Practice Questions

Q36. Correct order of basic strength of Pyrrole , Pyridine , and Piperidine is: (1) Pyrrole > Piperidine > Pyridine (2) Pyrrole > Pyridine > Piperidine (3) Pyridine > Piperidine > Pyrrole (4) Piperidine > Pyridine > Pyrrole

Q36. X ⇌Y; K1 = 1.0 For the given hypothetical reactions, the equilibrium constants are as follows : Y ⇌Z; K2 = 2.0 The Z ⇌W; K3 = 4.0 equilibrium constant for the reaction X ⇌W is (1) 6.0 (2) 12.0 (3) 7.0 (4) 8.0

Q36.The equilibrium constant for the reaction SO3(g) ⇌SO2( g) + 12 O2( g) is Kc = 4.9 × 10−2 . The value of Kc for the reaction given below is 2SO2( g) + O2( g) ⇌2SO3( g) is : (1) 4.9 (2) 49 (3) 41.6 (4) 416

Q36.Which of the following reactions are disproportionation reactions? 1 Cu+ →Cu2 + + Cu 2 3MnO42 - + 4H+ →2MnO4- + MnO2 + 2H2O 3 2KMnO4 →K2MnO4 + MnO2 + O2 4 2MnO4- + 3Mn2 + + 2H2O →5MnO2 + 4H+ Choose the correct answer from the options given below: (1) 1, 2 (2) 2, 3, 4 (3) 1, 2, 4 (4) 1, 4

Q36.The incorrect statement regarding ethyne is (1) The C −C bonds in ethyne is shorter than that in (2) Both carbons are sp hybridised ethene (3) Ethyne is linear (4) The corbon - carbon bonds in ethyne is weaker than that in ethene

Q36.Given below are two statement one is labeled as Assertion (A) and the other is labeled as Reason (R). Assertion (A): CH2 = CH −CH2 −Cl is an example of allyl halide Reason (R): Allyl halides are the compounds in which the halogen atom is attached to sp2 hybridised carbon atom. JEE Main 2024 (30 Jan Shift 1) JEE Main Previous Year Paper In the light of the two above statements, choose the most appropriate answer from the options given below: (1) (A) is true but (R) is false (2) Both (A) and (R) are true but (R) is not the correct explanation of A (3) (A) is false but (R) is true (4) Both (A) and (R) are true and (R) is the correct explanation of (A)

Q36.The correct statement among the following, for a "chromatography" purification method is : (1) Organic compounds run faster than solvent in the (2) Rf is an integral value. thin layer chromatographic plate. (3) Rf of a polar compound is smaller than that of a (4) Non-polar compounds are retained at top and non-polar compound. polar compounds come down in column chromatography.

Q36.The correct stability order of carbocations is (1) + + + (2) + + + + CH33C+ > CH3 - CH2 > CH32 CH > CH3 CH3 > CH32 CH > CH3 - CH2 > CH33 C (3) + + + + (4) $\stackrel{+\quad} CH33 C > CH32 CH > CH3 - CH2 > CH3 {\mathrm{C}\mathrm{H}_3}>\mathrm{CH}_3- \stackrel{+ \quad}{\mathrm{C} \mathrm{H}_2}>\mathrm{CH}_3-\underset{| \atop \stackrel{ \atop }{\huge \mathrm{CH}_3}} {\stackrel{+ \quad}{\mathrm{C} \mathrm{H}}}>\left(\mathrm{CH}_3\right) \mathrm{C}^{+}$

Q36.Given below are two statements : Statement I : The electronegativity of group 14 elements from Si to Pb gradually decreases. Statement II : Group 14 contains non-metallic, metallic, as well as metalloid elements. In the light of the above statements, choose the most appropriate from the options given below : (1) Statement I is false but Statement II is true (2) Statement I is true but Statement II is false (3) Both Statement I and Statement II are true (4) Both Statement I and Statement II are false

Q37.Given below are two statements : Statement I: Group 13 trivalent halides get easily hydrolysed by water due to their covalent nature. Statement II: AlCl3 upon hydrolysis in acidified aqueous solution forms octahedral AlH2O6 3 + ion. In the light of the above statements, choose the correct answer from the options given below : (1) Statement I is true but statement II is false (2) Statement I is false but statement II is true (3) Both statement I and statement II are false (4) Both statement I and statement II are true

