9.17 (a) sin i¢c = 1.44/1.68 which gives i¢c = 59°. Total internal reflection takes place when i > 59° or when r < rmax = 31°. Now, (sin i /sin r max max ) = 1.68 , which gives imax ~ 60°. Thus, all incident rays of angles in the range 0 < i < 60° will suffer total internal reflections in the pipe. (If the length of the pipe is finite, which it is in practice, there will be a lower limit on i determined by the ratio of the diameter to the length of the pipe.) (b) If there is no outer coating, i¢c = sin–1(1/1.68) = 36.5°. Now, i = 90° will have r = 36.5° and i¢ = 53.5° which is greater than i¢c. Thus, all incident rays (in the range 53.5° < i < 90°) will suffer total internal reflections.

9.15 Apply mirror equation and the condition: (a) f < 0 (concave mirror); u < 0 (object on left) (b) f > 0; u < 0 (c) f > 0 (convex mirror) and u < 0 (d) f < 0 (concave mirror); f < u < 0 to deduce the desired result.

5.12 Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?