Practice Questions

Q69.Consider the given plots of vapour pressure (VP) vs temperature(T/K). Which amongst the following options is correct graphical representation showing ΔTf , depression in the freezing point of a solvent in a solution? (1) (2) (3) (4)

Q69.The d- electronic configuration of an octahedral Co(II) complex having magnetic moment of 3.95 BM is: (1) t2 g3eg0 (2) t2 g6eg1 (3) t2 g5eg2 (4) e4t23 2025 (23 Jan Shift 1) JEE Main Previous Year Paper

Q69.The incorrect decreasing order of atomic radii is (1) Si > P > Cl > F (2) Be > Mg > Al > Si (3) Al > B > N > F (4) Mg > Al > C > O

Q69. In the following substitution reaction: product ′P′ formed is : (1) (2) (3) (4)

Q69.Given below are two statements : Statement (I): In partition chromatography, stationary phase is thin film of liquid present in the inert support. Statement (II) : In paper chromatography, the material of paper acts as a stationary phase. In the light of the above statements, choose the correct answer from the options given below : (1) Statement I is true but Statement II is false (2) Statement I is false but Statement II is true (3) Both Statement I and Statement II are false (4) Both Statement I and Statement II are true

Q70.Consider ' n ' is the number of lone pair of electrons present in the equatorial position of the most stable structure of ClF3 . The ions from the following with ' n ' number of unpaired electrons are A. V3+ B. Ti3+ C. Cu2+ D. Ni2+ E. Ti2+ Choose the correct answer from the options given below: (1) A and C Only (2) A, D and E Only (3) B and D Only (4) B and C Only

Q70.If C (diamond ) →C (graphite ) + XkJmol−1 C( diamond ) + O2( g) →CO2( g) + YkJmol−1 C (graphite) +O2( g) →CO2( g) + ZkJmol−1 at constant temperature. Then (1) X=-Y+Z (2) -X=Y+Z (3) X=Y+Z (4) X=Y-Z

Q70.Identify correct conversion during acidic hydrolysis from the following : (A) starch gives galactose. (B) cane sugar gives equal amount of glucose and fructose. (C) milk sugar gives glucose and galactose. (D) amylopectin 2025 (28 Jan Shift 2) JEE Main Previous Year Paper gives glucose and fructose. (E) amylose gives only glucose. Choose the correct answer from the options given below : (1) (A), (B) and (C) only (2) (B), (C) and (E) only (3) (C), (D) and (E) only (4) (B), (C) and (D) only

Q70.Which of the following linear combination of atomic orbitals will lead to formation of molecular orbitals in homonuclear diatomic molecules [internuclear axis in z -direction] ? A. 2pz and 2px B. 2 s and 2px C. 3 dxy 2025 (24 Jan Shift 1) JEE Main Previous Year Paper and 3 dx2−y2 D. 2 s and 2pz E. 2pz and 3dx2 −y2 Choose the correct answer from the options given below: (1) A and B Only (2) D Only (3) E Only (4) C and D Only

Q70.From the magnetic behaviour of [NiCl4]2− (paramagnetic) and [Ni(CO)4] (diamagnetic), choose the correct geometry and oxidation state. (1) [NiCl4]2−: NiII , tetrahedral [Ni(CO)4] : NiII , (2) [NiCl4]2− : NiII , square planar [Ni(CO)4] : Ni(0) square planar , square planar (3) [NiCl4]2−: NiII , tetrahedral [Ni(CO)4] : Ni(0), (4) [NiCl4]2−: Ni(0), tetrahedral [Ni(CO)4] : Ni(0), tetrahedral square planar

Q70.The correct stability order of the following species/molecules is: (1) q > r > p (2) r > q > p (3) q > p > r (4) p > q > r Q71. 1 The standard enthalpy and standard entropy of decomposition of N2O4 to NO2 are 55.0 kJ mol−1 and 175.0 J/K/mol respectively. The standard free energy change for this reaction at 25∘C in J mol−1 is ______ (Nearest integer)

Q70.When a non-volatile solute is added to the solvent, the vapour pressure of the solvent decreases by 10 mm of Hg . The mole fraction of the solute in the solution is 0.2 . What would be the mole fraction of the solvent if decrease in vapour pressure is 20 mm of Hg ? (1) 0.8 (2) 0.4 (3) 0.2 (4) 0.6 Q71.0.01 mole of an organic compound (X) containing 10% hydrogen, on complete combustion produced 0.9 gH2O. Molar mass of (X) is _____ gmol−1 .

