14.1 In an n-type silicon, which of the following statement is true: (a) Electrons are majority carriers and trivalent atoms are the dopants. (b) Electrons are minority carriers and pentavalent atoms are the dopants. (c) Holes are minority carriers and pentavalent atoms are the dopants. (d) Holes are majority carriers and trivalent atoms are the dopants.

9.4 Alkynes 1 2 3 4 5 Like alkenes, alkynes are also unsaturated II. H3C–C≡ C– CH2– CH3 Pent–2-yne hydrocarbons. They contain at least one triple 4 3 2 1 bond between two carbon atoms. The number III. H3C–CH–C≡ CH 3-Methyl but–1-yne |of hydrogen atoms is still less in alkynes as CH3compared to alkenes or alkanes. Their general Structures I and II are position isomers formula is CnH2n–2. and structures I and III or II and III are chain The first stable member of alkyne series isomers. is ethyne which is popularly known as acetylene. Acetylene is used for arc welding Problem 9.13 purposes in the form of oxyacetylene flame Write structures of different isomers obtained by mixing acetylene with oxygen corresponding to the 5 th member of gas. Alkynes are starting materials for a large alkyne series. Also write IUPAC names of number of organic compounds. Hence, it all the isomers. What type of isomerism is interesting to study this class of organic is exhibited by different pairs of isomers? compounds. Solution 9.4.1 Nomenclature and Isomerism th 5 member of alkyne has the molecular In common system, alkynes are named as formula C6H10. The possible isomers are: derivatives of acetylene. In IUPAC system, they Table 9.2 Common and IUPAC Names of Alkynes (CnH2n–2) Value of n Formula Structure Common name IUPAC name 2 C2H2 H-C≡CH Acetylene Ethyne 3 C3H4 CH3-C≡CH Methylacetylene Propyne 4 C4H6 CH3CH2-C≡CH Ethylacetylene But-1-yne 4 C4H6 CH3-C≡C-CH3 Dimethylacetylene But-2-yne Reprint 2025-26 Hydrocarbons 315 (a) HC ≡ C – CH2 – CH2 – CH2 – CH3 Hex-1-yne (b) CH3 – C ≡ C – CH2 – CH2 – CH3 Hex-2-yne (c) CH3 – CH2 – C ≡ C – CH2– CH3 Hex-3-yne 3-Methylpent-1-yne 4-Methylpent-1-yne 4-Methylpent-2-yne Fig. 9.6 Orbital picture of ethyne showing (a) sigma overlaps (b) pi overlaps. orbitals of the other carbon atom, which undergo lateral or sideways overlapping to 3,3-Dimethylbut-1-yne form two pi (π) bonds between two carbon atoms. Thus ethyne molecule consists of one Position and chain isomerism shown by C–C σ bond, two C–H σ bonds and two C–C different pairs. π bonds. The strength of C≡C bond (bond enthalpy 823 kJ mol -1) is more than those 9.4.2 Structure of Triple Bond of C=C bond (bond enthalpy 681 kJ mol –1) Ethyne is the simplest molecule of alkyne and C–C bond (bond enthalpy 348 kJ mol–1). series. Structure of ethyne is shown in The C≡C bond length is shorter (120 pm) Fig. 9.6. than those of C=C (133 pm) and C–C (154 pm). Electron cloud between two carbon Each carbon atom of ethyne has two sp atoms is cylindrically symmetrical about thehybridised orbitals. Carbon-carbon sigma (σ) internuclear axis. Thus, ethyne is a linear bond is obtained by the head-on overlapping molecule. of the two sp hybridised orbitals of the two carbon atoms. The remaining sp hybridised 9.4.3 Preparation orbital of each carbon atom undergoes 1. From calcium carbide: On industrial overlapping along the internuclear axis with scale, ethyne is prepared by treating the 1s orbital of each of the two hydrogen calcium carbide with water. Calcium atoms forming two C-H sigma bonds. carbide is prepared by heating quick lime H-C-C bond angle is of 180°. Each carbon with coke. Quick lime can be obtained byhas two unhybridised p orbitals which are heating limestone as shown in the followingperpendicular to each other as well as to the reactions:plane of the C-C sigma bond. The 2p orbitals of one carbon atom are parallel to the 2p CaCO3 ∆ CaO + O2 (9.55) Reprint 2025-26 316 chemistry CaO + 3C CaC2 + CO (9.56) the sp hybridised carbon2 atoms whereas they are attached to sp hybridised carbon Calcium 3 atoms in ethene and sp hybridised carbons carbide in ethane. Due to the maximum percentage of CaC2 + 2H2O Ca(OH)2 + C2H2 (9.57) s character (50%), the sp hybridised orbitals of carbon atoms in ethyne molecules have2. From vicinal dihalides : Vicinal dihalides highest electronegativity; hence, these attract on treatment with alcoholic potassium the shared electron pair of the C-H bond of hydroxide undergo dehydrohalogenation. ethyne to a greater extent than that of the One molecule of hydrogen halide is 2 sp hybridised orbitals of carbon in ethene eliminated to form alkenyl halide which 3 and the sp hybridised orbital of carbon in on treatment with sodamide gives alkyne. ethane. Thus in ethyne, hydrogen atoms can be liberated as protons more easily as compared to ethene and ethane. Hence, hydrogen atoms of ethyne attached to triply bonded carbon atom are acidic in nature. You may note that the hydrogen atoms attached to the triply bonded carbons are acidic but not all the hydrogen atoms of alkynes. HC ≡ CH + Na → HC ≡ C–Na++ 1/2 H2 9.4.4 Properties Monosodium Physical properties ethynide Physical properties of alkynes follow the same (9.59) trend of alkenes and alkanes. First three HC ≡ C– Na + Na → Na+ C–Na+ ≡ C–Na++ 1/2 H2members are gases, the next eight are liquids and the higher ones are solids. All alkynes Disodium ethynide are colourless. Ethyene has characteristic (9.60)odour. Other members are odourless. Alkynes are weakly polar in nature. They are lighter CH3 – C ≡ C – H + Na+ NH–2 than water and immiscible with water but ↓ soluble in organic solvents like ethers, carbon CH3 – C ≡ C– Na+ + NH3 tetrachloride and benzene. Their melting Sodium propynide (9.61) point, boiling point and density increase with These reactions are not shown by alkenesincrease in molar mass. and alkanes, hence used for distinction Chemical properties between alkynes, alkenes and alkanes. What Alkynes show acidic nature, addition reactions about the above reactions with but-1-yne and and polymerisation reactions as follows : but-2-yne ? Alkanes, alkenes and alkynes A. Acidic character of alkyne: Sodium follow the following trend in their acidic metal and sodamide (NaNH2) are strong behaviour : bases. They react with ethyne to form sodium i) CH ≡ CH > H2C – CH2 > CH3 –CH3acetylide with the liberation of dihydrogen gas. These reactions have not been observed ii) HC ≡ CH > CH3 –C≡ CH >> CH3 –C≡C–CH3in case of ethene and ethane thus indicating that ethyne is acidic in nature in comparison B. Addition reactions: Alkynes contain a to ethene and ethane. Why is it so ? Has triple bond, so they add up, two molecules of it something to do with their structures dihydrogen, halogen, hydrogen halides etc. and the hybridisation ? You have read that Formation of the addition product takes place hydrogen atoms in ethyne are attached to according to the following steps. Reprint 2025-26 Hydrocarbons 317 The addition product formed depends upon stability of vinylic cation. Addition in unsymmetrical alkynes takes place according to Markovnikov rule. Majority of the reactions of alkynes are the examples of electrophilic addition reactions. A few addition reactions (9.66)are given below: (i) Addition of dihydrogen (iv) Addition of water Pt/Pd/Ni H2 Like alkanes and alkenes, alkynes are alsoHC≡CH+H2 [H2C = CH2] CH3–CH3 immiscible and do not react with water. (9.62) However, one molecule of water adds to alkynes on warming with mercuric sulphate CH3–C≡CH + H2 Pt/Pd/Ni [CH3–CH=CH2] and dilute sulphuric acid at 333 K to form Propyne Propene carbonyl compounds. ↓H2 CH3–CH2–CH3 Propane (9.63) (ii) Addition of halogens (9.67) (9.64) Reddish orange colour of the solution of bromine in carbon tetrachloride is decolourised. This is used as a test for unsaturation. (iii) Addition of hydrogen halides (9.68) Two molecules of hydrogen halides (HCl, HBr, (v) Polymerisation HI) add to alkynes to form gem dihalides (in (a) Linear polymerisation: Under suitable which two halogens are attached to the same conditions, linear polymerisation of ethyne carbon atom) takes place to produce polyacetylene or H–C≡C–H+H–Br [CH2 = CH–Br]→ CHBr2 polyethyne which is a high molecular Bromoethene weight polyene