Practice Questions

Q36.The following reaction occurs in the Blast furnance where iron ore is reduced to iron metal Fe2O3( s) + 3CO(g) ⇌Fe(l) + 3CO2( g) Using the Le-chatelier's principle, predict which one of the following will not disturb the equilibrium. (1) Addition of CO2 (2) Removal of CO2 (3) Addition of Fe2O3 (4) Removal of CO

Q36. List - I List - II (Molecule/Species) (Property/Shape) A. SO2Cl2 I. Paramagnetic Match List I with List II Choose the correct answer B. NO II. Diamagnetic C. NO−2 III. Tetrahedral D. I−3 IV. Linear from the options given below: (1) A-II, B-III, C-I, D-IV (2) A-III, B-I, C-II, D-IV (3) A-IV, B-I, C-III, D-II (4) A-III, B-IV, C-II, D-I

Q36.The technique used for purification of steam volatile water immiscible substance is: (1) Fractional distillation (2) Fractional distillation under reduced pressure (3) Distillation (4) Steam distillation

Q36.The correct statements from the following are : (A) The decreasing order of atomic radii of group 13 elements is Tl > In > Ga > Al > B . (B) Down the group 13 electronegativity decreases from top to bottom. (C) Al dissolves in dil. HCl and liberates H2 but conc. HNO3 renders Al passive by forming a protective oxide layer JEE Main 2024 (05 Apr Shift 2) JEE Main Previous Year Paper on the surface. (D) All elements of group 13 exhibits highly stable +1 oxidation state. (E) Hybridisation of Al in [Al(H2O)6]3+ ion is sp3 d2 . Choose the correct answer from the options given below : (1) (A), (C) and (E) only (2) (A) and (C) only (3) (C) and (E) only (4) (A), (B), (C) and (E) only

Q36.The correct sequence of acidic strength of the following aliphatic acids in their decreasing order is: CH3CH2COOH, CH3COOH, CH3CH2CH2COOH, HCOOH JEE Main 2024 (08 Apr Shift 2) JEE Main Previous Year Paper (1) CH3CH2CH2COOH > CH3CH2COOH > CH3COOH > HCOOH (2) CH3COOH > CH3CH2COOH > CH3CH2CH2COOH > HCOOH (3) HCOOH > CH3COOH > CH3CH2COOH > CH3CH2CH2COOH (4) HCOOH > CH3CH2CH2COOH > CH3CH2COOH > CH3COOH

Q37. IUPAC name of following compound (P) is : JEE Main 2024 (27 Jan Shift 1) JEE Main Previous Year Paper (1) 1 −Ethyl −5, 5 −dimethylcyclohexane (2) 3 −Ethyl −1, 1 −dimethylcyclohexane (3) 1 −Ethyl −3, 3 −dimethylcyclohexane (4) 1, 1 −Dimethyl −3 −ethylcyclohexane

Q37.In acidic medium, K2Cr2O7 shows oxidising action as represented in the half reaction JEE Main 2024 (01 Feb Shift 1) JEE Main Previous Year Paper Cr2O72 - + XH+ + Ye- →2 A + ZH2O X, Y, Z and A are respectively are: (1) 8, 6, 4 and Cr2O3 (2) 14, 7, 6 and Cr3 + (3) 8, 4, 6 and Cr2O3 (4) 14, 6, 7 and Cr3 +

Q37.Which of the following molecule/species is most stable? (1) (2) (3) (4)

Q37.Which among the following is incorrect statement? (1) Electromeric effect dominates over inductive (2) The electromeric effect is, temporary effect effect (3) Hydrogen ion (H+)shows negative electromeric (4) The organic compound shows electromeric effect effect in the presence of the reagent only.