Q70.The maximum covalency of a non-metallic group 15 element ' E ' with weakest E −E bond is : (1) 4 (2) 6 (3) 3 (4) 5

Q70.The correct increasing order of stability of the complexes based on Δo value is : I. [Mn(CN)6]3− II. [Co(CN)6]4− III. [Fe(CN)6]4− IV. [Fe(CN)6]3− (1) IV < III < II < I (2) I < II < IV < III (3) III < II < IV < I (4) II < III < I < IV

Q71.The compound with molecular formula C6H6 , which gives only one monobromo derivative and takes up four moles of hydrogen per mole for complete hydrogenation has ________ = electrons. 2025 (22 Jan Shift 2) JEE Main Previous Year Paper Q72.20 mL of 2 M NaOH solution is added to 400 mL of 0.5 M NaOH solution. The final concentration of the solution is _______ ×10−2M. (Nearest integer)

Q71.In Carius method of estimation of halogen, 0.25 g of an organic compound gave 0.15 g of silver bromide (AgBr). The percentage of Bromine in the organic compound is … … ×10−1% (Nearest integer). (Given : Molar mass of Ag is 108 and Br is 80 g mol−1 )

Q71.Electrolysis of 600 mL aqueous solution of NaCl for 5 min changes the pH of the solution to 12 . The current in Amperes used for the given electrolysis is ____. (Nearest integer).

Q71.The formation enthalpies, ΔHf⊖ for H(g) and O(g) are 220.0 and 250.0 kJ mol−1 , respectively, at 298.15 K , and ΔHf ⊖ for H2O(g) is −242.0 kJ mol−1 at the same temperature. The average bond enthalpy of the O −H bond in water at 298.15 K is __________ kJmol−1 (nearest integer).

Q71.The molar mass of the water insoluble product formed from the fusion of chromite ore (FeCr2O4) with Na2CO3 in presence of O2 is _______ gmol−1 .

Q71.In the sulphur estimation, 0.20 g of a pure organic compound gave 0.40 g of barium sulphate. The percentage of sulphur in the compound is ______ ×10−1% . (Molar mass : O = 16, S = 32, Ba = 137 in gmol−1 ) 2025 (29 Jan Shift 2) JEE Main Previous Year Paper

Q71.The number of molecules/ions that show linear geometry among the following is ________ SO2, BeCl2, CO2, N−3 , NO2, F2O, XeF2, NO+2 , I−3 , O3

Q71.Xg of benzoic acid on reaction with aq NaHCO3 released CO2 that occupied 11.2 L volume at STP. X is _____ g.

Q72.A group 15 element forms dπ −dπ bond with transition metals. It also forms hydride, which is a strongest base among the hydrides of other group members that form dπ −dπ bond. The atomic number of the element is ____.

Q72.For the thermal decomposition of N2O5( g) at constant volume, the following table can be formed, for the reaction mentioned below. 2 N2O5( g) →2 N2O4( g) + O2( g) x = … × 10−3 atm [nearest integer] Given : Rate constant for the reaction is 4.606 × 10−2 s−1 .

Q72.Consider the following reaction occurring in the blast furnace: Fe3O4( s) + 4CO(g) →3Fe(l) + 4CO2( g) ' x ' kg of iron is produced when 2.32 × 103 kgFe3O4 and 2.8 × 102 kgCO are brought together in the furnace. The value of ' x ' is _____. (nearest integer) Given: molar mass of Fe3O4 = 232 g mol−1 molar mass of CO = 28 g mol−1 molar mass of Fe = 56 g mol−1} Q73. 37.8 g N2O5 was taken in a 1 L reaction vessel and allowed to undergo the following reaction at 500 K 2 N2O5( g) ⇌2 N2O4( g) + O2( g) The total pressure at equilibrium was found to be 18.65 bar. Then, Kp = ______ ×10−2 [nearest integer] Assume N2O5 to behave ideally under these conditions. Given: R = 0.082 bar Lmol−1 K−1