containing repeating units of CH3 (CH = CH – CH = CH ) and can be represented 1,1-Dibromoethane as —(CH = CH – CH = CH)n— Under special (9.65) conditions, this polymer conducts electricity. Reprint 2025-26 318 chemistry Thin film of polyacetylene can be used as but in a majority of reactions of aromatic electrodes in batteries. These films are good compounds, the unsaturation of benzene ring conductors, lighter and cheaper than the is retained. However, there are examples of metal conductors. aromatic hydrocarbons which do not contain a (b) Cyclic polymerisation: Ethyne on benzene ring but instead contain other highly unsaturated ring. Aromatic compoundspassing through red hot iron tube at 873K containing benzene ring are known asundergoes cyclic polymerization. Three benzenoids and those not containing amolecules polymerise to form benzene, which benzene ring are known as non-benzenoids.is the starting molecule for the preparation of Some examples of arenes are givenderivatives of benzene, dyes, drugs and large below:number of other organic compounds. This is the best route for entering from aliphatic to aromatic compounds as discussed below: Benzene Toluene Naphthalene (9.69) Biphenyl Problem 9.14 How will you convert ethanoic acid into 9.5.1 Nomenclature and Isomerism benzene? The nomenclature and isomerism of aromatic Solution hydrocarbons has already been discussed in Unit 8. All six hydrogen atoms in benzene are equivalent; so it forms one and only one type of monosubstituted product. When two hydrogen atoms in benzene are replaced by two similar or different monovalent atoms or groups, three different position isomers are possible. The 1, 2 or 1, 6 is known as the ortho (o–), the 1, 3 or 1, 5 as meta (m–) and the 1, 4 as para (p–) disubstituted compounds. A few examples of derivatives of benzene are given below:

1.4 DIMENSIONS OF PHYSICAL QUANTITIES formula of the given physical quantity. For example, the dimensional formula of the volume The nature of a physical quantity is described is [M° L3 T°], and that of speed or velocity is by its dimensions. All the physical quantities [M° L T-1]. Similarly, [M° L T–2] is the dimensional represented by derived units can be expressed formula of acceleration and [M L–3 T°] that of in terms of some combination of seven mass density. fundamental or base quantities. We shall call An equation obtained by equating a physical these base quantities as the seven dimensions quantity with its dimensional formula is called of the physical world, which are denoted with the dimensional equation of the physical square brackets [ ]. Thus, length has the quantity. Thus, the dimensional equations are dimension [L], mass [M], time [T], electric current the equations, which represent the dimensions [A], thermodynamic temperature [K], luminous of a physical quantity in terms of the base intensity [cd], and amount of substance [mol]. quantities. For example, the dimensional The dimensions of a physical quantity are the equations of volume [V], speed [v], force [F ] and powers (or exponents) to which the base mass density [ρ] may be expressed as quantities are raised to represent that [V] = [M0 L3 T0] quantity. Note that using the square brackets [v] = [M0 L T–1] [ ] round a quantity means that we are dealing [F] = [M L T–2] with ‘the dimensions of’ the quantity. [ρ] = [M L–3 T0] In mechanics, all the physical quantities can be written in terms of the dimensions [L], [M] The dimensional equation can be obtained and [T]. For example, the volume occupied by from the equation representing the relations between the physical quantities. Thean object is expressed as the product of length, dimensional formulae of a large number andbreadth and height, or three lengths. Hence the wide variety of physical quantities, derived fromdimensions of volume are [L] × [L] × [L] = [L]3 = [L3]. the equations representing the relationships As the volume is independent of mass and time, among other physical quantities and expressed it is said to possess zero dimension in mass [M°], in terms of base quantities