa at 273 K. Osmotic pressure of the same solution at 283 K is _______ × 104 Nm−2 .(Nearest integer)

Q57.Given below are two statements : Statement I: The rate law for the reaction A + B →C is rate (r) = k[A]2[B] . When the concentration of both A and B is doubled, the reaction rate is increased " x " times. Statement II : JEE Main 2024 (09 Apr Shift 1) JEE Main Previous Year Paper The figure is showing "the variation in concentration against time plot" for a " y " order reaction. The Value of x + y is ______

Q57.The spin-only magnetic moment value of the ion among Ti2+, V2+, Co3+ and Cr2+ , that acts as strong oxidising agent in aqueous solution is _______ BM (Near integer). (Given atomic numbers : Ti : 22, V : 23, Cr : 24, Co : 27)

Q57.Consider the following redox reaction: MnO4- + H+ + H2C2O4 ⇌Mn2 + + H2O + CO2 The standard reduction potentials are given as below Ered° E0 = + 1 . 51 V; E0 = - 0 . 49 V CO2 / H2C2O4 MnO4- / Mn2 + If the equilibrium constant of the above reaction is given as Keq = 10x, then the value of x = _______ (nearest integer)

Q57.The fusion of chromite ore with sodium carbonate in the presence of air leads to the formation of products A and B along with the evolution of CO2 . The sum of spin-only magnetic moment values of A and B is ______ B.M. (Nearest integer) [Given atomic number : C : 6, Na : 11, O : 8, Fe : 26, Cr : 24]

Q57.Consider the following first order gas phase reaction at constant temperature A(g) →2 B( g) + C(g) If the total pressure of the gases is found to be 200 torr after 23sec. and 300 torr upon the complete decomposition of A after a very long time, then the rate constant of the given reaction is ______ ×10−2 s−1 (nearest integer) [Given : log10(2) = 0.301]

Q57.The 'spin only' magnetic moment value of MO42− is _______ BM. (Where M is a metal having least metallic radii. among Sc, Ti, V, Cr, Mn and Zn ). (Given atomic number: Sc = 21, Ti = 22, V = 23, Cr = 24, Mn = 25 and Zn = 30)

Q57.On a thin layer chromatographic plate, an organic compound moved by 3. 5 cm, while the solvent moved by 5 cm . The retardation factor of the organic compound is _____________ ×10−1