Practice Questions

Q43.The correct group of halide ions which can be oxidised by oxygen in acidic medium is (1) Br– and I– only (2) Br– only (3) I– only (4) Cl– , Br– and I– only

Q43.What is the mass ratio of ethylene glycol ( C2H6O2 , molar mass = 62 g/ mol) required for making 500 g of 0. 25 molal aqueous solution and 250 mL of 0. 25 molar aqueous solution? (1) 1 : 1 (2) 3 : 1 (3) 2 : 1 (4) 1 : 2

Q43. Be(OH)2 reacts with Sr(OH)2 to yield an ionic salt. Choose the incorrect option related to this reaction from the following (1) Both Sr and Be elements are present in the ionic (2) Beis tetrahedrally coordinated in the ionic salt salt (3) The element Be is present in the cationic part of (4) The reaction is an example of acid-base the ionic salt neutralization reaction

Q44.Match List-I with List-II. Choose the correct answer from the options given below: (1) A-II, B-IV, C-I, D-III (2) A-IV, B-I, C-III, D-II (3) A-IV, B-I, C-II, D-III (4) A-II, B-IV, C-III, D-I

Q44.Match List I with List II List I List II A I Fittig reaction B II Wurtz Fittig reaction JEE Main 2023 (30 Jan Shift 1) JEE Main Previous Year Paper C III Finkelstein reaction D C2H5Cl + NaI →C2H5I + Nacl IV Sandmeyer reaction (1) A–II, B–I, C–III, D–IV (2) A–III, B–II, C–IV, D–I (3) A–IV, B–II, C–III, D–I (4) A–II, B–I, C–IV, D–III

Q44.In the following reaction ‵X′ is Anhy.AlCl3 −CH3 (CH2)4 CH3 → X HCl major product △ (1) (2) (3) CH3 (CH2)4 CH2 Cl (4) Cl −CH2 −(CH2)4 −CH2 −Cl

Q44.Which of the following are the example of double salt? (A) FeSO4 · NH42SO4 · 6H2O (B) CuSO4 · 4NH3 · H2O (C) K2SO4 · Al2SO43 · 24H2O (D) Fe ( CN · 4KCN ) 2 Choose the correct answer. (1) A and C only (2) A and B only (3) A, B and D only (4) B and D only

Q44.The major product formed in the following reaction is A. B. JEE Main 2023 (11 Apr Shift 2) JEE Main Previous Year Paper C. D. choose the correct answer from the options Given below: (1) B only (2) A only (3) C only (4) D only

Q44.The descending order of acidity for the following carboxylic acid is- (A) CH3 COOH (B) F3C −COOH JEE Main 2023 (08 Apr Shift 2) JEE Main Previous Year Paper (C) ClCH2 −COOH (D) FCH2 −COOH (E) BrCH2 −COOH Choose the correct answer from the options given below: (1) B > C > D > E > A (2) E > D > B > A > C (3) B > D > C > E > A (4) D > B > A > E > C

Q44.The complex that dissolves in water is (1) NH43AsMo3O104 (2) Fe4Fe ( CN ) 63 (3) K3CoNO26 (4) Fe3 ( OH ) 2 ( OAc ) 6Cl

Q44.Which of the following statements are correct? (A) The M3 + / M2 + reduction potential for iron is greater than manganese. (B) The higher oxidation states of first row d-block elements get stabilized by oxide ion (C) Aqueous solution of Cr2 + can liberate hydrogen from dilute acid (D) Magnetic moment of V2 + is observed between 4 . 4 - 5 . 2 BM JEE Main 2023 (10 Apr Shift 1) JEE Main Previous Year Paper Choose the correct answer from the options given below: (1) B, C only (2) A, B, D only (3) C, D only (4) A, B only

Q44.Cobalt chloride when dissolved in water forms pink colored complex X which has octahedral geometry. This solution on treating with cone HCl forms deep blue complex, Y which has a Z geometry. X, Y and Z, respectively, are (1) X = CoH2O6 2 + , Y = CoCl4 2 - , Z = Tetrahedral(2) X = CoH2O6 2 + , Y = CoCl6 3 - , Z = Octahedral (3) X = CoH2O6 3 + , Y = CoCl6 3 - , Z = Octahedral(4) X = CoH2O4Cl2 +, Y = CoCl4 2 - , Z = Tetrahedral

Q44.The complex with highest magnitude of crystal field splitting energy (Δ0) is (1) [Ti(OH2)6]3+ (2) [Cr (OH2)6]3+ (3) [Mn (OH2)6]3+ (4) [Fe (OH2)6]3+

Q45.The reaction occurs in which of the given galvanic cell? 1 2 H2( g) + AgCl(s) ⇌H+(aq) + Cl−(aq) + Ag(s) (1) Pt |H2(g)| HCl(soln )| AgCl(s)| Ag (2) Ag | AgCl(s)| KCl(soln )| AgNO3 | Ag (3) Pt |H2(g)| HCl(soln )| AgNO3(soln )| Ag (4) Pt |H2(g)| KCl(soln )| AgCl(s)| Ag

Q45.For the reaction Acetone RCH2Br + I- ⟶ RCH2I + Br- major The correct statement is (1) Br– can act as competing nucleophile. (2) The reaction can occur in acetic acid also. (3) The transition state formed in the above reaction (4) The solvent used in the reaction solvates the ions is less polar than the localised anion. formed in rate determining step

Q45.Which of the following complexes will exhibit maximum attraction to an applied magnetic field? (1) [Ni ( H2O ) 6] 2 + (2) [Co ( en ) 3] 3 + (3) [Zn ( H2O ) 6] 2 + (4) [Co ( H2O ) 6] 2 +

Q45.Correct statement about smog is (1) NO2 is present in classical smog (2) Both NO2 and SO2 are present in classical smog (3) Photochemical smog has high concentration of (4) Classical smog also has high concentration of oxidizing agents oxidizing agents

Q45.The major product formed in the Friedel-Craft acylation of chlorobenzene is (1) (2) (3) (4) Q46. ‘ A’ formed in the above reaction is (1) (2) (3) (4)

Q45.The octahedral diamagnetic low spin complex among the following is (1) CoNH36 3 + (2) CoF6 3 - (3) CoCl6 3 - (4) NiCl4 2

Q45.Identify the incorrect option from the following: JEE Main 2023 (01 Feb Shift 1) JEE Main Previous Year Paper (1) (2) (3) (4)

Q45.The correct order of melting point of dichlorobenzenes is (1) (2) (3) (4)

Q45.Which of the following compounds would give the following set of qualitative analysis? (i) Fehling’s Test: Positive (ii) Na fusion extract upon treatment with sodium nitroprusside gives a blood red colour but not prussian blue. (1) (2) (3) (4)

Q45.The correct IUPAC nomenclature for the following compound is: (1) 2 -Methyl- 5 -oxohexanoic acid (2) 2 -Formyl- 5 -methylhexan- 6 -oic acid (3) 5 -Methyl- 2 -oxohexan- 6 -oic acid (4) 5 -Formyl- 2 -methylhexanoic acid

Q46.Decreasing order of dehydration of the following alcohols is (1) a > d > b > c (2) b > d > c > a (3) b > a > d > c (4) d > b > c > a

Q46.The number of given statement/s which is/are correct is_____ (A) The stronger the temperature dependence of the rate constant, the higher is the activation energy. (B) If a reaction has zero activation energy, its rate is independent of temperature. (C) The stronger the temperature dependence of the rate constant, the smaller is the activation energy. (D) If there is no correlation between the temperature and the rate constant then it means that the reaction has negative activation energy.