are given in zero dimension in time [T°] and three Appendix 9 for your guidance and ready dimensions in length. reference. Similarly, force, as the product of mass and acceleration, can be expressed as 1.6 DIMENSIONAL ANALYSIS AND ITS Force = mass × acceleration APPLICATIONS = mass × (length)/(time)2 The recognition of concepts of dimensions, which The dimensions of force are [M] [L]/[T]2 = guide the description of physical behaviour is [M L T–2]. Thus, the force has one dimension in of basic importance as only those physical Reprint 2025-26 8 PHYSICS quantities can be added or subtracted which such as angle as the ratio (length/length), have the same dimensions. A thorough refractive index as the ratio (speed of light in understanding of dimensional analysis helps us vacuum/speed of light in medium) etc., has no in deducing certain relations among different dimensions. physical quantities and checking the derivation, Now we can test the dimensional consistency accuracy and dimensional consistency or or homogeneity of the equation homogeneity of various mathematical 2expressions. When magnitudes of two or more x = x 0 + v 0 t + (1/2 ) a t physical quantities are multiplied, their units for the distance x travelled by a particle or body should be treated in the same manner as in time t which starts from the position x0 with ordinary algebraic symbols. We can cancel an initial velocity v0 at time t = 0 and has uniformidentical units in the numerator and acceleration a along the direction of motion. denominator. The same is true for dimensions The dimensions of each term may be written as of a physical quantity. Similarly, physical [x] = [L] quantities represented by symbols on both sides of a mathematical equation must have the same [x0 ] = [L] dimensions. [v0 t] = [L T–1] [T] = [L] [(1/2) a t2] = [L T–2] [T2]1.6.1 Checking the Dimensional Consistency of Equations = [L] As each term on the right hand side of this The magnitudes of physical quantities may be equation has the same dimension, namely that added together or subtracted from one another of length, which is same as the dimension of only if they have the same dimensions. In other left hand side of the equation, hence this words, we can add or subtract similar physical equation is a dimensionally correct equation. quantities. Thus, velocity cannot be added to It may be noted that a test of consistency of force, or an electric current cannot be subtracted dimensions tells us no more and no less than a from the thermodynamic temperature. This test of consistency of units, but has the simple principle called the principle of advantage that we need not commit ourselves homogeneity of dimensions in an equation is to a particular choice of units, and we need not extremely useful in checking the correctness of worry about conversions among multiples and an equation. If the dimensions of all the terms sub-multiples of the units. It may be borne in are not same, the equation is wrong. Hence, if mind that if an equation fails this consistency we derive an expression for the length (or test, it is proved wrong, but if it passes, it is distance) of an object, regardless of the symbols not proved right. Thus, a dimensionally correct appearing in the original mathematical relation, equation need not be actually an exact when all the individual dimensions are (correct) equation, but a dimensionally wrong simplified, the remaining dimension must be (incorrect) or inconsistent equation must be that of length. Similarly, if we derive an equation wrong. of speed, the dimensions on both the sides of ⊳equation, when simplified, must be of length/ Example 1.3 Let us consider an equation time, or [L T–1]. Dimensions are customarily used as a 1 2 m v = m g h preliminary test of the consistency of an 2 equation, when there is some doubt about the where m is the mass of the body, v its correctness of the equation. However, the velocity, g is the acceleration due to dimensional consistency does not guarantee gravity and h is the height. Check correct equations. It is uof dimensionless