Practice Questions

Q36.Among the following compounds, the one which shows highest dipole moment is (1) (2) (3) (4)

Q36.Enthalpies of formation of CCl4( g), H2O(g), CO2( g) and HCl are −105, −242, −394 and −92 kJ mol−1 respectively. The magnitude of enthalpy of the reaction given below is kJmol−1 . (nearest integer) CCl4( g) + 2H2O(g) →CO2( g) + 4 HCl(g)

Q36.If the pKa of lactic acid is 5 , then the pH of 0. 005 M calcium lactate solution at 25° C is __________ × 10–1 (Nearest integer)

Q36.Match List-I with List-II. List-I List-II Element detected Reagent used/Product formed A Nitrogen I Na2FeCN5NO B Sulphur II AgNO3 C Phosphorus III Fe4FeCN63 D Halogen IV NH42MoO4 Choose the correct answer from the options given below: (1) A →III; B →I; C →IV; D →II (2) A →II; B →IV; C →I; D → III (3) A →IV; B →II; C →I; D →III (4) A →II; B →I; C →IV; D →III

Q36. Three bulbs are filled with CH4, CO2 and Ne as shown in the picture. The bulbs are connected through pipes of zero volume. When the stopcocks are opened and the temperature is kept constant throughout, the pressure of the system is found to be______ atm. (Nearest integer).

Q36.The volume of HCl, containing 73g L−1 , required to completely neutralise NaOH obtained by reacting 0. 69 g of metallic sodium with water, is _____ mL. (Nearest Integer) (Given : molar Masses of Na, Cl, O, H are 23, 35. 5, 16 and 1g mol−1 respectively)

Q36.The strength of 50 volume solution of hydrogen peroxide is _____ g/L (Nearest integer). Given: Molar mass of H2O2 is 34 g mol−1 Molar volume of gas at STP = 22. 7 L.

Q37.One mole of an ideal gas at 350 K is in a 2. 0 L vessel of thermally conducting walls, which are in contact with the surroundings. It undergoes isothermal reversible expansion from 2. 0 L to 3. 0 L against a constant pressure of 4 atm. The change in entropy of the surroundings (ΔS) is _____ J K–1 (Nearest integer) Given: R = 8. 314 J K−1 mol−1 . JEE Main 2023 (12 Apr Shift 1) JEE Main Previous Year Paper

Q37. Where Nu = Nucleophile Find out the correct statement from the options given below for the above two reactions. JEE Main 2023 (11 Apr Shift 1) JEE Main Previous Year Paper (1) Reaction (I) is of 2nd order and reaction (II) is of (2) Reactions (I) and (II) both are of 2nd order 1st order (3) Reactions (I) is of 1st order and reaction (II) is of (4) Reaction (I) and (II) both are of 1st order 2 nd order

Q37.The equilibrium composition for the reaction PCl3 + Cl2 ⇌PCl5 at 298 K is given below: [PCl3]eq = 0. 2 mol L−1, [Cl2]eq = 0. 1 mol L−1, [PCl5]eq = 0. 40 mol L−1 If 0. 2 mol of Cl2 is added at the same temperature, the equilibrium concentrations of PCl5 is _____ ×10–2 mol L–1 Given: Kc for the reaction at 298 K is 20

Q37.Millimoles of calcium hydroxyide required to produce 100 mL of the aqueous solution of pH 12 is x × 10−1 . The value of x is _____ (Nearest integer). Assume complete dissociation.

Q37.The major product for the following reaction is : JEE Main 2023 (13 Apr Shift 2) JEE Main Previous Year Paper (1) (2) (3) (4)

Q37.Which of the following statement is correct for paper chromatography? (1) Water present in the pores of the paper forms the (2) Paper sheet forms the stationary phase. stationary phase. (3) Water present in the mobile phase gets absorbed (4) Paper and water present in its pores together by the paper which then forms the stationary form the stationary phase. phase.

Q37.The incorrect statements from the following is: A. The electrical work that a reaction can perform at constant pressure and temperature is equal to the reaction Gibbs energy. B. E∘cell is dependent on the pressure. ° ΔrS° C. dE cell = dT nF D. A cell is operating reversibly if the cell potential is exactly balanced by an opposing source of potential difference. JEE Main 2023 (08 Apr Shift 2) JEE Main Previous Year Paper

Q37.Which of the following is true about freons? (1) These are chlorofluorocarbon compounds (2) These are chemicals causing skin cancer (3) These are radicals of chlorine and chlorine (4) All radicals are called freons monoxide

Q37.Lime reacts exothermally with water to give ‘A’ which has low solubility in water. Aqueous solution of ‘A’ is often used for the test of CO2, a test in which insoluble B is formed. If B is further reacted with CO2 then soluble compound is formed. ‘A' is (1) Quick lime (2) Slaked lime (3) White lime (4) Lime water

Q37.A certain quantity of real gas occupies a volume of 0. 15 dm3 at 100 atm and 500 K when its compressibility factor is 1. 07. Its volume at 300 atm and 300 K (When its compressibility factor is 1. 4) is ______ × 10−4 dm3 (Nearest integer)

Q37.Which of the following represents the lattice structure of A0 . 95O containing A2 + , A3 + and O2 – ions? A. JEE Main 2023 (01 Feb Shift 1) JEE Main Previous Year Paper B. C. (1) B and C only (2) B only (3) A and B only (4) A only

Q37. O −O bond length in H2O2 is X than the O −O bond length in F2O2 . The O −H bond length in H2O2 is Y ¯¯ than that of the O −F bond in F2O2 . Choose the correct option for X and Y from the given below. ¯¯ (1) X - shorter, Y− shorter (2) X -shorter, Y -longer (3) X -longer, Y -longer (4) X-longer, Y - shorter

Q37.Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R Assertion A:- The alkali metals and their salts impart characteristic colour to reducing flame. Reason R:- Alkali metals can be detected using flame tests. In the light of the above statements, choose the most appropriate answer form the options given below (1) Both A and R are correct but R is NOT the (2) A is correct but R is not correct. correct explanation of A. (3) A is not correct but R is correct (4) Both A and R are correct and R is the correct explanation of A.

Q37.Which of the following conformations will be the most stable? JEE Main 2023 (25 Jan Shift 1) JEE Main Previous Year Paper (1) (2) (3) (4)

Q37.Which one of the following statements is correct for electrolysis of brine solution? (1) Cl2 is formed at cathode (2) O2 is formed at cathode (3) H2 is formed at anode (4) OH-is formed at cathode

Q37.Incorrect statement for the use of indicator in acid-base titration is: JEE Main 2023 (31 Jan Shift 2) JEE Main Previous Year Paper (1) Methyl orange may be used for a weak acid vs (2) Phenolphthalein may be used for a strong acid vs weak bas titration. strong base titration. (3) Methyl orange is a suitable indicator for a strong (4) Phenolphthalein is a suitable indicator for a weak acid vs weak base titration. acid vs strong base titration.

Q37.Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide. JEE Main 2023 (24 Jan Shift 2) JEE Main Previous Year Paper (1) (2) (3) (4)

Q37.What is the correct order of acidity of the protons marked 𝐴– 𝐷 in the given compounds? (1) HC > HD > HB > HA (2) HC > HD > HA > HB (3) HD > HC > HB > HA (4) HC > HA > HD > HB