Q37.The incorrect statement regarding the geometrical isomers of 2-butene is : (1) cis-2-butene and trans-2-butene are not (2) cis-2-butene and trans-2-butene are interconvertible at room temperature. stereoisomers. (3) cis-2-butene has less dipole moment than trans-2- (4) trans-2-butene is more stable than cis-2-butene. butene. JEE Main 2024 (06 Apr Shift 2) JEE Main Previous Year Paper

Q37.For a sparingly soluble salt AB2 , the equilibrium concentrations of A2+ ions and B− ions are 1.2 × 10−4M and 0.24 × 10−3M, respectively. The solubility product of AB2 is : (1) 6.91 × 10−12 (2) 0.276 × 10−12 (3) 27.65 × 10−12 (4) 0.069 × 10−12

Q37.Among the following halogens F2, Cl2, Br2 and I2 Which can undergo disproportionation reactions? (1) F2, Cl2 and Br2 (2) F2 and Cl2 (3) Only I2 (4) Cl2, Br2 and I2

Q37.Product A and B formed in the following set of reactions are: (1) (2) (3) (4)

Q37. For the given compounds, the correct order of increasing pKa value : Choose the correct answer from the options given below : (1) (B) < (D) < (C) < (A) < (E) (2) (D) < (E) < (C) < (B) < (A) (3) (E) < (D) < ( C ) < ( B ) < ( A ) (4) (E) < (D) < (B) < (A) < (C) JEE Main 2024 (09 Apr Shift 1) JEE Main Previous Year Paper

Q37. Correct order of stability of carbanion is - (1) d > a > c > b (2) a > b > c > d (3) d > c > b > a (4) c > b > d > a

Q37.Which one of the following will show geometrical isomerism? JEE Main 2024 (29 Jan Shift 2) JEE Main Previous Year Paper (1) (2) (3) (4)

Q37.The interaction between π bond and lone pair of electrons present on an adjacent atom is responsible for (1) Hyperconjugation (2) Inductive effect (3) Electromeric effect (4) Resonance effect

Q37.The number of neutrons present in the more abundant isotope of boron is ' x '. Amorphous boron upon heating with air forms a product, in which the oxidation state of boron is ' y '. The value of x + y is _______ (1) 3 (2) 9 (3) 4 (4) 6

Q37. IUPAC name of following hydrocarbon (X) is : (1) 2-Ethyl-3,6-dimethylheptane (2) 2,5,6-Trimethyloctane (3) 3,4,7-Trimethyloctane (4) 2-Ethyl-2,6-diethylheptane

Q37.The final product A, formed in the following reaction sequence is: (1) Ph - CH2 - CH2 - CH3 (2) (3) (4) Ph - CH2 - CH2 - CH2 - OH

Q37.At −20∘C and 1 atm pressure, a cylinder is filled with equal number of H2, I2 and HI molecules for the reaction H2( g) + I2( g) ⇌2HI(g), the Kp for the process is x × 10−1 . x = _____ [Given : R = 0.082 L atm K−1 mol−1 ] (1) 0.01 (2) 10 (3) 2 (4) 1

Q37.The correct nomenclature for the following compound is : (1) 2-formyl-4-hydroxyhept-7-enoic acid (2) 2-formyl-4-hydroxyhept-6-enoic acid (3) 2-carboxy-4-hydroxyhept-7-enal (4) 2-carboxy-4-hydroxyhept-6-enal

Q37.Given below are two statements: Statement I: IUPAC name of HO - CH2 - ( CH2 ) - CH2 - COCH3 is 7-hydroxyheptan-2-one. 3 Statement II: 2-oxoheptan-7-ol is the correct IUPAC name for the above compound. In the light of the above statements, Choose the most appropriate answer from the options given below: (1) Statement I is correct but Statement II is (2) Both Statement I and Statement II are incorrect. incorrect. (3) Both Statement I and Statement II are correct. (4) Statement I is incorrect but Statement II is correct. JEE Main 2024 (31 Jan Shift 1) JEE Main Previous Year Paper

Q38.Compound A formed in the following reaction reacts with B gives the product C. Find out A and B. (1) A = CH3 −C ≡C−Na+, B = CH3 −CH2 −CH2 −Br (2) A = CH3 −CH = CH2, B = CH3 −CH2 −CH2 −Br (3) A = CH3 −CH2 −CH3, B = CH3 −C ≡CH (4) A = CH3 −C ≡C−Na+, B = CH3 −CH2 −CH3

Q38.If a substance '𝐴' dissolves in solution of a mixture of ' 𝐵' and ' 𝐶 ' with their respective number of moles as 𝑛𝐴, 𝑛𝐵 and 𝑛𝐶, mole fraction of 𝐶 in the solution is: JEE Main 2024 (30 Jan Shift 2) JEE Main Previous Year Paper nC nC (1) (2) nA × nB × nC nA + nB + nC (3) nC (4) nB nA - nB - nC nA + nB