quantities or functions. The correct. arguments of special functions, such as the trigonometric, logarithmic and exponential Answer The dimensions of LHS are functions must be dimensionless. A pure [M] [L T–1 ]2 = [M] [ L2 T–2] number, ratio of similar physical quantities, = [M L2 T–2] Reprint 2025-26 UNITS AND MEASUREMENT 9 The dimensions of RHS are string, that oscillates under the action of [M][L T–2] [L] = [M][L2 T–2] the force of gravity. Suppose that the period = [M L2 T–2] of oscillation of the simple pendulum depends on its length (l), mass of the bobThe dimensions of LHS and RHS are the same and hence the equation is dimensionally correct. ⊳ (m) and acceleration due to gravity (g). Derive the expression for its time period ⊳ using method of dimensions. Example 1.4 The SI unit of energy is J = kg m2 s–2; that of speed v is m s–1 and Answer The dependence of time period T on of acceleration a is m s–2. Which of the the quantities l, g and m as a product may be formulae for kinetic energy (K) given below written as : can you rule out on the basis of T = k lx gy mz dimensional arguments (m stands for the mass of the body) : where k is dimensionless constant and x, y (a) K = m2 v3 and z are the exponents. (b) K = (1/2)mv2 By considering dimensions on both sides, we (c) K = ma have (d) K = (3/16)mv2 o o 1 1 x 1 –2 y 1 z [L M T ]=[L ] [L T ] [M ] (e) K = (1/2)mv2 + ma = Lx+y T–2y Mz Answer Every correct formula or equation must On equating the dimensions on both sides, have the same dimensions on both sides of the we have equation. Also, only quantities with the same x + y = 0; –2y = 1; and z = 0 physical dimensions can be added or 1 1 subtracted. The dimensions of the quantity on So that x = , y = – , z = 0 2 2the right side are [M2 L3 T–3] for (a); [M L2 T–2] for (b) and (d); [M L T–2] for (c). The quantity on the Then, T = k l½ g–½ right side of (e) has no proper dimensions since two quantities of different dimensions have been l or, T = kadded. Since the kinetic energy K has the g dimensions of [M L2 T–2], formulas (a), (c) and (e) Note that value of constant k can not be obtainedare ruled out. Note that dimensional arguments by the method of dimensions. Here it does notcannot tell which of the two, (b) or (d), is the matter if some number multiplies the right sidecorrect formula. For this, one must turn to the of this formula, because that does not affect itsactual definition of kinetic energy (see dimensions.Chapter 5). The correct formula for kinetic energy is given by (b). ⊳ l Actually, k = 2π so that T = 2π ⊳ 1.6.2 Deducing Relation among the g Physical Quantities The method of dimensions can sometimes be Dimensional analysis is very useful in deducing used to deduce relation among the physical relations among the interdependent physical quantities. For this we should know the quantities. However, dimensionless constants dependence of the physical quantity on other cannot be obtained by this method. The method quantities (upto three physical quantities or of dimensions can only test the dimensional linearly independent variables) and consider it validity, but not the exact relationship between as a product type of the dependence. Let us take physical quantities in any equation. It does not an example. distinguish between the physical quantities having same dimensions.⊳ Example 1.5 Consider a simple A number of exercises at the end of this pendulum, having a bob attached to a chapter will help you develop skill in dimensional analysis. Reprint 2025-26 10 PHYSICS SUMMARY 1. Physics is a quantitative science, based on measurement of physical quantities. Certain physical quantities have been chosen as fundamental or base quantities (such as length, mass, time, electric current, thermodynamic temperature, amount of substance, and luminous intensity). 2. Each base quantity is defined in terms of a certain basic, arbitrarily chosen but properly standardised reference standard called unit (such as metre, kilogram, second, ampere, kelvin, mole and candela). The units for the fundamental or base quantities are called fundamental or base units. 