Q37. IUPAC name of following hydrocarbon (X) is : (1) 2-Ethyl-3,6-dimethylheptane (2) 2,5,6-Trimethyloctane (3) 3,4,7-Trimethyloctane (4) 2-Ethyl-2,6-diethylheptane

Q37. IUPAC name of following compound (P) is : JEE Main 2024 (27 Jan Shift 1) JEE Main Previous Year Paper (1) 1 −Ethyl −5, 5 −dimethylcyclohexane (2) 3 −Ethyl −1, 1 −dimethylcyclohexane (3) 1 −Ethyl −3, 3 −dimethylcyclohexane (4) 1, 1 −Dimethyl −3 −ethylcyclohexane

Q37.The number of neutrons present in the more abundant isotope of boron is ' x '. Amorphous boron upon heating with air forms a product, in which the oxidation state of boron is ' y '. The value of x + y is _______ (1) 3 (2) 9 (3) 4 (4) 6

Q37.The final product A, formed in the following reaction sequence is: (1) Ph - CH2 - CH2 - CH3 (2) (3) (4) Ph - CH2 - CH2 - CH2 - OH

Q37.Which among the following is incorrect statement? (1) Electromeric effect dominates over inductive (2) The electromeric effect is, temporary effect effect (3) Hydrogen ion (H+)shows negative electromeric (4) The organic compound shows electromeric effect effect in the presence of the reagent only.

Q37.Given below are two statements: Statement I: IUPAC name of HO - CH2 - ( CH2 ) - CH2 - COCH3 is 7-hydroxyheptan-2-one. 3 Statement II: 2-oxoheptan-7-ol is the correct IUPAC name for the above compound. In the light of the above statements, Choose the most appropriate answer from the options given below: (1) Statement I is correct but Statement II is (2) Both Statement I and Statement II are incorrect. incorrect. (3) Both Statement I and Statement II are correct. (4) Statement I is incorrect but Statement II is correct. JEE Main 2024 (31 Jan Shift 1) JEE Main Previous Year Paper

Q37.At −20∘C and 1 atm pressure, a cylinder is filled with equal number of H2, I2 and HI molecules for the reaction H2( g) + I2( g) ⇌2HI(g), the Kp for the process is x × 10−1 . x = _____ [Given : R = 0.082 L atm K−1 mol−1 ] (1) 0.01 (2) 10 (3) 2 (4) 1

Q37.The correct nomenclature for the following compound is : (1) 2-formyl-4-hydroxyhept-7-enoic acid (2) 2-formyl-4-hydroxyhept-6-enoic acid (3) 2-carboxy-4-hydroxyhept-7-enal (4) 2-carboxy-4-hydroxyhept-6-enal

Q37. Correct order of stability of carbanion is - (1) d > a > c > b (2) a > b > c > d (3) d > c > b > a (4) c > b > d > a

Q37.Among the following halogens F2, Cl2, Br2 and I2 Which can undergo disproportionation reactions? (1) F2, Cl2 and Br2 (2) F2 and Cl2 (3) Only I2 (4) Cl2, Br2 and I2

Q37. For the given compounds, the correct order of increasing pKa value : Choose the correct answer from the options given below : (1) (B) < (D) < (C) < (A) < (E) (2) (D) < (E) < (C) < (B) < (A) (3) (E) < (D) < ( C ) < ( B ) < ( A ) (4) (E) < (D) < (B) < (A) < (C) JEE Main 2024 (09 Apr Shift 1) JEE Main Previous Year Paper

Q37.For a sparingly soluble salt AB2 , the equilibrium concentrations of A2+ ions and B− ions are 1.2 × 10−4M and 0.24 × 10−3M, respectively. The solubility product of AB2 is : (1) 6.91 × 10−12 (2) 0.276 × 10−12 (3) 27.65 × 10−12 (4) 0.069 × 10−12

Q37.Which one of the following will show geometrical isomerism? JEE Main 2024 (29 Jan Shift 2) JEE Main Previous Year Paper (1) (2) (3) (4)

Q37.The interaction between π bond and lone pair of electrons present on an adjacent atom is responsible for (1) Hyperconjugation (2) Inductive effect (3) Electromeric effect (4) Resonance effect

Q37.Product A and B formed in the following set of reactions are: (1) (2) (3) (4)