3. Other physical quantities, derived from the base quantities, can be expressed as a combination of the base units and are called derived units. A complete set of units, both fundamental and derived, is called a system of units. 4. The International System of Units (SI) based on seven base units is at present internationally accepted unit system and is widely used throughout the world. 5. The SI units are used in all physical measurements, for both the base quantities and the derived quantities obtained from them. Certain derived units are expressed by means of SI units with special names (such as joule, newton, watt, etc). 6. The SI units have well defined and internationally accepted unit symbols (such as m for metre, kg for kilogram, s for second, A for ampere, N for newton etc.). 7. Physical measurements are usually expressed for small and large quantities in scientific notation, with powers of 10. Scientific notation and the prefixes are used to simplify measurement notation and numerical computation, giving indication to the precision of the numbers. 8. Certain general rules and guidelines must be followed for using notations for physical quantities and standard symbols for SI units, some other units and SI prefixes for expressing properly the physical quantities and measurements. 9. In computing any physical quantity, the units for derived quantities involved in the relationship(s) are treated as though they were algebraic quantities till the desired units are obtained. 10. In measured and computed quantities proper significant figures only should be retained. Rules for determining the number of significant figures, carrying out arithmetic operations with them, and ‘rounding off ‘ the u 11. The dimensions of base quantities and combination of these dimensions describe the nature of physical quantities. Dimensional analysis can be used to check the dimensional consistency of equations, deducing relations among the physical quantities, etc. A dimensionally consistent equation need not be actually an exact (correct) equation, but a dimensionally wrong or inconsistent equation must be wrong. EXERCISES Note : In stating numerical answers, take care of significant figures. 1.1 Fill in the blanks (a) The volume of a cube of side 1 cm is equal to .....m3 (b) The surface area of a solid cylinder of radius 2.0 cm and height 10.0 cm is equal to ...(mm)2 (c) A vehicle moving with a speed of 18 km h–1 covers....m in 1 s (d) The relative density of lead is 11.3. Its density is ....g cm–3 or ....kg m–3. 1.2 Fill in the blanks by suitable conversion of units (a) 1 kg m2 s–2 = ....g cm2 s–2 (b) 1 m = ..... ly (c) 3.0 m s–2 = .... km h–2 (d) G = 6.67 × 10–11 N m2 (kg)–2 = .... (cm)3 s–2 g–1. Reprint 2025-26 UNITS AND MEASUREMENT 11 1.3 A calorie is a unit of heat (energy in transit) and it equals about 4.2 J where 1J = 1 kg m2 s–2. Suppose we employ a system of units in which the unit of mass equals α kg, the unit of length equals β m, the unit of time is γ s. Show that a calorie has a magnitude 4.2 α–1 β–2 γ 2 in terms of the new units. 1.4 Explain this statement clearly : “To call a dimensional quantity ‘large’ or ‘small’ is meaningless without specifying a standard for comparison”. In view of this, reframe the following statements wherever necessary : (a) atoms are very small objects (b) a jet plane moves with great speed (c) the mass of Jupiter is very large (d) the air inside this room contains a large number of molecules (e) a proton is much more massive than an electron (f) the speed of sound is much smaller than the speed of light. 1.5 A new unit of length is chosen such that the speed of light in vacuum is unity. What is the distance between the Sun and the Earth in terms of the new unit if light takes 8 min and 20 s to cover this distance ? 1.6 Which of the following is the most precise device for measuring length : (a) a vernier callipers with 20 divisions on the sliding scale (b) a screw gauge of pitch 1 mm and 100 divisions on the circular scale (c) an optical instrument that can measure length to within a wavelength of light ? 1.7 A student measures the thickness of a human hair by looking at it through a microscope of magnification 100. He makes 20 observations and finds that the average width of the hair in the field of view of the microscope is 3.5 mm. What is the estimate on the thickness of hair ? 1.8 Answer the following : (a)You are given a thread and a metre scale. How will you estimate the diameter of the thread ? (b)A screw gauge has a pitch of 1.0 mm and 200 divisions on the circular scale. Do you think it is possible to increase the accuracy of the screw gauge arbitrarily by increasing the number of divisions on the circular scale ? (c) The mean diameter of a thin brass rod is to be measured by vernier callipers. Why is a set of 100 measurements of the diameter expected to yield a more reliable estimate than a set of 5 measurements only ? 1.9 The photograph of a house occupies an area of 1.75 cm2 on a 35 mm slide. The slide is projected on to a screen, and the area of the house on the screen is 1.55 m2. What is the linear magnification of the projector-screen arrangement. 1.10 State the number of significant figures in the following : (a) 0.007 m2 (b) 2.64 × 1024 kg (c) 0.2370 g cm–3 (d) 6.320 J (e) 6.032 N m–2 (f) 0.0006032 m2 1.11 The length, breadth and thickness of a rectangular sheet of metal are 4.234 m, 1.005 m, and 2.01 cm respectively. Give the area and volume of the sheet to correct significant figures. 1.12 The mass of a box measured by a grocer’s balance is 2.30 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is (a) the total mass of the box, (b) the difference in the masses of the pieces to correct significant figures ? 1.13 A famous relation in physics relates ‘moving mass’ m to the ‘rest mass’ mo of a particle in terms of its speed v and the speed of light, c. (This relation first arose as a consequence of special relativity due to Albert Einstein). A boy recalls the relation almost correctly but forgets where to put the constant c. He writes : m 0 m = 2 1/2 . 1 − v ( ) Guess where to put the missing c. Reprint 2025-26 12 PHYSICS 1.14 The unit of length convenient on the atomic scale is known as an angstrom and is denoted by Å: 1 Å = 10–10 m. The size of a hydrogen atom is about 0.5 Å. What is the total atomic volume in m3 of a mole of hydrogen atoms ? 1.15 One mole of an ideal gas at standard temperature and pressure occupies 22.4 L (molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen ? (Take the size of hydrogen molecule to be about 1 Å). Why is this ratio so large ? 1.16 Explain this common observation clearly : If you look out of the window of a fast moving train, the nearby trees, houses etc. seem to move rapidly in a direction opposite to the train’s motion, but the distant objects (hill tops, the Moon, the stars etc.) seem to be stationary. (In fact, since you are aware that you are moving, these distant objects seem to move with you). 1.17 The Sun is a hot plasma (ionized matter) with its inner core at a temperature exceeding 107 K, and its outer surface at a temperature of about 6000 K. At these high temperatures, no substance remains in a solid or liquid phase. In what range do you expect the mass density of the Sun to be, in the range of densities of solids and liquids or gases ? Check if your guess is correct from the following data : mass of the Sun = 2.0 ×1030 kg, radius of the Sun = 7.0 × 108 m. Reprint 2025-26 CHAPTER TWO MOTION IN A STRAIGHT LINE 2.1 INTRODUCTION Motion is common to everything in the universe. We walk, run and ride a bicycle. Even when we are sleeping, air moves 2.1 Introduction into and out of our lungs and blood flows in arteries and 2.2 Instantaneous velocity and veins. We see leaves falling from trees and water flowing speed down a dam. Automobiles and planes carry people from one 2.3 Acceleration place to the other. The earth rotates once every twenty-four 2.4 Kinematic equations for hours and revolves round the sun once in a year. The sun uniformly accelerated motion itself is in motion in the Milky Way, which is again moving